323 resultados para TeO2-ZnO-Na2O-K2O glasses
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分析了掺Er^3+碲酸盐玻璃的热力学稳定性能,研究了掺Er^3+碲酸盐玻璃的吸收和荧光光谱性质;应用Judd-Ofelt理论计算了碲酸盐玻璃中Er^3+离子的强度参数Ω(Ω2=4.79×10^-20cm^2,Ω4=1.52×10^-20cm^2,Ω6=0.66×10^-20cm^2),计算了离子的自发跃迁几率,荧光分支比;应用McCumber理论计算了Er^3+的受激发射截面(σe=10.40×10^-21cm^2)、Er^3+离子^4I13/2→^4I15/2发射谱的荧光半高宽(FWHM=65.5nm)
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研究了Al2O3 ,B2O3对P2O5-Al2O3-B2O3-ZnO-Na2O-CuCl玻璃形成区的影响规律;包边玻璃的物化性质随B/(B+Al)的变化规律;以及特定组分包边玻璃的透射光谱和吸收系数。这些研究工作对高功率大尺寸钕磷酸盐激光包边玻璃的研制具有非常重要的意义。
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采用改进的外束质子激发x射线荧光、电感耦合等离子体原子发射光谱分析等技术,对广西合浦地区出土的一批汉代古玻璃样品的化学成分和结构特性等进行了检测。结果表明:两汉时期,合浦地区的古代玻璃存在K2O—SiO2、PbO-BaO-SiO2、PbO—SiO2、Na2O-K2O-PbO-SiO2、(Na2O)K2O-CaO—SiO2等多种类型,但绝大多数为K2O—SiO2玻璃。表面风化可引起K2O-SiO2玻璃表面K2O等助熔剂的流失和富硅层的形成。综合化学成分以及器型特征,认为我国汉代K2O—SiO2玻璃制造技术可
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研究了西汉(公元前200年)以前不同地区的最早的中国古代玻璃.古玻璃样品出土于新疆维吾尔自治区、湖北省、湖南省、四川省、云南省、广东省和贵州省等地.用质子激发X光荧光技术、能量分散X光荧光技术和电感耦合等离子发射光谱等方法测定了玻璃的化学成分.这些古玻璃样品的化学成分属于以下玻璃系统:Na2O(K2O)-CaO—SiO2(K2O:Na2O〈1),K2O(Na2O)-CaO—SiO2(K2O:Na2O〉1),K2O—SiO2和BaO—PbO—SiO2.从考古和历史学观点讨论了这些最早的中国古代玻璃的起源,指
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利用全谱直读电感耦合等离子体原子发射光谱仪(ICP—AES)定量分析了TeO2-ZnO系统玻璃的化学稳定性,并从TeO2-ZnO系统玻璃的结构与价键理论的角度分析了水对该系统玻璃的侵蚀机理。实验结果表明,水对该玻璃系统的侵蚀过程属于连续性溶解过程,且获得该系统玻璃化学稳定性较理想组分。
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锗酸盐和氟铝酸盐透红外玻璃材料作为窗口或头罩材料具有广泛的应用前景。结合锗酸盐玻璃含有少量水的问题,在成分中引入氟化物,实验表明:随氟化物含量增加.玻璃中羟基含量逐渐降低。同时通过对熔制温度的调整,获得了不合羟基的红外玻璃。针对氟铝酸盐玻璃在冷却过程中易析晶的问题,在氟化物组分中加入少量重金属氧化物TeO2,得到析晶性能好的氧氟铝酸盐玻璃。同时给出了两类红外材料的一些物理、化学性质。
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以TeO2-ZnO-ZnF2系统为研究对象,采用差热分析计算分析了玻璃样品的析晶活化能E,并且得出了析晶速率k与温度的关系。结果表明,随着玻璃中氟化物含量的增加析晶速率提高,不利于实现热处理可控析晶过程,氟化物组分引入的含量对制备该系统透明玻璃陶瓷有很大的影响。
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Tazhong-Bachu region is located in the Western Tarim basin.The early Permian magmatic rocks occur in the earth surface of Tazhong-Bachu region are mainly distributed in Kepintag,Mazhartag and Wajilitag region. There are a lot of wells, in which researchers found the early Permian magmatic rocks,in desert cover area.Most magmatic rocks are basic rocks, a few of which are ultrabasic rocks and intermediate-acid magmatic rocks.The ultrabasic rocks are are mainly occur in the Cryptoexplosive Breccia Pipes ,which is located in the volcanic complex body of Wajilitag region.The basic rocks can be divided into three rock types:The first type of the magmatic rocks in Tazhong-Bachu region is volcanic rock ,which occurs in the Lower Permian Kupukuziman Formation and Kaipaizileike Formation. Most Volcanic rocks are basalts,a few of which are volcanic breccias and pyroclastic rocks.The basalts are distributed in stratiform occurrences and interbeded the clastic rocks in Kepintag region.The attitudes of the basalts are nearly horizontal.Columnar Joints, gas pore textures and amygdaloidal structure are to develop in basalts.The second type of the magmatic rocks in Tazhong-Bachu region is diabase,which occurs in Mazhartag region.Diabase dike swarms occur in the stratums of Silurian, Devonian, Carboniferous and Lower Permian.They make from NNW direction to SSE direction, the obliquity of stratum is greater than 60°, and the dike thickness is form several cm to several