一种结晶硒铁复合物Fe(HSeO3)(Se2O5)的制备方法

本发明提供一种结晶硒铁复合物Ｆｅ（ＨＳｅＯ＃－［３］）（Ｓｅ＃－［２］Ｏ＃－［５］）的制备方法，在较低的反应温度、较短的反应时间下，由Ｆｅ（ＯＨ）＃－［３］溶胶和固体Ｈ＃－［２］ＳｅＯ＃－［３］反应，得到悬浊液，水分蒸干后Ｈ＃－［２］还原，制取Ｆｅ（ＨＳｅＯ＃－［３］）（Ｓｅ＃－［２］Ｏ＃－［５］）。和同类合成方法相比，本方法具有反应条件温和、操作规程简单的优点。

高温超导体中Fe占位研究的一种半经验方法

利用一种半经验方法研究了高温超导体Y-124的化学键性质.阐明了Y-124的Mssbauer谱同质异能位移和化学键参数之间的关系.计算结果支持掺杂的铁元素是以Fe3+价态占据Y-124的平面正方形Cu(1)3+晶位的观点.表明从化学键的观点预测高温超导体性质的可能性.

Large-scale synthesis of Berlin green Fe[Fe(CN)(6)] microcubic crystals

Berlin green FeFe(CN)(6) microcubic crystals have been successfully prepared by a simple hydrothermal process between K-3[Fe(CN)(6)] with Na2S2O3 aqueous solution, free of any surfactant or template. The experimental results clearly show that the molar ratio of K-3[Fe(CN)(6)] to Na2S2O3 and their concentrations are the dominant processing factors in controlling the size, morphology, and composition of the resulting products.

Electrooxidation of methanol on carbon nanotubes supported Pt-Fe alloy electrode

The synthesis and characterization of catalysts based on bimetallic materials, Pt-Fe supported on multi-walled carbon nanotubes (MWNTs) for methanol electrooxidation is reported here. The catalyst was prepared by a spray-cooling process and characterized by TEM, EDS, ICP and XRD. The electrocatalytic properties of the Pt-Fe/MWNTs electrode for methanol oxidation have been investigated by cyclic voltammetry and chronoamperometry. It presented higher electrocatalytic activity and stability than a comparative Pt/ MWNTs catalyst. This may be attributed to the addition of Fe which leads to the small average particle size and high utilization of Pt in the Pt-Fe/MWNTs catalyst. The results imply that the Pt Fe/MWNTs composite has good potential applications in fuel cells.

Characterization of FeNi3 alloy in Fe-Ni-O system synthesized by citric acid combustion method

Fe-Ni-O samples, with Fe/Ni ratio ranging from 2 to 1/3, were synthesized. Samples synthesized with and without citric acid in the precursor were compared and it was found that the addition of citric acid is the necessary condition for FeNi3 formation; it was found that FeNi3 alloys were formed in these samples even when calcined in an air atmosphere. X-ray diffraction and X-ray photoelectron spectroscopy measurements were used to characterize the samples. Because of the existence of FeNi3 alloys, Fe-Ni-O samples showed strong reactivity to NO and NO + O-2 but were inert to O-2 alone.

Studies of interaction between iron (III) and intermediates of synthetic neuromelanin by means of cyclic voltammetry of Fe(CN)(3-)(6) and dopamine

Neuromelanin is a complex polymer pigment found primarily in the dopaminergic neurons of the human substantia nigra, whose composition is complex including production of dopamine auto-oxidation, glutathione and a variety of amino acid. Neuromelanin forms stable complex with iron (111). We observed that 5,6-dihydroxyindole and its ramification possessed strong ability of chelating iron (111), and they are the production of dopamine auto-oxidation under physiological pH condition. In the present Of L-Cysteine, the relative yields of electrochemical oxidation of dopamine also had strong ability of chelating iron (111). The experimental results suggest that 5,6-dihydroxyindole and 5-S-cysteineldopamine play important roles in the process of synthetic neuromelanin chelating iron (111).

Fe(2-EHA)(3)/Al(i-Bu)(3)/hydrogen phosphite catalyst for preparing syndiotactic 1,2-polybutadiene

Polymerizing 1,3-butadiene into syndiotactic 1,2-polybutadiene with art iron(III) catalyst system has been investigated. Activity of the catalyst was affected by the type of cocatalyst alkylaluminum and the phosphorus compound as an electron donor, molar ratio of catalyst components, and their aging sequence and aging time of the catalyst. The microstructure and configuration of the polymer was decided by the catalyst components, the higher [Al]/[Fe] molar ratio tending to yield syndiotactic 1,2-polybutadiene, while the higher [P]/[Fe] molar ratio favors the formation of amorphous 1,2-polybutadiene.

填充油的种类对Fe系1,2-聚丁二烯性能的影响

研究了芳烃油和环烷烃油对充油铁系1,2-聚丁二烯橡胶性能的影响。结果表明,基础胶充油后门尼粘度值下降,可塑性增加,混炼行为变佳;填充芳烃油比填充环烷烃油的橡胶在拉伸强度、撕裂强度、伸长率和生胶门尼值等方面均有所提高;充油后虽然硫化胶硬度降低,但是生热和耐磨性能提高。填充芳烃油可适当提高硫化胶的抗湿滑性,但滚动阻力也升高。环烷烃油可降低硫化胶的滚动阻力。充油可适当改善胶料的抗老化性能。

Determination of ultra-trace concentrations of elements in high purity tellurium by inductively coupled plasma mass spectrometry after Fe(OH)(3) coprecipitation

In this work, a method was established for the determination of impurities in high purity tellurium by inductively coupled plasma mass spectrometry (ICP-MS) after Fe(OH)(3) coprecipitation. After comparison of coprecipitation ability and separation efficiency between Fe(OH), and Al(OH)(3), Fe(OH)(3) was chosen as the precipitate. A separation factor of 160 for 200 mg tellurium was obtained under conditions of pH 9 and 2 mg of Fe3(+). The 13 elements, such as Bi, Sn, Pb, In, Tl, Cd, Cu, Co, Ni, Zn, Ti, Be and Zr, could be almost completely coprecipitated under these conditions. In addition, Te memory effect imposed on the ICP-MS instrument was assessed, as well as Te matrix effect that caused the low recovery of Ga, As, Sb and V in real sample was discussed. Finally, the method was evaluated through recovery test and was applied to practical sample analysis, with detection limits of most of the elements being below 0.15 mug g(-1) and R.S.D. below or at approximately 10%, which indicated that this method could fully satisfy the requirements for analysis of 99.999% similar to 99.9999% high purity Te.

Fe改性工业Cu/Zn/Al催化剂甲醇水蒸气重整反应制氢的研究

中国科学院山西煤炭化学研究所

Fe在丝光沸石骨架中取代位置的DFT研究

中国科学院山西煤炭化学研究所