Measurement of trace phosphorus in dichlorosilane by high-temperature hydrogen reduction gas chromatography

Dichlorosilane, a gas at normal temperature with a boiling point of 8.3 degrees C, is very difficult to sample and detect using conventional methods. We reduced phosphorus in dichlorosilane to PH3 by hydrogen at high temperature, then PH3 was separated from chlorosilanes by NaOH solution and from other hydrides by chromatographic absorption. Thus the problem of interference of chlorosilanes and other hydrides was overcome and PH, was measured by a double flame photometric detector at 526 nm. This method was sensitive, reliable and convenient and the sensitivity reached as low as 0.04 mu g/l.

The mean value concept in mono-linear regression of multi-variables and its application to trace studies in geosciences

IEECAS SKLLQG

Use of Zr/Rb ratios in Chinese loess sequences to trace paleo-winter monsoon winds strength

IEECAS SKLLQG

Mineral and chemical composition and some trace element contents in coals and coal ashes from Huaibei coal field, China

IEECAS SKLLQG