meters. Diabasic texture is found in the rocks .The first type of the magmatic rocks in Tazhong-Bachu region are gabbro- pyroxenite rocks ,which occur in the Wajilitag igneous complex body. The intermediate-acid magmatic rocks, which are mainly syenites, are located in Mazhartag and Wajiltag region. But they are small in the whole Tazhong-Bachu region.There are intermediate-acid magmatic rocks,which are mainly dacite,in the northeast part of the wells in Tazhong-Bachu region.But ,it is not found in earth surface.Through systematical geochemical research of early Permian magmatic rocks,which are distributed in Kepintag,Mazhartag, Wajilitag region and the wells such as F1 well、Z1 well、Z13 well、TZ18 well、H3 well、H4 well et al., the focus on the geochronologic characteristics, the main element,trace element and REE geochemistry, the mineralogic characteristics, the Sr-Nd and Pb isotopic characteristics are put forward. The main points are: 1、A combined study of CL imaging and LA-ICP-MS U-Pb dating were carried out for zircon grains of the magmatic rocks in the Tazhong-Bachu region from the Tarim basin.The results of the systematic zircon LA-ICP-MS U-Pb dating reveal 272±6Ma to 291±10Ma for the magamatic rocks. It indicated that Early Permian is an important period of magmatic acvivity in the Tazhong-Bachu region. 2、There are a big hunch in the curves of primitive mantle-normalized trace element concentrations in the early Permian magmatic rocks from Kepintag, Mazhartag, Wajilitag region and the 14 wells. Light rare earth elements are comparatively rich and heavy rare earth elements are comparatively poor. The slope rates are same between light rare erath elements and heavy rare earth elements. It is not like the curves of the basalts in the convergent margin of plate , in which the slope rates of light rare erath elements is bigger than the alope rates of heavy rare erath elements, and the curves of heavy rare earth elements are comparatively flat. The magmatic rocks of Tazhong-Bachu region rarely have the characteristics of the basalts in the convergent margin of plate, which is that Tantalum, Niobium and Titanium are much poor, and Zirconium, Hafnium and Phosphorus are moderately poor. The magamatic rocks are mostly alkaline, which is indicated by the dots of the (Na2O+K2O)-SiO2 identification diagram. All of these indicate that the early Permian magmatic rocks were formed in an extension environment of intraplate. 3、The Thorium abundance is high and Tantalum abundance is low in most magmatic rocks from Tazhong-Bachu reguion, which is formed for crustal contamination.In the Th/Yb-Ta/Yb identification diagram,most dots are in the region, which means active continental margin, but a few dots are in the region, which means mantle source. It indicated the feeding of continental crust materials. 4、The magnesium content of the olvines from Wagilitag region is richest, and the olvines from Kepintag region is poorest in the tree region. 5、Through the the Sr-Nd and Pb isotopic study of the basalts and diabases from the F1 well core, Z1 well core, Z13 well core,TZ18 well core, and the basalts,gabbros, diabases(diabase-prophyrites) and pl-peridotites from Kepintag,Mazhartag, Wajilitag region , it indicated that all isotopic data is similar and close to enriched mantle.
