202 resultados para reduce toxic Cr


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The absorption characteristic of lithium niobate crystals doped with chromium and copper (Cr and Cu) is investigated. We find that there are two apparent absorption bands for LiNbO3:Cr:Cu crystal doped with 0.14 wt.% Cr2O3 and 0.011 wt.% CuO; one is around 480 nm, and the other is around 660 nm. With a decrease in the doping composition of Cr and an increase in the doping composition of Cu, no apparent absorption band in the shorter wavelength range exists. The higher the doping level of Cr, the larger the absorbance around 660 nm. Although a 633 nm red light is located in the absorption band around 660 nm, the absorption at 633 nm does not help the photorefractive process; i.e., unlike other doubly doped crystals, for example, LiNbO3:Fe:Mn crystal, a nonvolatile holographic recording can be realized by a 633 nm red light as the recording light and a 390 nm UV light as the sensitizing light. For LiNbO3:Cr:Cu crystals, by changing the recording light from a 633 nm red light to a 514 nm green light, sensitizing with a 390 nm UV light and a 488 nm blue light, respectively, a nonvolatile holographic recording can be realized. Doping the appropriate Cr (for example, N-Cr = 2.795 X 10(25)m(-3) and N-Cr/N-Cu = 1) benefits the improvement of holographic recording properties. (c) 2005 Optical Society of America.

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研究了LiNbO3:Cr:Cu晶体的吸收特性,发现LiNbO3:Cr:Cu(含0.14wt.%Cr2O3和0.011wt.%CuO)晶体存在两个明显的吸收峰,中心波长分别位于480nm和660nm;随着Cr的含量逐渐减小,Cu的含量逐渐增大,短波段不存在明显吸收峰,掺Cr的含量越大,中心波长在660nm处的吸收越大;633nm红光虽然位于中心波长为660nm的吸收峰内,但它无助于光折变过程.分别采用390nm紫外光和488nm蓝光作为敏化光,514nm绿光作为记录光的记录方案,实现了非挥发全息记录,掺入适

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Ultrafast lasers ablation of Cr film was investigated by using double-pulse method. Experimental results show that there exists a temporal ablation window effect with each of the double pulses adjusted just smaller than the threshold. When the delay between the double pulses is within the order of 400 ps, the ablation of Cr film could happen. When the delay between the double pulses is beyond the order of 400 ps, the ablation of Cr film would not happen, and the reflectivity from the surface of the Cr film shows a sharp rise at the same time. The two-temperature model was developed into the form of double pulses to explain the experimental phenomena. Furthermore, microbump structures were formed on the surface of Cr film after ablation by ultrafast double pulses. Their heights exhibit an obvious drop between 1 and 10 ps double pulses delay, which is involved with the electron-phonon coupling process according to the numerical simulation. These results should be helpful for understanding the dynamic processes during ultrafast lasers ablation of metal films. (C) 2008 Elsevier B.V. All rights reserved.

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Cr~(2+):ZnSe具有很宽的吸收带和发射带,是中红外波段优秀的可调谐激光材料。从吸收光谱、发射光谱以及角度调谐输出对Cr~(2+):ZnSe晶体的激光输出性能进行了研究。采用真空高温扩散法制备Cr~(2+):ZnSe晶体.获得了高浓度的Cr~(2+)离子掺杂的厚1.7 mm,直径10 mm的薄片ZnSe晶体。使用中心波长2.05μm,最大输出功率8 W的Tm离子掺杂的光纤激光器抽运,使用平凹腔结构搭建谐振腔,获得了最大平均功率1.034 W,中心波长2.367μm,线宽10 nm的连续激光输出。利用角度调谐的方法,对Cr:ZnSe晶体的调谐性能进行了研究,在100 nm范围内获得了调谐输出。

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介绍了近几年迅速发展的一种新型激光介质——透明Nd:YAG多晶陶瓷的发展状况,对比分析了多晶陶瓷与单晶的光谱特性、激光特性和连续实验研究情况。并对钛宝石激光器调谐至808nm,端面抽运Nd:YAG陶瓷被动调Q全固态激光器的脉冲运转进行了较为详细的理论分析和实验研究。采用初始透射率为90%的Cr^4+:YAG可饱和吸收晶体,被动调Q的阈值功率为119mW,当端面抽运功率为465mW时,获得波长为1064nm,脉宽为16ns,重复频率为18.18kHz,单脉冲能量为3.4μJ,平均输出功率为61mW的稳定调Q

