辽河盆地西部凹陷深部流体的地球化学特征与成藏效应

The main research area of this thesis is the Western Depression in the Liaohe Basin. Based on the drilling core observation and mud logging data, the features of the mantle–derived fluids and their effects on oil/gas generation in the Western Depression of the Liaohe Basin,was studied with comprehensive methods of volcanic petrology, sediment petrology, fluid geochemistry, sedimentlogy, and structural geology, and use of polarized light microscope, fluorescence microscope, electron microscope, fluid and melt inclusion test, and isotopic test of nature gas etc. The observation of drill cores in study area and other studies reveal that the main passageway of the volcanic eruption in the Cenozoic was the Xibaqian-Gaosheng fault, and the volcanic rocks of each stage were distributed around it. Mantle-derived fluid which affected on oil/gas generation formed later than the volcanic spew and those fluids entered into the depression through the Taian-Dawa fault and the Central fault. The volatile fraction analysis of the melt inclusion reveals the presence of two kinds of mantle fluids; they are hydrogen-rich fluid and carbon dioxide-rich fluid. These the two kinds of fluids were mainly distributed in olivine and pyroxene respectively. The hydrothermal veins development have multiple stages, from high temperature quartz vein to low temperature calcite vein and analcime vein, in which the fluid inclusion extremity component are methane and carbon dioxide, which indicate that when mantle-derived fluids ascended and entered into the basin, most of these fluids interacted with the organic matter in the basin even though some of these entered into atmosphere. The present isotopic test of the nature gas reveals the high 3He/4He value between the region of the Taian-Dawa fault and the Central fault, which also imply the feature of origin in mantle. This phenomenon indicates that the Mesozoic basement faults and the main Cenozoic faults had connected crust and the mantle during the basin evolution, so the mantle derived fluids could enter the basin along those faults. The main source rocks of the ES3 and ES4 members of the Shahejie Formation began to expel hydrocarbon at the end period of the ES1 member of the Shahejie Formation, and reached its peak during the period of the Dongying Formation deposition. During these periods, the mantle derived-fluids entered the basin constantly along the main faults, and supplied lots of hydrogen for hydrocarbon generation. Though the volcanic rocks and the mantle-derived fluids in the Eastern Depression were more developed than in the Western Depression, the source rocks and the deep fluids were not interacted better than the Western Depression because of the affection of structural evolution. In the Eocene, the Eastern Depression did not deposit the ES4 member of the Shahejie Formation, furthermore, the mantle-fluid formed in the Fangshengpao stage escaped to the atmosphere, which confined the later stage hydrocarbon generation capability.

海底金属矿床充水条件及矿坑突水的断层效应研究

The Xinli mine area of Sanshandao mine is adjacent to the Bohai Sea and its main exploitable ore deposit occurs in the undersea rock mass. The mine is the biggest undersea gold mine of China after production. The mine area faces a latent danger of water bursting, even sudden seawater inrush. There is no mature experience in undersea mining in China so far. The vein ore deposit is located in the lower wall of a fault; its possible groundwater sources mainly include bittern, Quaternary pore water and modern seawater. To ensure the safety of undersea mining, to survey the flooding conditions of the ore deposit using proper measures and study the potential seawater inrush pattern are the key technical problems. With the Xinli mine area as a case study, the engineering geological conditions of the Xinli mine area are surveyed in situ, the regional structural pattern and rock mass framework characteristics are found out, the distribution of the structural planes are modeled by a Monte Carlo method and the connectivity coefficients of rock mass structural planes are calculated. The regional hydro-geological conditions are analyzed and the in-situ hydro-geological investigation and sampling are performed in detail, the hydrochemistry and isotopes testing and groundwater dynamic monitoring are conducted, the recharge, runoff, discharge conditions are specified and the sources of flooding are distinguished. Some indices are selected from the testing results to calculate the proportion of each source in some water discharge points and in the whole water discharge of the Xinli mine area. The temporal and spatial variations of each water source of the whole ore deposit flooding are analyzed. According to the special project conditions in the Xinli mine area, the permeability coefficient tensors of the rock mass in Xinli mine area are calculated based on a fracture geometry measurement method, in terms of the connectivity and a few hydraulic testing results, a modified synthetic permeability coefficient are calculated. The hydro-geological conceptual and mathematical model are established，the water yield of mine is predicted using Visual Modflow code. The spreading law of surrounding rock mass deformation and secondary stress are studied by numerical analysis; the intrinsic mechanism of the faults slip caused by the excavation of ore deposit is analyzed. The results show that the development of surrounding rock mass deformation and secondary stress of vein ore deposit in the lower wall of a fault, is different from that in a thick-big ore deposit. The secondary stress caused by the excavation of vein ore deposit in the lower wall of a fault, is mainly distributed in the upper wall of the fault, one surface subsidence center will occur. The influences of fault on the rock mass movement, secondary stress and hydro-geological structures are analyzed; the secondary stress is blocked by the fault and the tensile stress concentration occurs in the rock mass near the fault, the original water blocking structure is destructed and the permeable structure is reconstructed, the primary structural planes begin to expand and newborn fissures occur, so the permeability of the original permeable structure is greatly enhanced, so the water bursting will probably occur. Based on this knowledge, the possible water inrush pattern and position of the Xinli mine area are predicted. Some computer programs are developed using object-oriented design method under the development platform Visual Studio.Net. These programs include a Monte Carlo simulation procedure, a joint diagrammatizing procedure, a structural planes connectivity coefficient calculating procedure, a permeability tensor calculating procedure, a water chemical formula edit and water source fixture conditions calculating procedure. A new computer mapping algorithm of joint iso-density diagram is raised. Based on the powerful spatial data management and icon functions of Geographic Information System, the pit water discharge dynamic monitoring data management information systems are established with ArcView.

