290 resultados para Tm3 doped fluorophosphate glasses


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Tm^3+Yb^3+RamanTm^3+Yb^3+Tm^3+Yb^3+Tm^3+Yb^3+

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Er^3+Tm^3+/Yb^3+Raman980nmLD(476nm)(530nm545nm)(656nm)(476nm)Tm^3+1^G43^3H6(530nm545nm)Er^3+2^H11/24^I1524^S3/24^I15/2(6

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70TeO2-(20-x)ZnO-xPbO-5La2O3-2.5K2O-25Na2O(x=05101520)Yb2O31Yb^3+((Tx-Tg)>195TZN(118))X=15(125pm^2)(

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DexterEr^3+R0Er^3+CEr-ErCEr-ErEr^3+OH^-

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Ce3+ ions were introduced into the Er3+/Yb3+ -codoped TeO2-WO3-ZnO glasses, and the effect of Ce3+ on the emission properties at 1.5 mu m band and the upconversion luminescence of Er3+ in the glasses was investigated. With the increasing of Ce3+ concentration, the emission intensity of Er3+ at 1.5 mu m band increases firstly, and then decreases. The optimal doping concentration of Ce3+ is about 2.07 x 10(20)/cm(3). As for the Er3+ emission at 1.5-mu m band, the fluorescence lifetime decreases a little from 3.4ms to 3.0ms, while the full width at half maximum (FWHM) hardly changes with the increase of Cc 3+ concentration. Due to the effective cross relaxation between Ce3+ and Er3+ : Er3+ (I-4(11/2)) + Ce3+ (F-2(5/2)) -> Er3+ (I-4(13/2)) + Ce3+ (F-2(7/2)), the upconversion emission intensity of Er3+ is reduced greatly. But when Ce3+ -doping concentration is too high, the other cross relaxation between Ce3+ and Er3+ : Er3+ (4I(13/2)) + Ce3+ (F-2(5/2)) -> Er3+ (I-4(15/2)) + Ce3+ (F-2(7/2)) happens, which depopulates the I-4(13/2) level of Er3+ and results in the decrease of the emission intensity and fluorescence lifetime of Er3+ at 1.5 mu m band.