卫星跟踪技术在候鸟迁徙研究中的应用

：自20世纪80年代末期应用基于Argos系统的卫星跟踪技术开展候鸟迁徙研究以来，鸟类学家取得了 许多利用传统鸟类迁徙研究方法所无法取得的成果。但在中国，卫星跟踪技术在鸟类迁徙中的应用尚属空白。作 者利用参与中国首次应用卫星跟踪技术跟踪候鸟迁徙研究之机，对该技术用于候鸟迁徙研究的技术平台、主要内 容和未来研究进行了综述和展望。利用卫星跟踪技术开展的主要研究内容有：揭示迁徙路线和重要停歇地点；寻 找新繁殖地和越冬地；利用卫星数据对栖息地及其利用进行评价；探讨鸟类的迁徙策略。期望该技术能够成为中 国濒危鸟类保护的有效方法，并尽快得到应用。

云南鸟类种的新记录——海南■

2006年10月28日凌晨3点,笔者在位于云南省新平县哀牢山的金山丫口鸟类环志站进行夜间鸟类环志工作时,用灯光诱捕到一只鹭科鸟类,经鉴定为海南(Gorsachius magnificus),为云南省鸟类物种新记录。形态特征:头和颊部黑褐色;枕部具黑褐色的延长羽冠;有明显的白色眼后条纹,颊纹白色;眼球外凸,黄绿色的眼睑向外伸出;眼先裸露皮肤呈黄绿色;喉白,中央有褐色条纹;颈侧棕色,前端有黑色条纹,前颈具褐白斑驳的条纹,后颈黑褐色;背部、翅和尾羽褐色;第一枚初级飞羽外栗红色;胸、腹部、尾下覆羽及翅下覆羽白色,杂有褐色斑纹;上嘴黑色,下嘴嘴基黄色,嘴端黑色;虹膜褐色(中国鸟类野外手册上记载的虹膜为黄色,MacKinnon et al,2000);跗黄绿色。雌性标本量度(g,mm)如下:体重563,全长565,嘴峰72,翅长305,尾长111,跗76。海南是中国的特有种鸟类,属国家Ⅱ级重点保护鸟类。分布于中国南方的少数地区,国外仅在越南东京有过一次记录(MacKinnon et al,2000),种群数量稀少,过去曾记录于安徽、浙江、福建(Cheng,1987)、海南、广西及广东(Gao et al,200...

黄喉噪鹛分类地位新议

著名鸟类学家N.J.Collar在英国东方鸟类学会(The Oriental Bird Club)最新一期的Forktail上发表文章,对亚洲鹛类(文中用的是Timaliidae———画眉科)中一些种类的分类地位做了厘正,涉及多个在中国有分布的种类,其中包括将黄喉噪鹛东南亚种Garrulax galbanus courtoisi重新升格为独立种G.courtoisi[1]。1923年,法国鸟类学会会长M.A.Ménégaux依据1919年采自江西婺源(当时属安徽省)的两号标本发表了新种Garrulas courtoisi[2]。J.Berlioz随之将其归为黄喉噪鹛G.galbanus下的一亚种[3]。1958年,郑作新将1956年3月在云南思茅石头山采到的3只标本定名为G.g.courtoisi[4];1982年,郑作新、唐瑞昌又依据这3号标本发表了思茅亚种G.g.simaoensis[5]。1994年,Long等人即已指出应将黄喉噪鹛G.galbanus视为单型种,而将courtoisi和simaoensis分立之[6]。Inskipp等人也指出courtoisi(包括simaoensis)与galban

Bioaccumulation of polychlorinated dibenzo-p-dioxins and dibenzofurans in the foodweb of Ya-Er Lake area, China

Bioaccumulation of PCDD/F in the foodweb was investigated in the Ya-Er Lake area, which was heavily polluted by PCDD/F. The high concentrations of PCDD/F in sediment can be transferred and bioaccumulated by aquatic organisms and humans through various pathways. Benthonic invertebrate animals and aquatic plants with a lot of fibers in the root can accumulate PCDD/F from sediment and water. Snail (Bellamya aeruginosa), shrimp (Macrobranchium sp.) and freshwater mussel (Acuticosta chinensis (Lea)) took up PCDD/F from the water and maintained the emission patterns, whereas fish tended to selectively accumulate 2,3,7,8-substituted isomers. The tissues of fish-eating bird and duck (Anas platyrhynchos) were very highly contaminated by PCDD/F due to ingestion of fish and other aquatic organisms from sediment. The residual concentration in breast milk depended on the original concentration of PCDD/F in the food. A resident in Ya-Er Lake area showed a daily intake of PCDD/ F of about 9.14 pg TEQ/kg body weight/day. This is higher than the tolerable daily intake (TDI) for PCDD/F (1 pg TEQ/kg body weight/day), which was recommended by the World Health Organization (WHO). (C) 2001 Elsevier Science Ltd. All rights reserved.