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The most widespread rock associations in the Western Block of North China Craton are khondalites distributed mainly in Jining, Liangcheng and Datong. A large quantitiy of garnet-bearing granites are contained in the khondalites. A great deal of research has been carried out on them by previous researchers. Studies of these garnet-bearing granites consist essentially of structural characteristics, petrography and geochemistry, and finally geochronological determinations. Summing up these researches, it will not be difficult to see that all of these authors have regarded these large numbers of garnets (up to 20%) contained in granites as crystallized products from magmas, but they have not proved this from petrological perspective. Theoretically, there are possibly three kinds of petrogenesis as to these garnets. The first one is that they have been transferred to the granites from khondalites by melt when anatexis happened to khondalites, and they, in essence, are residual metamorphic garnets; The second one is that when the khondalites were being melted, these garnets were produced from biotite dehydration melting, and the newly formed garnets intruded together with the melt and eventually molded the garnet-bearing granites. Garnets of this possible kind either showed independent crystals, or garnets from khondalites took place secondary growth under favorable temperature and pressure conditions for their crystallization; The last possibility is that these garnets were crystallized from magmas in which suitable pressure, temperature and composition were available. These garnets, generally, should be fine-grained. The aim of this study is, through examining the mineral chemistry of the garnets and the whole rock chemistry, to ascertain under which kind of mechanism, in the world, did these garnets form? Besides, we try to calculate the temperatures under which khondalites began melting and reactions of the garnets and the cooled melts happened by garnet-biotite thermometry. The whole rock chemistry analyses of the garnet-bearing granites tell us that all the samples are strongly peraluminous (A/CNK greater than 1.1) on the A/NK vs. A/CNK plot. On the SiO2-K2O plot, the granites are mainly constrained to be high-K calc-alkaline and calc-alkaline series, consistent with previous researches. On the ACF((Al2O3-Na2O-K2O)-FeO(T)-CaO) discrimination plot, all the six garnet-bearing granite samples drop into the area of S-type granites. The relationship between CaO/Na2O and SiO2 shows that the overwhelming majority of garnet-bearing granites have a CaO/Na2O value over 0.3, revealing that they probably come from metagreywacke precursors or mediate-felsic orthogeneisses compositionally similar to them. Detailed EPMA analyses conducted on the garnets contained in the garnet-bearing granites show that all the garnets are dominated by almandine and pyrope, which occupy 92-96% (Weight Percentage) of each garnet analyzed, typical of granulite facies. Their chemical composition is entirely different from those crystallized in magmas, but extremely similar to those of typical granulite facies metapelites in khondalites and typical granulites, indicating all the garnets to be metamorphogenic. In addition, REEs distribution patterns of the garnets are totally different from typical biotite granites and peraluminous granites. In other words, both LREE and HREE of our garnets are evidently lower than those from these two kinds of rocks. Moreover, compared to the REE pattern of the garnets from typical amphibolites, LREE content of our garnets is obviously higher and HREE content is a little lower. However, REE patterns of our garnets are completely in harmony with those of garnets from typical granulites. So, the REE patterns of garnets, again, prove that all the garnets we studied are metamorphogenic. Biotites appear in two forms, being as inclusions in the garnet and as selvages immediately adjacent to the garnet, respectively. Two reactions and their corresponding temperatures, with the help of petrography and Garnet-Biotite geothermometers, could be obtained, which are Bt+ Pl+ Qtz→Kfs+ Opx+ Grt+ melt as positive reaction and Kfs+ Grt+ melt→Bt+ Pl+ Qtz as reverse reaction, respectively. Summing up the discussion above, we declare that the garnet-bearing granites distributed in the Western Block of North China Craton are the mixture of melts and restites resulted from biotite dehydration melting. The garnets contained in the restites are the products from biotite dehydration melting and restites from the khondalites, respectively.
