30.4nm极紫成像探测器实验研究

中国科学院知识创新方向性项目(061Z291213) 资助课题

X-RAY-SCATTERING FROM A ROUGH-SURFACE AND DAMAGED LAYER OF POLISHED WAFERS

Theoretical and experimental investigations were performed to show the application of x-ray crystal truncation rod scattering combined with x-ray reflectivity in the measurements of surface roughness and near-surface damage of mechanochemically polished wafers. By fitting the measured crystal truncation rod curves it has been shown that polished wafers are divided into three parts -irregular steps on the surface, a damaged thin layer beneath the surface and a perfect bulk. The results show that the root mean square of the surface roughness of mechanochemically polished Fe-doped and/or S-doped InP wafers is one to two atom layers, and that the lateral correlation length of the surface roughness is about 3000-7500 Angstrom. The thickness of the damaged region is found to be about 1000 atom layers.

OPTICAL-PHONON MODES AND FROHLICH POTENTIAL IN ONE-DIMENSIONAL QUANTUM-WELL WIRES

By extending our microscopic model on optical-phonon modes in quantum wells to one-dimensional (1D) quantum-well wires (QWW), the optical displacements and associated electrostatic potentials of optical-phonon modes in 1D QWW are calculated. The modes can be clearly divided into confined LO bulklike, TO bulklike modes, and extended interfacelike modes provided the bulk phonon dispersion is ignored. The character of each type of mode is illustrated with special attention to the interfacelike modes, which are hybrids of longitudinal- and transverse-optical waves from the corresponding bulk materials. Based on the numerical results, approximate analytical formulas for bulklike modes are presented. As in 2D wells, both the optical displacements and Frohlich potentials for the bulklike modes vanish at the interfaces. The finite dispersion of bulk phonons has a more pronounced effect on the 1D phonon modes because interfacelike modes show mixed characteristics of 2D interface and bulklike modes.

大气CO_2浓度升高对红松和长白赤松幼苗非根际土壤微生物的影响

以连续5 a不同CO2浓度处理的长白赤松和红松幼苗为对象,采用CFU(活细胞计数)菌落计数法研究了大气CO2浓度对幼苗非根际土壤微生物数量的影响。结果表明:高浓度CO2(700μmol.mol-1和500μmol.mol-1)处理对长白赤松和红松幼苗非根际土壤细菌数量具有显著的(p<0.01)抑制作用,对真菌数量亦有抑制作用。大气CO2浓度升高对红松幼苗非根际土壤放线菌数量具有抑制作用(p<0.05),而对长白赤松幼苗土壤放线菌数量没有明显的影响。

粉煤灰钝化污泥人工土壤理化性质研究

通过添加不同比例的粉煤灰对城市污泥进行钝化,对钝化污泥的pH值、养分含量及重金属含量变化以及各配比人工土壤的持水性能进行了研究,评价其用于无土排岩场生态修复的可行性.结果表明,当粉煤灰与污泥以Ⅲ(1∶1)和Ⅱ(2∶1)配比时,人工土壤持水性能高于对照(草甸棕壤),以Ⅳ(1∶2)配比时,持水性接近于对照;粉煤灰钝化污泥中养分含量极其丰富,处于高肥力水平,随着粉煤灰添加量的增加,人工土壤的养分含量呈现降低趋势;粉煤灰钝化污泥人工土壤中除了Ⅲ(1∶1)中Ni含量较高,为187.67 mg.kg-1外,各处理中重金属Cd、Pb、Cu、Zn、Cr含量都显著低于国家农用标准(GB 4284-84、GB 8173-87).