A nanowire magnetic memory cell based on a periodic magnetic superlattice

We analyse the operation of a semiconductor nanowire-based memory cell. Large changes in the nanowire conductance result when the magnetization of a periodic array of nanoscale magnetic gates, which comprise the other key component of the memory cell, is switched between distinct configurations by an external magnetic field. The resulting conductance change provides the basis for a robust memory effect, which can be implemented in a semiconductor structure compatible with conventional semiconductor integrated circuits.

喷灌均匀系数的三次样条两次插值计算方法

为提高喷灌水量分布均匀性评价的准确性,当雨量筒径向布置时,为考虑所有测点数据对插值点降水深的影响,采用径向和周向两次的三次样条插值计算出未知点的降水深,从而计算喷灌均匀系数。以美国雨鸟30PSH型喷头雨量筒间隔为1m和2m的喷洒试验数据,计算网格点取1m和0.25m,分别采用三次样条两次插值法和邻近四点距离线性插值法计算了克里斯琴森均匀系数。结果表明,均匀系数由高至低的顺序依次为采样间隔为2m的线性插值、采样间隔为2m的三次样条两次插值、采样间隔为1m的线性插值和采样间隔为1m的三次样条两次插值。采样间隔2m比1m计算出的均匀系数总体高3~4个百分点,三次样条两次插值法比邻近点距离线性插值法略低1个百分点,2种计算网格点间距下的均匀系数差值小于1个百分点。结果证明,采样间距、插值方法、计算网格间距对均匀系数的影响依次降低,三次样条两次插值法可以用来评价喷灌组合均匀系数。

液体多脉冲及2D NMR实验的计算机模拟

现代多脉冲及2D NMR技术是过去十年中发展起来的崭新的NMR实验方法。计算机模拟做为NMR实验的强有力分析手段已日益受到重视。国内这方面工作开展得尚很少；国外发表的工作主要采用的是数字模拟，存在分析结果不够直观、物理意义不够清晰等缺陷。本论文工作采用乘积算符方法研制出对分析多脉冲及2D NMR实验普适的模拟程序PROPER；在乘积算符基础上，针对磁等性自旋体系，提出了实用的对称化乘积算符及多量子积算符方法。一、多脉冲及2D NMR实验的计算机模拟 1. 采用乘积算符方法在本所PDP－11／23微机上研制了多脉冲及2D NMR实验的模拟程序PROPER。该程序对不超过4核（I ＝ 1／2）的同核及异核弱耦合自旋体系非选择性脉冲序列的分析是普遍适用的。受计算机内存的限制，PROPER程序所能处理的脉冲序列脉冲间隔数目一般不超过10。2. 应用PROPER模拟程序对INEP和DEPT脉冲序列进行了分析比较；特别对BIRD脉冲序列的各种相位变型进行了模拟分析，给出了分析结果，分析过程中考虑了影响BIRD作用效果的同核耦合因素。应用结果表明，PROPER程序计算正确、迅速、给出的模拟结果较通常的数字模拟方法简单、直观、物理意义清楚，便于分析。由于采用算符模拟，结果的输出打印比较费时。目前，PROPER程序正在改进和完善之中。二、多脉冲及2D NMR实验的密度算符描述 1. 针对磁等性自旋（I ＝ 1／2）体系，首次提出了对称化乘积算符描述方法。在通常的乘积算符基础上，引入了对称化乘积算符，并对其数理基础进行了详细论证。推导了算符循环对易关系决定的Liourill-Von Neumann方程的解，给出了算符间普遍存在的循环对易关系及其相应的演化公式。据此，以InS(I = 1/2, S = 1/2; n = 2,3)自旋体系为例，对DEPT脉冲序列进行了分析；结果表明，该方法较通常的乘积算符方法对磁等性自旋体系的分析要简单、实用，且物理意义更加明确。由于该方法涉及较多的算符对易关系，因此不易计算机编程。2. 在对称化乘积算符基础上引入了多量子积算符的概念。以In(I = 1/2; n = 2,3)体系为例，给出了两者的互换关系。推导出了具有标量耦合作用的两组合粒子体系普适的多量子积算符环对易关系及相应的演化解析式。多量子积算符方法可望将1／2－自旋磁等性组合粒子表象与自旋大于1／2的单粒子表象统一起来，并为计算机模拟提供新的数学方法。该方法尚有待于进一步研究。