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In recent years, thanks to the improvement of analytical methods and the use of MC-ICP-MS, Fe isotope can be measured precisely. Fe isotope shows considerable variation both in biological and inorganic processes (from low T to high T) in nature, Therefore, Fe isotope has become one of the exciting frontier sciences and has favorable prospects of the application to the geosciences and life sciences. Based on a comprehensive review of available references in the related field, this study focuses on the development of techniques for high-precision measurement of iron isotope using MC-ICP-MS, and application of the techniques developed to study the Fe isotopes as well as major and trace element compositions of minerals (Ol, Opx, Cpx and Sp) from spinel peridotitic xenoliths from Cenozoic alkaline basalts to investigate Fe isotopic features of the lithospheric mantle beneath the North China Craton. The minerals from these xenoliths are similar to those off-cratonic peridotites world-wide, but are remarkably different from those on-cratonic peridotites and clinopyroxenes from these spinel lherzolites exhibit two types of chondrite-normalized REE patterns i.e. LREE-depleted and flat or spoon-shaped. It is noted that total abundances of REE in clinopyroxenes from these peridotites show a broad negative correlation with Cr# numbers of Cpx and Sp. The Fe isotope results show that the spinel peridotitic xenoliths have small but distinguishable Fe isotopic variations in minerals (generally Ol < Opx < Cpx) and samples, and the isotopic range in spinel is relatively large. Positive linear relationship with the ε57Fecpx/ε57Feopx ratio close to one unit has been observed between Fe isotopes of coexistent Opx and Cpx, indicating that the Cpx and Opx have generally reached Fe isotopic equilibrium. However, Fe isotopes between the Ol and Sp show apparent disequilibrium. The broadly negative correlation between mineral Fe isotopes and oxygen fugacity (fo2), metasomatic indexes such as spinel Cr#, (La/Yb) N and (La/Sm) N ratios of clinopyroxenes suggest that Fe isotopic variations in different minerals and peridotites were probably produced by melt-peridotite interaction. This study further confirms the previous observation that the lithospheric mantle has distinguishable and heterogeneous Fe isotopic variations at a scale of xenoliths. Mantle metasomatism that induces the interaction of the lithospheric mantle peridotite with metasomatic agent is a most potential mechanism for the Fe isotope fractionation in mantle peridotites. Therefore, Fe isotope could be a new and powerful tool to probe the evolution of the lithospheric mantle. We also report mineral compositions, clinopyroxene trace element concentrations and Sr-Nd isotopes for newly-discovered phlogopite-bearing spinel lherzolite and olivine clinopyroxenite xenoliths from three different localities (Hannuoba, Hebei Province; Jining Sangyitang, Inner Mongolia; Hebi, Henan Province)of the North China Craton. Systematic comparisons with phlogopite-free spinel lherzolite xenolith from the same locality reveals that the phlogopite-bearing peridotitic xenoliths have relatively higher Al2O3, CaO, Na2O, K2O, TiO2 contents and lower MgO contents than those phogopite-free counterparts. The former also has higher LREE concentrations, but relatively less radiogenic Sr-Nd isotopic ratios. This demonstrates that mantle metasomatism can not only enrich the basaltic components and trace element concentrations, but also make a decrease in Mg# of the peridotites and olivines and a relative depletion in Sr-Nd isotopes. 87Rb/86Sr-87Sr/86Sr isochrons of the phlogopite-bearing xenoliths indicate that mantle metasomatism happened in the Mesozoic and/or Cenozoic time. The metasomatic agent was derived from the asthenosphere. The result also manifests that the widespread similarity of the geochemical features such as major and trace elements and isotopic compositions in the Cenozoic lithospheric mantle beneath the North China Craton to those “oceanic” lithospheric mantle could be as a result of the ubiquitous presence of the interaction between the old refractory peridotites and the infiltrated asthenospheric melt, rather than the actually newly-accreted lithospheric mantle.