科尔沁沙地小叶锦鸡儿人工林防风固沙及改良土壤效应研究

为探讨小叶锦鸡儿防风固沙、改良土壤养分状况和生物活性的能力,选取6年和11年生小叶锦鸡儿人工固沙林为对象,以流动沙丘为对照,研究不同年龄固沙林降低风速和风沙流结构特征、土壤有机质和N,P含量、土壤酶的活性以及微生物生物量C,N,P含量的变化特征。结果表明:在小叶锦鸡儿灌木林内,各个高度风速和输沙量均显著低于流动沙丘,防风固沙效果明显。随着小叶锦鸡儿固沙群落发育时间的增长,其综合防风性能提高,土壤有机质、N,P,K含量和生物活性逐渐得到改善。O～30 cm土层中磷酸单酯酶、蛋白酶、脲酶、蔗糖酶、硝酸还原酶、多酚氧化酶、脱氢酶的活性和土壤微生物生物量C,N和P含量均大幅度提高,其中0~10 cm土层增幅最大。土壤酶中蔗糖酶的活性增加最为迅速,6年和11年生固沙林0～10 cm土层分别是流动沙丘的28.58倍和55.2l倍。小叶锦鸡儿不仅具有较好的防风固沙性能,而且表现出强大的改善土壤养分和生物活性的能力,可作为优良的固沙植物材料在科尔沁沙地大面积推广应用。

Stabilization of poly(lactic acid) by polycarbodiimide

Polycarbodiimide (CDI) was used to improve the thermal stability of poly(L-lactic acid) (PLA) during processing. The properties of PLA containing various amounts of CDI were characterized by GPC, DSC, rheology, and tensile tests. The results showed that an addition of CDI in an amount of 0.1-0.7 wt% with respect to PLA led to stabilization of PLA at even 210 degrees C for up to 30 min, as evidenced by much smaller changes in molecular weight. melt viscosity, and tensile strength and elongation compared to the blank PLA samples. In order to examine the possible stabilization mechanism, CDI was reacted with water, acetic acid, L-lactic acid, ethanol and low molecular weight PLA. The molecular structures of the reaction products were measured with FTIR.

Studies on the coordination of lanthanide with L-hydroxyproline and DL-citrulline

The stability constants of binary and ternary complexes of lanthanide with L-hydroxyproline and DL-citrulline were obtained by using potentiometric titration under the physiological condition(37 degrees C, 0.15 mol/L NaCl). The coordination of lanthanide with the two ligands was discussed.

Classification of jinjiang oysters Crassostrea rivularis (Gould, 1861) from China, based on morphology and phylogenetic analysis

The jinjiang oyster Crassostrea rivularis [Gould, 1861. Descriptions of Shells collected in the North Pacific Exploring Expedition under Captains Ringgold and Rodgers. Proc. Boston Soc. Nat. Hist. 8 (April) 33-40] is one of the most important and best-known oysters in China. Based on the color of its flesh, two forms of C rivularis are recognized and referred to as the "white meat" and 11 red meat" oysters. The classification of white and red forms of this species has been a subject of confusion and debate in China. To clarify the taxonomic status of the two forms of C. rivularis, we collected and analyzed oysters from five locations along China's coast using both morphological characters and DNA sequences from mitochondrial 16S rRNA and cytochrome oxidase 1, and the nuclear 28S rRNA genes. Oysters were classified as white or red forms according to their morphological characteristics and then subjected to DNA sequencing. Both morphological and DNA sequence data suggest that the red and white oysters are two separate species. Phylogenetic analysis of DNA sequences obtained in this study and existing sequences of reference species show that the red oyster is the same species as C. ariakensis Wakiya [1929. Japanese food oysters. Jpn. J. Zool. 2, 359-367.], albeit the red oysters from north and south China are genetically distinctive. The white oyster is the same species as a newly described species from Hong Kong, C. hongkongensis Lam and Morton [2003. Mitochondrial DNA and identification of a new species of Crassostrea (Bivalvia: Ostreidae) cultured for centuries in the Pearl River Delta, Hong Kong, China. Aqua. 228, 1-13]. Although the name C. rivularis has seniority over C. ariakensis and C. hongkongensis, the original description of Ostrea rivularis by Gould [1861] does not fit shell characteristics of either the red or the white oysters. We propose that the name of C. rivularis Gould [1861] should be suspended, the red oyster should take the name C. ariakensis, and the white oyster should take the name C. hongkongensis. (C) 2004 Elsevier B.V. All rights reserved.