基于QuickBird卫星影像的沈阳城市绿地景观格局研究

城市绿地是城市景观的重要组成部分，起着调节城市生态环境、美化城市景观、提供休闲游憩场所的重要作用，在城市发展中扮演着关键角色。沈阳市近年来将城市绿地建设作为城市建设的重要方面，取得了显著成效。因此，本文利用2006年Quick Bird高分辨率卫星影像对沈阳市三环内的城市绿地景观格局进行了研究，具体结论如下： (1) 沈阳三环内绿地斑块18261个，绿地面积 173.71km2，斑块数目主要以中型斑块为主(62.25%)；在面积上以大型斑块为主(85.59%)；绿地总体呈现斑块分布不均衡。 (2) 居住绿地、单位附属绿地与道路绿地破碎化程度高，分布分散，斑块形状复杂。城市绿地廊道连通性较高，道路绿地平均分维数最大。 (3) 公园绿地亚类中，综合型公园与带状公园面积较大，破碎化程度低；社区公园与街头绿地面积较小，破碎化程度高，分布分散。 (4) 绿地景观整体上，绿地斑块密度较大，破碎化程度高，景观多样性指数为1.6，斑块类型丰富，均匀度指数为0.73，蔓延度指数为0.83，存在着少数类型控制整个景观的现象。 (5) 绿地系统梯度分析表明:类型水平上,不同的绿地类型沿景观格局梯度表现出明显的空间特征；景观水平上,不同景观指数沿样带梯度也表现出差异性,表明城市化导致景观的破碎化程度增大,景观异质性增高。城乡边缘区绿地类型最为丰富，多样性指数较高，其格局有利于绿地生态环境维护功能的发挥。

