CRYSTAL-STRUCTURES AND MOSSBAUER-SPECTRA OF LAFE1-XMNXO3 AND LAFE1-XCOXO3 (X=0 TO 0.9)

The crystal structures and Mossbauer spectra of various mixed oxides LaFe1-xMnxO3 and LaFe1-xCoxO3 (x = 0 to 0.9) are determined and measured at room temperature. The results indicate that the crystal structure of both the La-Fe-Mn-O and the La-Fe-Co-O sy

MOSSBAUER-EFFECT STUDIES OF THE DIMER OF A BIMETALLIC EU-AL COMPLEX

Mossbauer spectra of the dimer of a bimetallic Eu-Al complex, [(CF3COO)3EuHAl(C2H5)2 . 2 THF]2 are measured at different temperatures (81 to 166 K) and some Mossbauer parameters, such as isomer shift, electric quadrupole splitting and asymmetric parameter, are derived from the experimental spectra. The Debye temperature of the compound determined by a Debye model is 128 K. The results indicate that europium in the organo-europium compound is trivalent and that a bridging hydrogen atom between two europium atoms exists in the dimer. The low Debye temperature implies that the weaker binding force between the europium atom and the lattice may be related to the structure and the chemical bonding in the organometallic compound of europium.

THE STUDY OF MOSSBAUER-EFFECT IN EUBA2CU3O7-Y

EuBa2(Cu1-xFex)3O7-y has been investigated by the Fe-57 and Eu-151 Mossbauer effect. The Fe-57 Mossbauer spectra of the EuBa2(Cu1xFex)3O7-y without or with DC electric current (the current strength I = 0.5A) around the superconducting transition temperature have been measured. The results indicate that the isomer shift (IS) and the quadrupole splitting (QS) of the Fe replacing the Cu(2) vary neither with increasing the Fe content nor with the small DC eletric current passing the superconductor and that the IS and the QS of the Fe replacing the Cu(1) vary with the Fe content. Especially, the IS and the QS of the Fe (D3) replacing the Cu(1) are changed when the small electric current passes the superconductor at 80K.

MOSSBAUER-EFFECT STUDIES OF THE PHASE-TRANSITION PROCESS IN EUROPIUM PENTAPHOSPHATE

Mossbauer spectra of europium pentaphosphate are measured at various temperatures (126 to 200-degrees-C). Some Mossbauer parameters, such as isomer shift, electric quadrupole splitting, and asymmetry parameter of the EFG at Eu-151 nuclei are derived from the experimental spectra. The lattice parameters of the crystal are determined at several temperatures. The experimental results indicate that the crystal structure of europium pentaphosphate changes from monoclinic to orthorhombic. All of the temperature dependences of the Mossbauer parameters provide evidence of a phase transition of the crystal. The phase transition temperature can be determined from the curve of the asymmetry parameter of EFG versus temperature to 165-degrees-C.

RESEARCH ON THE THERMAL-DECOMPOSITION OF THE BIOINORGANIC COMPLEX OF EUROPIUM AND L-GLUTAMINE BY MOSSBAUER-SPECTROSCOPY

Mossbauer spectroscopy has been used to investigate the thermal decomposition of the bioinorganic complex of europium and L-glutamine. The Mossbauer parameters can demonstrate that the water molecules in the complex and the chlorine anion in the hydrogen chloride molecule, dissociated from the complex below 200-degrees-C, are not linked directly to the europium atom. The thermal decomposition process of the complex is discussed and a possible coordination model for the europium L-glutamine complex is also proposed on the basis of the thermogravimetric and derivative thermogravimetric curves, and from some evidence obtained from the Mossbauer effects of some decomposition products of the complex.

MOSSBAUER-EFFECT STUDIES ON SOME BIOINORGANIC COMPLEXES OF EUROPIUM

The bioinorganic complexes of europium with N-acetyl-DL-alanine, N-acetyl-DL-valine, and DL-alanyl-DL-alanine have been synthesized and the Mossbauer spectra at room temperature have been measured for these solid state complexes. The Mossbauer parameters indicate that the water molecules in these complexes are not directly linked to the central europium ion and are outside the coordination sphere of europium and biological ligands, and that the chemical bond between the europium ion and the ligands may be predominantly ionic in character, with the possibility of partial covalent contribution.