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The fluvio-lacustrine sequence in the Nihewan Basin is an important archive of late Pliocene-Pleistocene climate and environment changes in temperate northern China, which provides excellent sources of early human settlements in high latitude East Asia. The recent years have witnessed a considerable progress in the paleomagnetic dating of its stratigraphy, which has notably increased our understanding of a series of important issues such as the early human occupation in the Old World, the infilling history of the Nihewan Basin, and the chronological sequence of the Nihewan faunas. Up to now, the long-term paleoenvironmental changes directly retrieved from this basin, which might influence the evolution and expansion of early humans in the Nihewan Basin, are still poorly constrained, although several paleoclimatic records have been retrieved from this area. In this study, a combined mineral-magnetic and geochemical investigation was carried out on the fluvio-lacustrine sequence from the Dachangliang section at the eastern margin of the basin in order to reveal its rock magnetic and environmental magnetic characteristics and its implications for early human evolution in East Asia. The major findings and conclusions are listed as the following: First, there is an increased cooling coupled with an intensified aridification recorded in the fluvio-lacustrine sequence of the Dachangliang section. The cooling is related to an up-section decrease in propensity to chemical weathering as inferred from an increase in low-field susceptibility after cycling to 700 °C. Close to 700 °C, reacting chlorite is providing the iron source for newly formed very fine-grained ferrimagnetic minerals which enhances the susceptibility signal. The reactivity of chlorite after annealing at temperatures above 600 °C is documented with X-ray diffraction. Second, degrees of chemical weathering in the Nihewan Basin are further estimated by clay mineralogy (i.e. chlorite and illite contents and chlorite/illite ratio) and a series of major element proxies (i.e. Na2O/Al2O3 versus K2O/Al2O3 diagram, Al2O3-(CaO + Na2O)-K2O ternary diagram (A-CN-K), chemical index of alteration (CIA), (CaO + Na2O + MgO)/TiO2, (CaO + Na2O + MgO + K2O)/(TiO2 + Al2O3), CaO/Al2O3 and CaO/TiO2). The up-section decrease in propensity to chemical weathering suggested by the aforementioned rock mangetic measurement is further confirmed by these geochemical analyses. Combining the chemical weathering records from the Nihewan Basin, Chinese Loess Plateau, South China Sea and eastern China, we find that the consecutive decreasing trend in chemical weathering intensity during the late Cenozoic is ubiquitous across China. This pattern may result from a long-term decreasing East Asian summer monsoon and increasing East Asian winter monsoon, and thus a consecutive increasing of aridification and cooling in Asia during the Quaternary. Furthermore, the chemical weathering intensity increased from South China to North China during the Quaternary, in line with the decreasing East Asian summer monsoon and increasing East Asian winter monsoon and thus the gradually intensified aridification and cooling from South China to North China. Third, a combined mineral-magnetic and geochemical investigation provides evidences that the large-amplitude alterations of concentration of magnetic minerals mainly result from preservation/dissolution cycles of detrital magnetic minerals in alternately oxic and anoxic depositional environments. The preservation/dissolution model implies that the high-magnetic and low-magnetic cycles of this sedimentary sequence represent glacial and interglacial climate cycles, respectively. This contribute significnatly to our understanding of the link between climate and magnetic properties. Finally, the paleoclimatic implications of these rock magnetic and geochemical characteristics significantly increase our understanding of the general setting of early humans in high northern latitude in East Asia. We propose that the cold and dry climate may have contributed significantly to the expansion and adaptation of early humans, rather than bringing hardship, as is often thought. The relationship between magnetic properties and climate possibly provides valuable information on the climatic context of the Paleolithic sites in the basin, especially whether the occupation occurred during an interglacial or glacial period.