有机质谱裂解规律及智能解析方法研究

本学位论文分为四个部分，第一部分报道了用串联质谱快速分析合成药物中的微量杂质成分以及分析中药材中的化学成分。第二部分报道了通过质谱和串联质谱发现并合成新型的PdPincer 催化剂，同时对其活性进行测试。第三部分为串联质谱自动解析软件的设计及应用。第四部分概述了应用在质谱中的各种碎裂方式。 第一部分首先总结了5-溴粉防己碱及其类似物的裂解规律，并以此为根据推测出2 个微量杂质的结构。随后针对无患子（Sapindus mukurossi Gatren.）中的皂苷成分，由ESI-QTOF 得到各个皂苷成份的高分辨质量数据进而得到其分子式，然后利用ESI-IT 电喷雾串联质谱对无患子总皂苷中各皂苷成分的结构进行进一步的鉴定。进而以同样的方式，先通过ESI-QTOF 得到黄山药（Dioscoreapanthaica）总皂苷中各个组分化合物的分子式，然后对已有的薯蓣皂苷标准品做串联质谱分析，以得到该类化合物的裂解规律并给出解析该类化合物的流程图。在此利用计算化学的方法讨论了离子的丰度与裂解活化能之间的关系。然后应用APCI-MS/MS 方法探讨了四对同分异构体和几个已知的化合物，并最后用液质联用对其进行确认，同时还给出了4 个未知化合物的可能结构。 第二部分报道通过质谱和串联质谱发现并合成新型的PdPincer 催化剂，同时对其活性进行测试。钯催化的交联反应是有机合成中C-C 键形成的最有效的方法，且硫脲是一类对空气和水都稳定的化合物，因此我们设计并合成了一系列的硫脲钯催化剂并得到了很好的催化活性。我们在对其中一类环状双硫脲化合物进行质谱实验的时候，在正离子模式下发现了反常的[M.H]+，通过串联质谱进一步确定了它是一种新型的PdPincer 结构。我们将其合成出来并通过X-ray 衍射实验确定了它的结构。同时测定其催化活性并与未形成pincer 的类似物进行比较发现该类化合物具有较宽的底物适用性。 第三部分为串联质谱自动解析软件的设计及应用。通过前面两部分的启示，独立设计开发了AuMass（1.0）。其算法是：先通过查找特殊的碎片离子，中性丢失或碎片离子质量差来确定某类化合物的骨架结构，然后利用该类化合物的自动解析流程来对其周边取代基进行确认。通过它快速地对白芍中的化学成分进行解析，并对未知的化合物进行了推测。为了增加它的解析能力，我又对其它类型的化合物裂解规律进行总结，并给出了自动解析流程。实践证明该软件具有相当好的应用价值。 第四部分综述了应用在质谱上的各类母离子的碎裂技术。这里包括了碰撞诱导裂解（CID）、光诱导碎裂（LID）、电子捕获裂解/电子转移裂解（ECD/ETD）、红外多光子解离（IRMPD）、黑体辐射解离（BIRD）和PQD 裂解技术。 This dissertation consists of four chapters. The first chapter reports the rapidanalysis of trace impurities from synthetical medicine and analysis of the chemicalconstitutents from Chinese herb medicines. The second chapter elaborates the studieson the discorvery and synthesis of new type of Pd Pincer catalyst by using MS andtandem MS together with the testing of its catalyst activity. The third chapter dwellson the designation and development of automatic tandem mass spectrometry analysissoftware. The last chapter presents a review on the dissociation technique of massspectrometry. The first chapter reports the rapid analysis of trace impurities from synthesismedicine and analysis of the chemical constitutents from Chinese herb medicines. The fission mechanism of 5-bromotetrandrine was obtained by analysis of the dissociationpathways of major product, by using which the possible structure of the two traceimpurties was assumed. There are lots of saponins in Sapindus mukurossi. Except forthe good spumescence and decontamination，it possesses the bioactivity of antigenand antitch. First of all, the high resolution mass information was obtained by ESI-QTOF. Hence the possible molecular formulars were acquired too. Then weconducted the further detection of the structures of its saponins by using ESI-ITtechnology. In the same manner, first the molecular formulars of every constituentfrom Dioscorea panthaica in total saponins were obtained by ESI-QTOF, and thenacquired the fission mechanism of this type of compounds by tandem massexperiment on a series of known and available saponins. In the same time, theanalysis flowchart was concluded. Here the relationship between the ion intensity andthe corresponding dissiociation activation energy was studied by computer chemistry.Then the four pairs of isomers were differentiated by APCI-MS/MS, as well as thecharacterization of known and unknown compounds. The assumption was confirmed by HPLC-MS/MS. Among them the possible structures of four unknown saponinswas presented. The second part was discovery and synthesis of a new type of Pd pincer catalystby MS and tandem MS. The coupling reaction catalyzed by Pd is the most effectivemethod in C-C formation in organic synthesis. Apart from that, thiourea is type ofcompounds that are stable to atmosphere and moisture. Hence we designed a series ofPd thiourea catalysts. Some of them show the excellent catalyst activity. The abnormalparent ion [M.H]+ was founded in positive ESI mode when we conduct some massspectrometry experiments on the bicyclical thiourea Pd complex. The structure wasproposed by mass and tandem mass spectrometry. Because it was a new type of pincer,we want to test its catalyst activity. So the Pd pincer was synthesized and the detailstructure was obtained by x-ray experiment. It shows the more fitness in catalysis ofSuzuki reaction by comparison with the analogue. The third chapter dwells on the design and development of automatic tandemmass spectrometry analysis software. Inspired by the former two chapters, theAuMass (version 1.0) was developed. Its algorithm is: first check the diagnostic ion,diagnostic neutral loss or diagnostic ions mass intervals in database to find out whatthe analyst’s skeleton belongs to, then identify the peripheral functional group by thecorresponding analysis flowchart. The chemical constituents of Paeonia lactiflorawere identified rapidly by using AuMass. To increase the analysis ability, the othertypes of compounds from Chinese herbs was concluded. Actually, the software isproven to have the much valuable application. The last chapter presented the review on the some kinds of fission technique ofmass spectrometry. It involves the collision induced dissociation (CID), laser induceddissociation (LID), electron capture dissociation/electron transfer dissociation(ECD/ETD), infrared multiple photons dissiociation, black body irraditiondissociation and PQD fission technique from Finnigan.

青海湖鸟岛地区植物群落物种多样性与土壤环境因子的关系

The study on the relationship between plant species diversity and soil factors in the bird island of Qinghai Lake indicated that this island was a low diversity district,its Shannon-Wienner index and species richness decreased with the increasing soil available K,water soluble salt concentration and pH,and there were significant linear and quadratic correlations between them.Stepwise linear regressions showed that soil available K and water soluble salt were the key factors to estimate Shannon-Wienner index and species richness in this island,respectively,and no correlation was found between species evenness and soil factors.