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报道了激光二极管(LD)抽运的Nd:YLF激光器,采用平凹腔结构,分别用两片Cr^4+:YAG可饱和吸收晶体,实现了被动调Q,输出激光波长为1053nm。采用厚度为0.5mm小信号透过率为90%的Cr^4+ YAG,在泵浦功率最大为17W时,输出脉冲宽度为60.6ns,平均功率为1.5W,重复频率为9.5kHz,单脉冲能量为157.9mJ;采用厚度为0.55mm小信号透过率为95%的Cr^4+ YAG,在泵浦功率最大为17W时,输出脉冲宽度为68.6ns,平均功率为1.35W,重复频率为14kHz,单脉冲

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Cr2+掺杂II-VI族化合物在中红外波段的输出,在气体检测、遥感、通信、眼科医学、神经外科等领域有着重要的应用前景。目前已经获得了最大1.7 W的连续输出功率,18.5 W的平均脉冲功率,1100 nm的调谐范围和最窄4 ps的脉宽。对Cr2+:ZnSe连续、脉冲、随机纳米激光器以及其它的Cr2+掺杂II-VI族化合物激光器的最新的国内外研究进展进行了综述。

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中红外全固态激光器在遥感、探测、医疗和生物成像中有着重要应用,但由于激光的振荡阈值与波长的四次方成反比,因而产生中红外波段的激光需要生长出低损耗、高质量的激光晶体。Cr^2+:ZnSe激光晶体具有宽的吸收和发射带宽、较高的激光增益,是非常有潜力的可调谐中红外激光晶体材料。

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We demonstrate passive Q-switching of short-length double-clad Tm3+-doped silica fiber lasers near 2 mu m pumped by a laser diode array (LDA) at 790 nm. Polycrystalline Cr2+:ZnSe microchips with thickness from 0.3 to 1 mm are adopted as the Q-switching elements. Pulse duration of 120 ns, pulse energy over 14 mu] and repetition rate of 53 kHz are obtained from a 5-cm long fiber laser. As high as 530 kHz repetition rate is achieved from a 50-cm long fiber laser at similar to 10-W pump power. The performance of the Q-switched fiber lasers as a function of fiber length is also analyzed. (c) 2008 Elsevier B.V. All rights reserved.

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研究了Cr^3+,Yb^3+,Er^3+共掺磷酸盐铒玻璃转镜调Q激光性质.三种Er2O3掺杂浓度的激光实验结果表明,在Er2O3名义掺杂浓度为0.5wt%时,玻璃的综合激光性质最好,重复频率为0.1Hz时,它的激光阈值功率为14.5mJ,最大输出能量为9.6mJ,斜率效率为0.55%.在同种实验条件下,比较了Cr14和Kigre公司生产的QE-7S激光性质参数,实验表明,前者激光阈值功率稍低,而后者的斜率效率和最大输出功率略高.

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The emission intensity of Ni2+ at 1200 nm in transparent ZnO-Al2O3-SiO2 glass ceramics containing ZnAl2O4 nanocrystals is improved approximately 8 times by Cr3+ codoping with 532 nm excitation. This enhanced emission could be attributed to an efficient energy transfer from Cr3+ to Ni2+, which is confirmed by time-resolved emission spectra. The energy transfer efficiency is estimated to be 57% and the energy transfer mechanism is also discussed. (C) 2008 Optical Society of America.

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Infrared (1.2-1.6 mum) luminescence in a yttrium aluminium garnet (YAG) crystal, co-doped with Yb (10 at.%) and Cr (0.05 at.%) ions, was investigated under CW laser diode pumping (lambda = 940 nm). The Cr4+ emission band was observed with its peak at 1.35 mum and measured to be about 6% with respect to Yb3+ IR luminescence (lambda = 1.03 mum). Analysis of the crystal absorption and luminescence spectra allows one to conclude that Yb3+-Cr4+ energy transfer is a mechanism responsible for the B-3(2)(T-3(2))-B-3(1)((3)A(2)) emission of Cr4+ ions. This crystal is promising as an efficient source of the near infrared emission. (C) 2004 Elsevier B.V. All rights reserved.

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对透光性良好的Cr^3+:Al2O3透明多晶陶瓷的光谱性能进行了研究,其吸收光谱中吸收峰与单晶红宝石相一致,按吸收光谱和Tanabe-Sugano能级图,算出其晶场强度参数Dq及Racah参数B分别为1792cm^-1,689cm^-1,Dq/B=2.6,陶瓷中Cr^3+离子所处格位的晶体场强比单晶弱一些,但Cr^3+:Al2O3透明陶瓷仍属于强场晶体材料;当Cr^3+掺杂浓度到达0.8wt%时,陶瓷的发射谱仍保持较好的R线发射;随Cr^3+掺杂浓度的增大,激发峰位发生“红移”.在Cr^3+:Al2O3透