On improving the phase stability and thermal expansion coefficients of lanthanum cerium oxide solid solutions

The phase stability of lanthanum cerium oxide (La2Ce2O7), which is stable up to 1400 degrees C, and the thermal expansion coefficient of La2Ce2O7 doped with Ta2O5 or WO3 were studied. The thermal expansion coefficient of La2Ce2O7 below 400 degrees C was increased by adding more CeO2 or doping with either Ta2O5 or WO3.

THE EFFECT ON PHYSICAL-PROPERTIES OF THE SUBSTITUTION OF CA OR BA FOR SR IN NDSRNIO4

A new solid solution series, NdSr(1-x)M(x)NiO(4) (M = Ca: 0.0 less than or equal to x less than or equal to 1.0; M = Ba: 0.0 less than or equal to x less than or equal to 0.6), was synthesized by solid state reaction, and the structures, magnetic and electrical properties and optical spectra of this series have been studied. All the samples crystalized in tetragonal systems, with the exception of NdCaNiO4, which crystallized in the orthohombic system. IR spectra of NdSr1-xCaxNiO4 indicated that the lengths of two Ni-O bonds decrease with increasing Ca content. The electrical conduction changed from metallic-type to semiconductive-type when x greater than or equal to 0.4 (M = Ca, Ba), and the room temperature resistivities of NdSr1-xCaxNiO4 increased with the increase of Ca content. Magnetic susceptibility measurements revealed that Ni+3 ions in all the samplies were in low-spin state over the temperature range 77-300 K.

CIM思想指导下的工业自动化总体技术

工业自动化总体技术是在ＣＩＭ思想指导下产生的实施ＣＩＭ的关键技术。总体技术的核心是总体设计与总体集成技术。本文言及总体技术产生的背景，其宗旨与含义，总体技术方法学，工业自动化系统体系结构与参考模型，以及实践总体技术的概况动向。

碳酸盐岩风化壳母岩的不均一性：来自粒度分析的证据

碳酸盐岩由于酸不溶物含量极低,在形成风化壳的过程中伴随巨大的体积缩小,形成1m厚的风化壳往往需要消耗原岩十几米至几十米。所以对于岩溶地区风化壳,尤其是厚层红色风化壳的机理研究中,母岩的均一性判别是必要的,是风化壳研究的基础。通过对贵州岩溶地区贵阳花溪、湖潮剖面和黔北遵义市新蒲剖面三个典型的残积风化壳的粒度分析表明,碳酸盐岩风化壳成土母岩的不均一性是客观存在的,从粒度分布特征给予了良好的指示。而不均一母岩上发育的风化壳的地球化学行为,也必然偏离建立在均一母岩前提下的风化壳的正常演化方向。此外,常作为表生环境下物源示踪的惰性元素比