内蒙古白云鄂博超大型REE-Nb-Fe矿床脉状矿化时代与成矿流体特征

Bayan Obo REE-Nb-Fe ore deposit is the largest REE deposit in the world. Owing to its unique type and tremendous economic value, this deposit has widely attracted interests from geological researchers and vast amount of scientific data have been accumulated. However, its genesis, especially ore-forming age and REE sources, have been under dispute for a long time. On the basis of previous research works, this paper mainly conducts studies on the Early Paleozoic ore-forming event in the Bayan Obo deposit. The following results and conclusions can be suggested: Sm-Nd isotopic analytical results of bastnaesite, beloeilite, albite and fluorite samples from a coarse-crystalline ore lode present an isochron age of 436±35Ma. Besides, Rb-Sr isotope dating of the coarse-crystalline biotite lode that intruded into banded ores gives an isochron age of 459±39Ma. The two ages verify the exist of Early Paleozoic ore-forming event at Bayan Obo, which characterized by extensive netted mineralization of REE fluorocarbonates, aeschynite and monazite, accompanied by widely fluorite-riebeckite-aegirine-apatite alteration. Sr-Nd isotope composition of vein minerals is located between EMI and ancient lower crust component in the ISr(t)-εNd(t) correlation diagram, indicating that there is a crustal contamination during veined mineralization. A large area late Paleozoic granitoids are distributed in the southeast region of east open pit of the mine. The granitoids intruded directly into the ore-bearing dolomite, and produced intense skarnization. Moreover, at 650-660m of the drill core on 22 line and 1598m level flat in the south of East Open Pit, we firstly found skarnization rocks. Single grain and low background Rb-Sr isochrone dating on phlogopite in skarn gives 309±12Ma. Considering the intruded contacting relationship, the late Paleozoic granitoids, already extended to the under part of REE ore bodies, must be posterior to the latest intense REE mineralization, and is only a destructive tectonic and magmatic activity. Fluid inclusion types of fluorite in the Bayan Obo deposit consist of multiphase daughter mineral-bearing inclusion, two or three phase CO2-bearing inclusion and two phase aqueous inclusion. Petrography, laser Raman analysis and microthermometry study indicate that the fluids involving in REE-Nb-Fe mineralization at Bayan Obo might be mainly of H2O-CO2-NaCl-(F-REE) system. The presence of REE-carbonate as a daughter mineral in fluid inclusions shows that the original ore-forming fluids are rich in REE elements.