The cDNA cloning and mRNA expression of a potential selenium-binding protein gene in the scallop Chlamys farreri

Selenium binding proteins (SeBP) represent a family of proteins that are believed to be involved in controlling the oxidation/reduction in many physiological processes. The cDNA of Zhikong Scallop Chlamys farreri selenium binding protein (zSeBP) was cloned by expressed sequence tag (EST) and RACE techniques. The high similarity of zSeBP deduced amino acid sequence with the SeBP in other organisms, such as bird, fish, frog, mosquito, fruit fly, mammalian, and even nematode and microorganism indicated that zSeBP should be a member of SeBP family. The temporal expression of zSeBP in the hemocytes was measured by semi-quantitative RT-PCR after scallops were stimulated by either oxidative stress or microbial challenge. The expression of zSeBP was up-regulated progressively after stimulation, and then dropped gradually to the original level. Meanwhile, malondialdehyde (MDA) measured by the colorimetric method in the microbial challenged scallops increased immediately after scallops was challenged by microbes, and was significantly higher than that in the control scallops. Results indicated that the microbial infection could incense the disorder of oxidation/reduction and may result in high MDA production. The negative correlation between the expression level of zSeBP and the MDA content suggested that zSeBP could play an important role in mediating the anti-oxidation mechanisms and immune response in marine invertebrates. (c) 2005 Published by Elsevier Ltd.

青海湖鸟岛地区植物群落物种多样性与土壤环境因子的关系

生物多样性是测度生态系统内物种组成、结构多样性和复杂化程度的客观指标,是生态系统内生物群落对生物和非生物环境综合作用的外在反映.生物多样性研究已经成为当今植物生态学研究的热点之一[2,3,6,7,1],对于具体的植物群落来说,大的气候条件相对一致,群落生境的差异可能是形成物种多样性的主要原因,而土壤因子可能是一个重要的环境因子,因此,研究物种多样性与土壤环境的关系有重要的意义,国内外都对此做了大量的研究[3,5,10,17].利用数学方法研究鸟岛地区物种多样性与土壤环境的关系,一方面可以进一步了解这一片新生土地的特点,增加高海拔地区的资料,另一方面可以为保护鸟岛这一青海湖物种多样性关键地区提供理论支持.

Livestock grazing, plateau pikas and the conservation of avian biodiversity on the Tibetan plateau

On the Qinghai-Tibet plateau increased livestock numbers have resulted in degradation of the grasslands with potential impacts on native biodiversity. Concurrently, perceived increases in populations of native small mammals such as plateau pikas (Ochotona curzoniae) have led to poisoning programs, with uncertain impacts on species such as ground-nesting birds. We explored the relationships between the local seasonal abundance of small birds and (1) the density of pika burrows; (2) livestock grazing practices; and (3) local poisoning of pikas. Around Naqu prefecture, central Tibet, we used a nested experimental design to collect data from areas rested from grazing over summer, nearby areas with year-round grazing and areas subjected to pika poisoning. Additional data were collected from a site where grazing had not occurred for at least 4 years prior to the study. Poisoning pikas in spring had no detectable effect on the local abundance of birds the following autumn. However, two ground-nesting species, white-rumped and rufous-necked snowfinches, showed positive associations with the density of pika burrows, indicating that long-term 'pika poisoning could reduce the density of these species by reducing the density of pika burrows. Rufous-necked snowfinches and non ground-nesting species including horned larks and common hoopoes showed positive responses to reduced grazing pressure from livestock, particularly in the long-rested site, indicating current grazing levels could be having a negative impact on these species. Conservation of small passerine biodiversity in this system will require changed management practices for livestock and pikas that consider the complex three-way interaction between livestock grazing, pikas and small birds. (C) 2008 Elsevier Ltd. All rights reserved.

Reproductive biology of great cormorant (Phalacrocorax carbo sinensis) in the qinghai-tibet plateau

There have been no detailed studies on reproductive biology of the Great Cormorant (Phalacrocorax carbo sinensis) in Qinghai-Tibet Plateau. We conducted such investigations during the breeding seasons of 1999 and 2000 in Qinghai-Lake Bird Isle, China. Great Cormorants began to migrate to Qinghai-Lake for reproduction from the middle of March and left from early October at the end of reproduction. Nesting periods were from early April to mid June and took 50 days. Egg-laying occurred during the three weeks from the end of April to 20 May. Females typically laid an egg every 1-2 days until clutch completion. Mean clutch size in the study area over two years was 3.3 (SE +/- 0.13, N = 68, range 1-5) and most (66.18%) fell within the range 3-4 eggs. Length of eggs averaged 61.01 mm and breadth averaged 34.13 mm. Fresh egg weight averaged 57.34 g (SE +/- 0.36, range 46.0-73.7 g, N = 179). Hatching success was 48.7% and fledging success was 64.9% over two years. Decline of available fish resources in Qinghai-Lake might be one of main causes of lower reproductive success. The causes of chick loss were possibly high altitude, high winds and prolonged rain.