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利用薄片观察、X射线粉晶衍射分析和化学分析方法研究了广西凭祥英安岩风化剖面的形成作用。风化作用初期,母岩中微量黄铁矿的氧化分解导致方解石与绿泥石的迅速分解;风化中期形成了大量的高岭石、伊利石、蒙脱石和蛭石;风化作用高级阶段以高岭石、石英和氧化铁矿物的富集为特征,但仍然存在少量蒙脱石、伊利石和蛭石。风化剖面的部分层段显示出与剖面其他部分明显不同的地球化学特征,即Na的富集和K的亏损。在Al2O3-(CaO+Na2O)-K2O三角图上,风化中期这些层段明显偏离了正常的风化趋势。矿物学和微形貌的研究表明,造成偏离的原因是古地下水引起的正长石的钠长石化作用。
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胶东地区脉岩属碱性超基性岩系(Na2O+K2O=4.67%~5.43%;SiO2=36.70%-39.99%),岩性为单一的橄榄辉石岩。从主量元素(包括CIPW标准矿物组成)和过渡元素组成来看,该岩系近似原始岩浆组成。电子探针结果显示:橄榄石为富镁质橄榄石(贵橄榄石)(Fo=71—90),单斜辉石为透辉石(次透辉石为主)。岩石富集大离子亲石元素(K、Rb、Sr、Th和Ba),但不具有高场强元素(Nb、Ta、Zr和Hf)的亏损,表明岩石形成于大陆板内环境。为地幔橄榄岩低度部分熔融(3.4%)的产物。同时,它具有大陆边缘弧的特性。暗示其为一种滞后型弧岩浆作用的产物。稀土元素特征显示,岩石强烈富集LREE,而相对亏损HREE,暗示了源区的富集特性。Eu/Eu^+=0.89—1.00,总体不表现明显的负Eu异常,暗示斜长石不是主要的分馏矿物相。结合板内碱性岩石的矿物结晶顺序认为,本区岩浆分馏以较弱的橄榄石分馏为主。
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闽东南的海边斜闪煌斑岩脉和赤湖辉长岩脉分别形成于晚白垩世和古新世,为高钾钙碱性和钙碱性系列岩石,具有高Al、Na2O>K2O的特征;岩浆演化过程中可能经历了以橄榄石、单斜辉石为主的结晶分异作用.海边和赤湖基性岩脉具有相对富集大离子亲石元素和轻稀土元素,亏损高强场元素特征,不相容元素蛛网图显示出大陆边缘弧的地球化学特征,以Nb、Ta、Ti负异常为特征;海边和赤湖明显富集轻稀土元素,(La/Yb)N分别为5.0~10.9和11.2~12.0.具有高Sr同位素初始值和低εNd(t)值,海边的(^87Sr/^86Sr)i:0.70577~0.707574,εNd(t):-8.1~-1.8,赤湖的(^87Sr/^86Sr)i:0.70547~0.70552,εNd(t):-0.2~0.6.根据Sr、Nd同位素、微量元素研究及野外地质观察,本区基性岩脉的岩浆在上升侵位过程中未发生地壳物质混染.通过Sr、Nd同位素和微量元素等研究,认为地幔源区的演化与古太平洋板块俯冲密切相关,俯冲流体交代地幔楔、消减洋壳携带的海洋与陆源沉积物参与地幔源区的混合,形成本区基性岩脉的富集地幔源区,大离子亲石元素和轻稀土元素特别富集是俯冲流体与沉积物共同参与源区演化的结果.海边和赤湖基性岩脉形成的构造背景属于活动大陆边缘弧,构造性质应为活动陆缘拉张带(或裂谷带).晚白垩世和古新世,闽东南发生了地壳拉张事件,与中国东南部晚白垩世以来的地壳拉张期次是一致.
Resumo:
对闽西三个地区基性岩脉的地球化学研究发现,该区域的基性岩脉为亚碱性岩石系列,具有高Al、低Ti、Na2O>K2O的特征;相对富集大离子亲石元素,亏损高强场元素。半村辉绿岩脉和拔里角闪辉长岩脉以Nb、Ta、Ti负异常为特征,林子坟辉长辉绿岩脉具有Nb、Ta负异常和Ti弱正异常。半村和拔里的岩脉稀土元素总量高,明显富集轻稀土元素,(La/Yb)N=6.8~8.4;林子坟的岩脉稀土元素总量相对较低,轻稀土元素弱富集,(La/Yb)N=2.0。结合基性岩脉的地球化学特征和区域构造演化分析,初步从为半村和拔里的基性岩脉来自与俯冲作用有关的富大离子亲石元素流体交代的富集地幔;林子坟基性岩脉是软流圈地幔部分熔融的产物,地壳混染作用是其相对富集大离子亲石元素的原因。结合玄武岩构造环境判别图解可知,半村和拔里岩脉具有的大陆边缘弧的特征并不指示基性岩脉形成的构造环境,而是说明其源区受列俯冲板片派牛出来的流体交代作用。半村和拔里岩脉形成于大陆板内拉张带,林子坟岩脉形成于板内裂谷环境,与华南其他地I夏的基性岩脉对比表明,虽然晚中生代华南地区处于拉张的构造背景下,但是岩脉形成的构造环境与微量元素地球化学特征均有明显的差异,反映了各地区构造环境演变和地幔演化的复杂性。