班公湖带多不杂超大型富金斑岩铜矿床的成岩成矿年代学、岩石学及高氧化岩浆¬流体-成矿作用

Duobuza copper deposit, newly discovered typical gold-rich porphyry copper deposit with superlarge potential, is located in the Tiegelong Mesozoic tectonic -magmatic arc of the southern edge of Qiangtang block and the northern margin of Bangonghu-Nujiang suture. Quartz diorite porphyrite and grandiorite porphyry, occurred in stock, are the main ore-bearing porphyries. As the emplacement of porphyry stock, a wide range of hydrothermal alteration has developed. Within the framework of the ore district, abundant hydrothermal magnetite developed, and the relationship between precipitation of copper and gold and hydrothermal magnetite seems much close. Correspondingly, a series of veinlets and network veinlets occurred in all alteration zones. Therefore, systematic research on such a superlarge high-grade Duobuza gold-rich porphyry copper deposit can fully revealed the metallogenic characteristics of gold-rich porphyry copper deposits in this region, establish metallogenetic model and prospecting criteria, and has important practical significance on the promotion of regional exploration. In addition, this research on it can enrich metallogenic theory of strong oxidation magma-fluid to gold-rich porphyry copper deposit, and will be helpful to understand the metallogenic characteristics in early of subduction of Gangdese arc stages and its entire evolution history of the Qinghai-Tibet Plateau, the temporal and spatial distribution of ore deposits and their geodynamics settings. Northern ore body of Duobuza copper deposit have been controlled with width (north-south) about 100 ~ 400 m, length (east-west) about 1400 m, dip of 200 °, angle of dip 65 °~ 80 °. And controlled resource amount is of 2.7 million tons Cu with grade 0.94% and 13 tons Au with 0.21g/tAu. Overall features of ore body are large scale, higher grade copper, gold-rich. Ore occurred in the body of granodiotite porphyry and quartz diorite porphyrite and its contact zone with wall rock. Through the detailed mapping and field work studies, some typies of alteration are identificated as follows: albitization, biotititation, sericitization, silication, epidotization, chloritization, carbonatization, illitization, kaolinization and so on. The range of alteration is more than 10km2. Wall alteration zone can be divided into potassic alteration, moderate argillization alteration, argillization, illite-hydromuscovite or propylitization from ore-bearing porphyry center outwards, but phyllic alteration has not well developed and only sericite-quartz veins occurred in local area. Moreover, micro-fracture is development in ore district , and correspondingly a series of veinlets are development as follows: biotite vein (EB type), K-feldspar-biotite-chalcopyrite-quartz vein, magnetite-antinolite-K-feldspar vein, quartz-chalcopyrite-magnetite veins (A-type), quartz-magnetite-biotite-K-feldspar vein, chalcopyrite veinlets in potassic alteration zone; (2) chalcopyrite occurring in the center vein–quartz vein (B type), chalcopyrite veinlets, chalcopyrite-gypsum vein in intermediate argillization alteration; (3) chalcopyrite- pyrite-quartz vein, pyrite-quartz vein, chalcopyrite-gypsum veins, quartz-gypsum- molybdenite-chalcopyrite vein in argillization alteration; (4) gypsum veins, quartz-(molybdenite)-chalcopyrite vein, quartz-pyrite vein, gypsum- chalcopyrite vein, potassium feldspar veinlets, Carbonate veins, quartz-magnetite veins in the wall rock. In short, various veins are very abundant within the framework of the ore district. The results of electronic probe microscopy analysis (EMPA) indicate that Albite (Ab 91.5~99.7%) occurred along the rim of plagioclase phenocryst and fracture, and respresents the earliest stages of alteration. K-feldspar (Or 75.1~96.9%) altered plagioclase phenocryst and matrix or formed secondary potassium feldspar veinlets. Secondary biotite occurred mainly in phenocryst, matrix and veinlets, belong to magnesium-rich biotite formed under the conditions of high-oxidation magma- hydrothermal. Chloritization developed in all alteration zones and alterd iron- magnesium minerals such as biotite and hornblende and then formed chlorite veinlets. As the temperature rises, Si in the tetrahedral site of chlorite decreased, and chlorite component evolved from diabantite to ripiolite. The consistent 280℃~360℃ of formation temperature hinted that chlorite formed on the same temperature range in all alteration zones. However, formation temperature range of chlorite from the gypsum-carbonate-chlorite vein was 190℃~220℃, and it may be the product of the latest stage of hydrothermal activity. The closely relationship between biotite and rutile indicate that most of rutiles are precipitated in the process of biotite alteration and recrystallization. In addition, the V2O3 concentration of rutile from ore body in Duobuza gold-rich porphyry copper deposit is >0.4％, indicate that V concentration in rutile has important significance on marking main ore body of porphyry copper deposit. Apatites from Duobuza deposit all are F-rich. And apatite in the wall rock contained low MnO content and relatively high FeO content, which may due to the basaltic composition of the wall rocks. The MnO in apatite from altered porphyry show a strong positive correlation with FeO. In addition, Cl/F ratio of apatite from wall rock was highest, followed by the potassic alteration zone and potassic alteration zone overprinted by moderate argillization alteration was the lowest. SO2 in Apatite are in the scope of 0 to 0.66%, biotite in the apatite has the highest SO2, followed by the potassic alteration zone, potassic alteration zone overprinted by moderate argillization alteration, and the lowest in the surrounding rocks, which may be caused by the decrease of oxygen fugacity of hydrothermal fluid and S exhaust by sulfide precipitation in potassic alteration. Magnetite in the wall rock have higher Cr2O3 and lower Al2O3 features compared with altered porphyry, this may be due to basalt wall rock generally has high Cr content. And magnetites have higher TiO2 content in potassic alteration than moderate argillization alteration overprinted by potassic alteration, argillization and wall rock, suggested that its formation temperature in potassic alteration was the highest among them. The ore minerals mainly are chalcopyrite and bornite, and Au contents of chalcopyrite, bornite, and pyrite are similar with chalcopyrite slightly higher. The Eu* negative anomaly of disseminated chalcopyrite was relatively lower than chalcopyrite in veinlets. Within a drill hole, the Eu* negative anomaly of disseminated chalcopyrite was gradually larger from bottom to top. Magnetite has the same distribution model, with obvious negative Eu* abnormal, and ΣREE in great changes. The gypsum has the highest ΣREE content and the obvious negative anomaly, and biotite obviously has the Eu* abnormal. Based on the petrographic and geochemical characteristics, five series of magmatic rocks can be broadly classified; they are volcanic rocks of the normal island arc, high-Nb basaltic rocks, adakites, altered porphyry and diorite. The Sr, Nd, Hf isotopes and geochemistry of various series of magmatic rock show that they may be the result of mixing between basic magma and various degrees of acid magma coming from lower crust melted by high temperature basic underplating from partial melting of the subduction sediment melt metasomatic mantle wedge. Furthermore S isotope and Pb isotope of the sulfide, ore-bearing porphyries and volcanic rocks indicated ore-forming source is the mantle wedge metasomatied by subduction sediment melt. Oxygen fugacity of magma estimated by Fe2O3/FeO of whole rock and zircon Ce4+/Ce3+ indicated that the oxidation of basalt-andesitic rocks is higher than ore-forming porphyry, and might imply high-oxidation characteristics of underplated basic magma. Its high oxidative mechanism is likely mantle sources metasomatied by subduction sediment magma, including water and Fe3+. And such high oxidation of basaltic magma is conducive to the mantle of sulfides in the effective access to melt. And the An component of dark part within plagioclase phenocryst zoning belong to bytownite (An 74%), and its may be a result of magma composition changes refreshment by basaltic magma injection. SHRIMP zircon U-Pb and LA-ICP-MS zircon U-Pb geochronology study showed that the intrusions and volcanic rocks from Duobuza porphyry copper deposit belong to early Cretaceous magma series (126~105Ma). The magma evolution series are as follows: the earliest diorite and diorite porphyrite → ore-bearing porphyry and barren grandiorite porphyry →basaltic andesite → diorite porphyrite → andesite → basaltic andesite, and magma component shows a evolution trend from intermediate to intermediate-acid to basic. Based on the field evidences, the formation age of high-Nb basalt may be the latest. The Ar-Ar geochronology of altered secondary biotite, K-feldspar and sericite shows that the main mineralization lasting a interval of about 4 Ma, the duration limit of whole magma-hydrothermal evolution of about 6 Ma, and possibly such a long duration limit may result in the formation of Duobuza super-large copper deposit. Moreover, tectonic diagram and trace element geochemistry of volcanic rocks and diorite from Duobuza porphyry copper deposit confirm that it formed in a continental margin arc environment. Zircon U-Pb age of volcanic rocks and porphyry fall in the range of 105~121Ma, and Duobuza porphyry copper deposit locating in the north of the Bangonghu- Nujiang suture zone, suggested that Neo-Tethys ocean still subducted northward at least early Cretaceous, and its closure time should be later than 105 Ma. Three major inclusion types and ten subtypes are distinguished from quartz phenocrysts and various quartz veins. Vapor generally coexisting with brine inclusions, suggest that fluid boiling may be the main ore-forming mechanism. Raman spectrums of fluid inclusions display that the content of vapor and liquid inclusion mainly contain water, and vapor occasionally contain a little CO2. In addition, the component of liquid inclusions mainly include Cl-, SO42-, Na+, K+, a small amount of Ca2+, F-; and Cl- and Na+ show good correlation. Vapor mainly contains water, a small amount of CO2, CH4 and C2H6 and so on. The daughter minerals identified by Laman spectroscopy and SEM include gypsum, chalcopyrite, halite, sylvite, rutile, potassium feldspar, Fe-Mn-chloride and other minerals, and ore-forming fluid belong to a complex hydrothermal system containing H2O-NaCl-KClFeCl2CaCl2. H and O isotopic analysis of quartz phenocryst, vein quartz, magnetite, chlorite and gypsum from all alteration zones show that the ore-forming fluid of Duobuza gold-rich porphyry copper deposit consisted mainly of magmatic water, without addition of meteric water. Duobuza gold-rich porphyry copper deposit formed by the primary magmatic fluid (600-950C), which has high oxidation, ultra-high salinity and metallogenic element-rich, exsolution direct from the magma, and it is representative of the typical orthomagmatic end member of the porphyry continuum. Moreover, the fluid evolution model of Duobuza gold-rich porphyry copper deposit has been established. Furthermore, two key factors for formation of large Au-rich porphyry copper deposit have been summed up, which are ore-forming fluids earlier separated from magma and high oxidation magma-mineralization fluid system.