OBSERVATION OF MOSSBAUER-EFFECT IN THE HIGH-TEMPERATURE SUPERCONDUCTOR EUBA2CU3O7-X WITH DC ELECTRIC-CURRENT

The difference between the Mossbauer parameters for EuBa2Cu3O7-x with dc electric current and those without dc electric current at 83 K has been observed. The change in isomer shift, electric quadrupole splitting and the asymmetry parameter of the electric field gradient at the Eu-151 nucleus may be caused by the movement of a mass of conduction electrons along a certain direction in the EuBa2Cu3O7-x crystal with a layered structure.

CALCULATIONS OF THE EIGENVALUES OF PURE QUADRUPOLE INTERACTION IN MOSSBAUER-EFFECT STUDIES

Two approximate formulae to calculate the eigenvalues of pure quadrupole interaction in Mossbauer effect studies have been proposed and the eigenvalue coefficients in the formulae have been given for various excited states and ground states of the nucleus with different spin. All the eigenvalues of pure quadrupole interaction between both excited state and ground state of nucleus with spin I = 3/2 divided-by 9/2 and the electric-field gradient with different asymmetry parameter (eta = 0 divided-by 1.0) have been calculated by these formulae. The results show that the accuracies in all the calculations are more satisfactory or same in comparison with those obtained by the formula of Shenoy and Dunlap, especially when the asymmetry parameter of electric-field gradient is larger than 0.8 for the nucleus with spin I = 5/2.

A METHOD OF FITTING TO MOSSBAUER SPECTRUM OF EU-151 AND ITS APPLICATION TO EUROPIUM COMPOUNDS

A method of fitting to Mossbauer spectrum of 151Eu has been proposed. The intensities and the positions of all the possible transitions between the sublevels of the ground state and those of the excited state of nucleus with spin I> 3/2 can be considered at one time in fitting to experimental Mossbauer spectra by this method. The method has been used to fit to the experimental Mossbauer spectra of europium orthophosphate crystal and of europium pentaphosphate crystal, and to derive Mossbauer parameters from...

黔西南高砷煤中砷赋存状态的XAFS和铁的Mossbauer谱研究

利用X 射线吸收精细结构分析(XAFS) 和铁的穆斯堡尔谱(MÊssbauer) 对黔西南高砷煤中砷和铁的存在形式进行了研究。研究发现,高砷煤中的砷主要以高价砷的形式存在,也有少量以As2O3 、砷黄铁矿、砷硫化物的形式存在。除1 个样品中的铁全部以顺磁性针铁矿或超顺磁性的针铁矿的形式存在外,其它样品中的Fe 主要是黄铁矿中的Fe ,约占全铁的60 %～91 %;其次是黄铁钾矾中的Fe ,约占全铁的9 %～40 %。

菱铁矿热转变过程中岩石磁学性质基本特征

利用吉林大栗子铁矿纯菱铁矿样品，系统测量了菱铁矿在空气环境的的磁化特征，揭示出其饱和曙剩磁（ＳＩＲＭ）、剩磁矫顽力（ＨＣＲ）和居里温度（ＴＣ）随加热温度升高而秘珠系列变化，菱放氧化中准稳定态性矿物磁赤铁矿是中间产物之一，并且具有较高的热稳定性，Ｘ射线衍射和穆斯堡尔效应等分析结果证实了岩石磁学研究所揭示的菱铁矿氧化中磁性矿物转变过程，菱铁矿氧化过程中结晶结构的转变可能会影响其氧化产物的磁性特性。

Magnetic properties of tin-doped magnetite nanoparticles

Structural and magnetic characteristics of Fe3-xSnxO4 (x < 0.3) nanoparticles synthesized using the precipitation exchange method have been investigated by X-ray diffraction, transmission electron microscope, Mossbauer spectra, X-ray photoelectron spectroscopy and magnetization measurement. The mean particle dimension decreases from 8 to 6 nm, the lattice parameters enlarge, the saturation magnetization decreases, as well as the magnetization and the coercive field increase, with increasing tin-content. The paramagnetic property of the specimens indicates that the replacement of Fe3+ by Sn4+ on the octahedral sites of Fe3O4 causes a progressive lowering of the Curie temperature and the Curie temperatures of the materials are all lower than that of crystallite tin-doped magnetite. This striking debasing is due to the lessening of the grain size. This is the smallest size reported thus far for paramagnetic tin-doped magnetite particles. (c) 2006 Elsevier B.V. All rights reserved.