内蒙古龙头山Ag-Pb-Zn多金属矿床成矿模式及找矿模型

The recent years research indicated that middle-south section of Da Hinggan Mountains metallogenic belt has two periods(Hercynian and Yanshanian) characteristics of metallogenesis, as well as the most of ore deposits in the area closely relate to Permian strata. Longtoushan ore deposit discovered in 2004 is an Ag-Pb-Zn polymetallic ore deposit born in Permian and located in the east hillside of the metallogenic belt, which has considerable resources potentials. It has important research value for its good metallogenic location and blank research history. Base on the detail field geology studies, the geology characteristics of "two stages and three kinds of metallogensis" has established. According to further work through geochemistry research including trace element, REE, S, Pb and Sr isotope, as well as petrography, microtemperature measurement, Laser Raman analysis and thermodynamics calculation of fluid inclusion, origin and characteristic of the ore-forming material and fluid has been discussed. And a new technology of single pellet Rb-Sr isochrones has been tried for dating its born time. Bae on above work, study of ore deposit comparison has been carried out, and metallogesis controlling factor and geological prospecting symbol have been summarized. Finally, metallogenic model and prospecting model have been established. According to above, the next step work direction has been proposed. Main achievement of the paper are listed as follow: 1.Longtoushan ore deposit has experienced two metallogenic periods including hot-water sedimentation period and hydrothermal reformation period. There are three kinds of metallizing phase: bedded(or near-bedded) phase, vein-shaped phase and pipe-shaped phase. The mian metallogenic period is hot-water sedimentation period. 2.Ore deposit geochemistry research indicated that the metal sulfides have charcateristic of hot-water sedimentation metallogensis, but generally suffered later hydrothermal transformation. The barite mineral isotope content is homogenous, showing the seabed hot-water sedimentation origin characteristic. Wall rock, such as tuff is one of metallogenic material origins. Both of Pb model age and Rb-Sr isochrone research older age value than that of strata, possibly for been influenced by hydrothermal transformation, and interfusion of ancient basis material. 3.There are two kinds of main metallogenic fluid inclusion in barite of the Longtoushan ore deposit, which are rich gas phase( C type) and liquid phase (D type). Their size is 2～7um, and principal components is H2O. Both kinds of fluid inclusion have freezing point temperature -7.1～-2.4℃ and -5.5～-0.3℃, salinity 4.0～10.6wt% and 0.5～8.5wt%, homogeneous temperature 176.8～361.6℃ and 101.4～279.9℃, which peak value around 270℃ and 170℃, respectively. Density of the ore-forming fluid is 0.73～0.97g/cm3, and metallogenic pressure is 62.3×105～377.9×105Pa. Above characteristic of the fluid inclusion are well geared to that of ore deposit originated in seabed hot-water sedimentation. 4.Through the comparison research, that Longtoushan ore deposit has main characteristic of hot-water sedimentation ore deposit has been indicated. Ore-forming control factor and prospecting symbol of it has been summarized, as well as metallogenic model and prospecting model. Next step work direction about prospecting has also been proposed finally.

胶东蓬家夼式金矿床矿床成因模型与找矿模型研究

The dynamic environments of mineralization in Mesozoic Jiaodong gold mine concentrated area can be devided into two types, compressive environment which related to intracontinental collision and extensional environment which related to intracontinental volcanic rift. The altered rock type (Jiaojia type) and quartz vein type (Linglong type) which related to the former one, were discovered for several years, and became the main types of gold deposits in recent years. A new type gold deposit, syn-detachment altered tectonic breccia type gold deposit, such as Pengjiakuang gold deposit and Songjiagou gold deposit has been discovered on the northeastern margin of Jiaolai Basin. In this paper, the new type of gold deposit has been studied in detail. The study area is located at the northeastern boundaries of Jiaolai Basin, and between the Taocun-Jimo Fault and Wji-Haiyang Fault, in the eastern part of the Jiaodong Block. Pengjiakuang gold deposit and Songjiagou gold deposit occur in a arc-shape detachment fault zone between conglomerate of Lower Cretaceous Laiyang Formation and metamorphic complex of Lower Proterozoic Jingshan Group. Regional geological studies show that Kunyuanshan and Queshan granite intrusions and Qingshanian volcanism were formed in different period of lithospheric thinning of East China in Mesozoic. Granite intrusions were formed in compressive environment, while Qingshanian volcanism were formed in extensional environment. They are all related to the detachment of Sulu Orogenic Belt and the sinistral motion of Tanlu Fault. The Pengjiakuang detachment systems which were formed in the the sinistral motion of Tanlu Fault are the important ore-controlling and ore-containing structure. The Pengjiakuang type gold deposit, controlled by detachment structure, was formed before Yanshanian volcanic period concerning with mixture of meteoric water and magmatic water found in fluid inclusions of gold ores. The minerogenetic epoch has been proposed in 90～120Ma. the host rocks have been extensively subjected to pyritization, silicification, sericitization and carbonatization. Individual ore-body has maximum length of 800m, oblique extension of 500～700m and gold grade of 1～43 * 10~(-6). Native gold is disseminated in silicified, phyllic or carbonatized tectonic breccia. Sulfur, carbon and lead isotope studies on gold ores and wall rocks show that the sulfur come from the metamorphic complex of Lower Proterozoic Jingshan Group, carbon comes from the marble in Jingshan Group, while a part of lead comes from the mantle. The mineralizing fluid is rich in Na~+ and Cl~-, but relatively impoverished in K~+ and F~-. According to the date from hydrogen and oxygen isotopic compositions (δ~(18)OH_2O = 0.59%～4.03%, δDH_2O = -89.5%～97.9%), the conclusion can be reached that the mineralizing fluid of Pengjiakuang gold deposit was a kind of mixed hydrothermal solution which was mainly composed of meteoric water and magmatic water. A genetical model has been formulated. Some apparent anomaly features which show low in the central part and high in the both sides corresponding to the gold-bearing structure, were sum up after analying a vast amount of date by prospecting the orebodies using gamma-ray spectrometer, electrogeochemical parameter technique, controlled source audio magnetic telluric (CSAMT) and shallow surface thermometry in Pengjiakuang gold deposit. The location forecasting problem of buried orebodies has been solved according to these features, and the successful rate is very high in well-drilling. The structural geological-geophysical-geochemical prospecting model has been formulated on the base of the study of geological, geophysical and geochemical characteristics of Pengjiakuang type gold deposit, and the optimum combinational process of geophysical and geochemical prospecting techniques has been summed up. A comparative study shows that the Pengjiakuang type gold deposit, the syn-detachment altered tectonic breccia type gold deposit, is different from Jiaojia type gold deposits and Linglong type gold deposits, in Jiaodong Block. In general, if formed under an extensional tectonic condition and located at detachment fault zone along the margin of Mesozoic Jiaolai basin, and the gold mineralization has also close genetic relationship with alkaline magamtism. Being a new type of gold deposit in Jiaodong gold mine concentrated area, it could be potential to explore in the same regions which processed the same ore-forming geological conditions and mineralization informations.

渭南地区末次冰期以来的蜗牛化石记录及古气候古环境研究

In this study, 172 mollusk assemblages from the Weinan loess section in the southeast of Loess Plateau, China, were identified quantitatively at relative high resolution. The results show: 1) the history and processes of paleoclimatic and paleoenvironmental changes in Weinan since the last 70 ka; 2) the characteristics of climatic changes during the period of the last glacial maximum (LGM); 3) the spatial pattern of paleoclimate variations at the south and middle parts of the Loess Plateau during the LGM period; 4) the timing of the last deglaciation and the return event of rapid climate change during the last deglaciation. The main conclusions are as follows: 1) 172 mollusk samples taken from the uppermost 9 m deposits cover the past 70 ka, which were sampled at the internals of 5 cm for S_0, 3 cm for L_(1-1) and L_(1-2), and 10 cm for L_(1-3), L_(1-4) and L_(1-5). Author analyzed quantitatively all individuals including broken pieces of snail shells, percentages of 15 species identified from 172 samples. Three main groups were determined according to the ecological requirement of each taxon. Based on the variations of three ecological groups and typical ecological species, The author intended to reconstruct the history of and processes of climate and environment since the last 70 ka in the Weinan region. The climate and environment in this region experienced the following changes: relative warm and humid stage from 67.5-20.3 cal. ka B.P., a period of forest-steppe or steppe developed; cold and arid stage from 20.3-15.5 cal. ka B.P., a dry steppe period, later wetter and colder; cold and humid period once time from 15.5 to 12.3 cal. ka B.P., a typical steppe or forest-steppe stage; cold and humid again from 12.3 cal. ka B.P. to 8.2 cal. ka B.P., a tropical steppe stage; warm and humid climate, a forest-steppe developed. 2) The climate during the period of the last glacial maximum (LGM) in Weinan was characterized by a general cold-humid condition, represented by occurrence of a number of the cool-humidiphilous mollusk species such as Gastocopta amigerella and Vallonia cf. pulchella in the section. 3) Comparison of the variations in abundance of Puncture orphana at Weinan with those at Luochuan and Changwu sections suggests that the summer monsoon intensity influenced differently at the three regions during the LGM period. The Weinan was weaker summer monsoon impact during all the period, the Luochuan was influenced occasionally, and Changwu was only a very short time affected, which indicated it might be located at the western margin of the summer monsoon influence during that period. 4) The ratio of thermo-humidiphilous mollusk group to cold-aridiphilous one shows an increase tendency at about 15 cal. ka B.P., reflecting the climate warming after the deglaciation in Weinan, which is approximately corresponding to the timing of warming period of the last deglaciation, found in the East Atlantic Ocean, the South China Sea and the Loess Plateau (indicated by the phytolith study). 5) A remarkable decrease in the number of thermo-humidiphilous and cool-humidiphilous mollusk species from 12.7 - 11.6 cal. ka B.P. indicates a cooling in climate and might be the reflection of the Younger Dryas event in Weinan. 6) Variations in the ratios of thermo-humidiphilous mollusk species to cold-aridiphilous ones reflect the climate instability in Holocene. There were four warm-humid periods (10-8.1 cal. ka B.P., 6.9-6.1 cal. ka B.P., 5.2-2.6cal. ka B.P., 1.6cal. ka B.P. to the present ) and three relative cold-arid periods (8.1-6.9 cal. ka B.P., 6.1-5.2 cal. ka B.P., 2.6-1.6 cal. ka B.P.), showing about a 1,000 year climatic oscillation.

山西堡子湾金矿角砾岩带控矿规律、成矿时代及隐伏矿体定位预测

The Puziwan gold deposit is located at the northern boundary of the North China platform where there are very favorable ore-forming conditions. The deposit is a medium-sized gold deposit associated with silver and copper polymetallic minerallization which were closely related to cryptoexplosive processes and fluidization and underwent multi-epoch superposition of mineralization. The mineralization consists of cryptoexplosive breccia-type, fluidizing-type, porphyry-type, quartz vein-type, etc. The ore-controlling law of ore-bearing brecciated zone is systematically studied in the paper. The shape, scale and attitude of ore bodies are dominat in the upper, the ore bodies of fluidizing breccia-type are dominant in the upper and the middle part, the porphyry-type ore bodies are dominant in the bottom. The quartz vein-type ore bodies are impenetrated in all the brecciated zone. The metallogenic epoch of Puziwan gold deposit is collated and stipulated. The Rb-Sr isochron age of quartz porphyry (wall rock) is 233 Ma, refering to the Ar-Ar age of gold-bearing quartz, excluded the former conclusion that the so-called metallogenic epoch (245.9Ma) is in Indosinian epoch. The nonage metallogenic age of Buziwan gold deposit shoule be in the Yanshanian epoch (142.5Ma). By applying the sub-specimen sampling technique, the Rb-Sr isochron age of gold-bearing pyrites in late mineralization epoch is dated to be 64 Ma. In conclusion, the metallogenetic epoch of Puziwan gold deposit is in late Yanshanian-early Himalayan epoch. On the above basis, the metallogenic model of the "train type" and new texture model of ore deposit are established. by applying the methods of geology, shallow seismic exploration, remote sensing, partial geochemical extraction and the study of inclusions in the late granite porphyry, the author has made the metallogenic progosis in the depth and the prephery of Puziwan gold deposit and eight prospecting targets are proposed.

胶东地区三类金矿成矿系统地质地球化学及动力学

The East Shandong gold province is located on the southeastern margin of the North China Craton and features uplift in the north and depression in the south. The uplift area is made up of the Archaean Jiaodong Group, the Proterozoic Jingshan Group and Yanshannian granites. Most gold deposits in the uplift area are spatially associated with the Yanshannian granites. Two types of gold mineralization occur in the region: the quartz-vein type hosted in the Linglong granite suite, and the shear zone type hosted by either the Linglong granite or Guojialing granitoid suites. The mineralization ages are 113～126 Ma. The southern part of East Shandong contains the Mesozoic Jiaolai basin, which formed during regional extension. The basin is bounded by the Wulian-Rongcheng fault in the southeast and the Tanlu fault in the west. The Pengjiakuang, Fayunkuang and Dazhuangzi gold deposit occurs on the northeastern margin of the basin. The mineralization ages of these deposits are 110～128 Ma. This paper focuses on a low-angle detachment fault developed between the Proterozoic Jingshan Group metamorphic complex and the northeastern margin of the basin. Our field work shows that the distribution of the Pengjiakuang gold deposit was controlled by the detachment fault. Moreover, the Fayunkuang, Guocheng and Liaoshang gold deposits also occurr in the periphery of the basin, and their features are similar to Pengjiakuang gold deposit. The study of geological geochemistry of the gold deposits has shown: ①three-type gold deposit was situated in the Jiaodong area, including altered rock type (Jiaojia type), quartz vein type (Linglong type) and breccia type (Pengjiakuang type); the ore-forming materials and fluid for Pengjiakuang type gold deposit shows multiple source; ②the ore materials of Jiaojia and Linglong type deposits are mainly from deep source. The author has studied geological-geochemical dynamics of three types deposits in Jiaodong area. The study of tectonic dynamics shows that ore-forming structure differential stress values of Pengjiakuang gold deposit is 100 * 10~6～130 * 10~6 Pa, and that of Jiaojia gold deposit is 100 * 10~5～194 * 10~6 Pa. Dynamics of hydrothermal ore-forming fluid has also been studied in this paper. Author applies Bernoulli equation to dynamic model of hydrothermal fluid motion in brittle fracture and cracks (quartz vein type gold mineralization), and applies Darcy law to dynamic model of hydro thermal fluid motion in porous medium (altered rock type gold mineralization). Author does daring try in order to study quantitativly transport mechanism of hydrothermal ore-forming fluid in this paper. The study of fluid inclusions and crystal dynamics shows that reaction system of hydrothermal ore-forming includes three types, as follows: ore-forming reaction, controlling reaction and buffer controlling reaction. They depend on each other, controlling each other, which form a organic system. Further research shown that formation of ore shoots was controlled by coincidence processes of tectonic dynamic condition and thermodynamic evolution. This paper has summaried reginoal metallogenic laws and seted up metallogenic(dynamics) models for Jiaodong gold ore belt.

山东莱州金城金矿床构造-流体成矿特征

This paper studied the metallotectonics, altered rocks, altered minerals and fluid inclusions. The conclusions are: (1)The gold deposits in Jiaodong district were formed quickly uplifted tectonic setting which was induced by the Mantle doming in Mesozoic era. (2)Both Jiaojia-type and Linglong-type gold mineralizations were formed in the same tectonic-fluid system. (3) The Ar-Ar age of the earlier stage of the gold mineralization is 114～116Ma. (4)The development of the plaiting ore-control tectonic system underwent four stagesrcounterclockwise ductile compresso-shearing, clockwise brittle tenso-shearing and counterclockwise brittle compresso-shearing and brittle normal faulting after mineralization. (5)The mineralization has five stages: quartz and k-feldspar stage, quartz and ferro-carbonate and pyrite stage, quartz and chalcopyrite stage, pyrite and sericite and quartz stage and carbonate stage, and they make up four ore-types: red ore, vein ore, mottled ore and grey ore. (6) The features of mineralizations and ore-forming fluids in different stages are different. But the ore-forming fluids are rich in Si, Fe, P_2O_5, H_2O, CO_2, SO_4~(2-), K~+, Na~+, Ca~(2+) and Cl~- in general and their salinities are from 4 to 18 NaClwt%. (7) The ore-forming fluids came mainly from the Mantle in early stage, then mainly from magma, and mainly from meteoric water in the last stage. (8) Au in the ore-forming fluid was mainly carried in the form of complex of Au and S. (9)The temperature of ore-forming fluid is from 350℃ to 120℃and its pressure is from 20MPa to 38MPa. (10)The gold vein composed by quartz, ferro-carbonate, chalcopyrite and pyrite (vein ore) was filled in the tensional fracture in the top of the magma dome. The disseminated ore bodies composed by pyrite, sericite and quartz (grey ore) was metasomatized in the shearing fault which developed along the contact zone between Linglong intrusive body and Jiaodong Group, which is placed in the flank top of magma dome. In the joint and fracture induced by the shearing fault which developed along the contact zone between Linglong intrusive body and Jiaodong Group, veiniet and stockwork ore (red ore) and veinlet-disseminated ore (mottled ore) composed by quartz and pyrite was formed. (ll)Fluid boiling maybe one of the form of the ore-forming substances precipitation.

河北寿王坟铜矿成矿定年及同位素地球化学特征

Samples from carbonate wall-rocks, skarn, ore of skarn type, later calcite vein, and ore of porphyry type in Shouwangfen copper deposit district were collected. Systematic study was carried out on carbon, oxygen, rubidium, strontium and sulfur isotope compositions of carbonates and sulfides in these samples. The first Isochron dating by the Rb-Sr isotopes in chalcopyrite of ore sub-sample was done as well. The following conclusions were obtained. The age (113.6±4.3Ma), obtained by Rb-Sr isotope isochron dating of chalcopyrite and pyrite from sub-sample of skarn ores, probably represents the true mineralization age of skarn ores. That demonstrates the genetic relationship between granodiorite in Shouwangfen complex and skarn copper ores. On the other hand, the Rb-Sr isochron age (73±15Ma) of chalcopyrite from porphyry ores is a little incredible because of bad synthesizing evaluation. But combined with other age data of igneous rocks, it implies the possibility of hydrothermal mineralization in connection with magma activity during the fourth period of Yanshanian in Hebei Province, even in the whole northern edge of Huabei continental block. Together from structure analysis of sulfide sub-samples, from pretreating preccedure of Rb-Sr isotope isochron and its' valuating, we found out that Rb-Sr isotope isochron of sulfide sub-samples is influenced by the crystal structure of sulfides. That is, sulfide ores with very big crystals are not suitable for sub-sample isochron. Carbon, oxygen, sulfur and strontium compositions, of different minerals in these two kinds of ores, imply that the ore-forming hydrothermal fluids were probably derived from magma deep under the crust. The calcite ~(87)Sr/~(86)Sr ratios from the porphyry are consistent to the initial 87Sr/86Sr ratio of the Rb-Sr isochron of chalcopyrite and pyrite in the skarn ore, indicating that these two kinds of ores have the same source characteristic, although the porphyry deposit was formed probably 40 million years later than the skarn one according to our dating results. Skarn and skarn ores are usually considered as interaction product between carbonate wall-rocks and magmatic fluids, but the carbon of the sedimentary carbonate seems not involved in the skarn ores. Considering the connection of magmatic processes and hydrothermal ore formation in the Shouwangfen district, particularly, the spatial distribution of skarn-type and porphyry-type ores, it is possible that the Shouwangfen ore district corresponds to a hydrothermal ore-forming system, which was promoted by high-intruding magmatic rocks. Systematic stable isotopic research can help to reveal the upper part of this hydrothermal ore-forming system, which mainly related to heated and circulating meteoric water, and the lower part principally related to ascending magmatic fluids. Both skarn and porphyry ore-bodies are formed by up-intruding magmatic fluids (even more deep mantle-derived fluids).

鄂尔多斯盆地上古生界包裹体研究及天然气成藏特征分析

Based on the study of types, even temperature, the character of age-old fluid and fluid pressure of the reservoir fluid-inclusion in the Upper Paleozoic of Ordos Basin , combining with the diagenesis and character of gas geochemistry, reservoir sequence, cause of the low pressure reservoir formation and formation environment have been studied, the following knows are acquired: Abundant fluid-conclusions have developed in sandstone reservoir in Upper Paleozoic of Ordos Basin,and its kinds is numerous , also taking place some changes such as shrinking rock, cracking, stretching after formation. According to formation cause, fluid inclusion is divided into two types:successive and nonsuccessive inclusion. Nonsuccessive inclusion is further divided into brine inclusion, containing salt crystal inclusion, gaseity hydrocarbon conclusion and liquid hydrocarbon conclusion and so on. The gaseity hydrocarbon conclusion distributes at all the Basin, the liquid hydrocarbon conclusion mainly distributes at the East of Basin, and its two kinds of fluorescence color: blue and buff reflects at least two periods of oil filling and oil source of the different maturity. The study of diagenesis has indicated that five periods of diagenesis correspond to five periods inclusion's growth.The first and second period conclusions mainly distribute at the increasing margin of quartz, little amount and low even temperature, containing little gaseity hydrocarbon conclusion; The third and fourth conclusions are very rich, and having multiplicity forms, gaseity hydrocarbon conclusion of different facies, distributing at the increasing margin and crevice of quartz, its even temperature is between 85℃and 135℃;The fifth inclusion is relatively few ,mainly distributing at vein quartz and calcite, and developing few gaseity hydrocarbon conclusion. The fluid in the inclusion is mainly NaCl brine:low and high salinity brine fluid(containing salt crystal).The former salinity is between 0.18% and 18.55%,and mainly centralized distributing at three sectongs: from 0% to 4%, from 6% to 8%, from 10% to 14%, expressing that the alternation of the underground fluid was not intense, the conservation condition was good in different periods. The trapping pressure of the gaseity hydrocarbon conclusion calculated by PVTsim(V10)simulation is between 21.39 MPa and 42.58MPa,the average is 28.99MPa,mainlydistributes at between 24 MPa and 34MPa,and having a character of gradually lower from early to late time. The pressure of SuLiGe and WuShenQi dropped quickly in early time, and YuLin, ShenMu-MIZhi gas area dropped slowly in early and quickly in late time, ha portrait the change of trapping pressure can be divided into three old-age pressure systems: TaiYuan-ShanXi formation, low ShiHeZi formation and high ShiHeZi-ShiQianFeng formation. In plane, the trapping pressure dropped lowly from south to north in main reservoir period, and this reflects the gas migrating direction in the geohistory period. The analysis of gas component and monnmer hydrocarbon isotope indicates that the gas in Upper Paleozoic of Ordos Basin is coal-seam gas. The gas C_1-C_4 rnonnmer hydrocarbon isotopes has distinct differences in different stratums of different areas, and forming YuLin, SuLiGe and ShenMu-MIZhi three different distributing types. To sum up, gas reservoir combination in Upper Paleozoic of Ordos Basin can be divided into three sets of combination of reservoir formation: endogenesis type, near source type and farther source type,and near source gas combinations of reservoir formation is the main gas exploration area for its high gas filling intensity, large reservoir size.

新疆萨吾尔金矿带构造-流体地球化学及成矿作用

The Sawuer gold belt is located in the transition belt between Siberian plate and Kazakhstan-Junggar plate. Based on the geological and geochemical studies on the Kuoerzhenkuola and Buerkesidai gold deposits, in Sawuer gold mineralization belt, the time-space structure of mineralization and mineralizing factor are studied, the metallogenic regularity is concluded in thistheses. The ore bodies have the regularity that orebody are of the extensive and compressive in the sallow and depth of volcanic apparatue, respectively, and the vertical extension of orebody is more intensive than the horizontal extension. The gold deposits were controlled by the fractures of volcanic apparatus and regional faults, and featured by the hydrothermal alteration and metasomatism type disseminated mineralization and filling type vein mineralization. By virtue of the geological and geochemical studies on the two deposits that the formation of the two deposits are significantly related to the volcanic activity, we propose new ideas about their origin: (1) the two deposits are located in the same strata, and share the same genesis. (2) both of two deposits are volcanogenic late-stage hydrothermal gold deposits. Based on mapping of volcanic lithofacies and structure for the first time, it is discovered that a volcanic apparatus existed in the study area. Volcanic-intrusive activity can be divided into three cycles and nine lithofacies. where the two deposits are hosted in the same volcanic cycle, in this case, the wall-rock should belong to the same strata. The 40Ar-39Ar age method is employed in this work to analyze the fluid inclusions of quartz in the ore bodies from Kuoerzhenkuola and Buerkesidai gold deposits. The results show that the main mineralization occurred in 332.05 + 2.02-332.59 + 0.5IMa and 335.53 + 0.32Ma~336.78 + 0.50Ma for Kuoerzhenkuola and Buerkesidai gold deposits respectively, indicating that the two deposits are formed almost at the same time, and the metallogenic epoch of the tow deposits are close to those of the hosting rocks formed by volcanic activity of Sawuer gold belt. This geochronological study supplies new evidence for determining the timing of gold mineralization, the geneses of gold deposits? and identifies that in Hercynian period, the Altai developed tectonic-magmatic-hydrothermal mineralization of Early Carboniferous period, except known two metallogenic mineralization periods including tectonic-magmatic-hydrothermal mineralization of Devonian period and Late Carboniferous-Permian period respectively. The study of fluid inclusions indicates that the ore-forming fluid is a type of NaCl-HbO fluid with medium-low temperature and low salinity, Au is transported by the type of auric-sulfur complex (Au (HS)2-), the ore is formed in reduction condition. Hydrogen and oxygen isotopes of fluid inclusions in the major mineralizating stage show that the solutions mainly originated from magmatic water and meteoric water. The fluid mixing and water-rock reaction cause the deposition of Au. The helium and argon isotope compositions of fluid inclusions hosted in pyrite have been measured from Kuoerzhenkuola and Buerkesidai gold deposits in Sawuer gold belt. The results show that the ore-forming fluids of two deposits possessed the same source and is a mixture of mantle- and partial meteoric water-derived fluid, and the reliability of He and Ar isotopic compositions in Hercynian period is discussed. Isotopic studies including H, O, He, C, S, Pb and Sr reveal the same result that the ore-forming fluids of two deposits possessed the same source: the water derived mainly from magmatic water, partially from meteoric water; the mineralizers and ore materials derived mainly from mantle beneath the island arc, and partially from crust. The ore-forming fluids of two deposits are a mixture of mantle-derived fluids being incorporated by crust-derived fluid, and shallow partial meteoric water. Based on these results, it is proposed that the geneses of the two gold deposits are the same, being volcanogenic late-stage hydrothermal gold deposits that the ore-forming fluids filled in fractures of volcanic apparatus and metasomatized the host rocks in the volcanic apparatus. It is the first time we carried out the geophysical exploration, that is, the EH-4 continuous electrical conductivity image system measurement, the results show that relative large-size mineralizing anomalies in underground have been discovered.lt can confirm the law and genesis of the deposits mentioned above, and change the two abandoned mines to current large-size potenial exploration target.

贵州锦屏地区石英脉型金矿床成矿条件研究

贵州锦屏地区石英脉型金矿是黔东南金矿的典型代表，本文在前人工作的基础上，通过对锦屏花桥、八克、平秋等典型金矿区成矿地质背景、矿床地质特征、矿物共生组合、金的地球化学丰度及赋存状态等方面的归纳总结，借助构造控矿成矿模拟实验等手段，从岩性、构造方面对该类型金矿的成矿条件进行了有益的探讨，取得了以下认识： 1. 研究区位于雪峰古陆的西南部分，区内发育两条东西向相距数十公里的基底剪切断裂带，由于两条断裂带的右旋剪切作用，强化了本区北东向的构造格局。这些主要形成于加里东期的褶皱和剪切带控制着区内金矿床（点）的分布及金矿的形态、产状； 2. 区内主要地层为含有大量火山碎屑物质的前震旦系下江群。通过大量样品的含金性研究发现，平均含金量为2～15ppb，大于上地壳金的平均丰度1.8ppb，尤其是夹有火山物质的砂岩、板岩及处于褶皱轴部的岩石，其含金量更高。推断成矿物质来源可能与围岩有关； 3. 通过对该区岩（矿）石进行的构造控矿成矿模拟实验表明，区域下江群浅变质岩系在高温高压作用下，产生了各种形式的裂隙，为金的成矿提供良好的空间条件；在较好的热动力条件下，能使原来分散在岩石中的成矿物质活化、迁移和聚集在有利的容矿部位，形成工业矿床；室内的模拟实验验证了野外观察到的剪切带——褶皱——石英脉三位一体的构造控矿模式； 4. 确定黔东南锦屏地区的金矿类型为赋存在浊积岩中的石英脉型金矿，其成矿期为加里东期，并受下江群地层及背斜、断裂构造的控制；有较好的成矿前景和找矿潜力；金除以自然金形式存在外还有部分呈类质同象分散于硫化物中；围岩蚀变发育、产状突变、脉体同围岩交界处或断层泥中、不同矿体类型的交汇处等都是金富集的良好地段。上述找矿标志，在勘探、开采、及选冶过程中应予以注意；

白云鄂博超大型Fe-Nb-REE矿床碳酸盐脉状体的包裹体研究

白云鄂博矿床是世界上最大的Fe-Nb-REE矿床,其矿床成因一直是中外地质学家争论的焦点.而矿床附近的碳酸盐脉状体则成为赋矿白云岩岩浆成因的直接因素,该文拟从包裹体的角度对矿区碳酸盐脉状体进行研究,对其成因进行探讨,并对其与赋矿白云岩的关系作初步的讨论.通过对碳酸盐脉状体包裹体在包裹体类型,组合,均一温度,盐度,成分等方面的研究,发现不同区域,不同产状的碳酸盐脉状体包裹体特征存在较大的差异,这反映了其在岩石成因方面的差异:(1)都拉哈拉和尖山附近:为典型的岩浆成因;(2)宽沟背斜核部:可能是富碳酸盐盐熔体侵入构造裂隙形成的;(3)白云镇东北部(CV31,CV32)可能为侵入到混合岩中的热液脉;(4)东介勒格勒以南:具有明显的沉积特征.