Effects of anaerobe in sea bottom sediment on the corrosion of carbon steel

The in-situ study of steel corrosion in sea bottom sediment (SBS) was carried out by Transplanting Burying Plate method (TBP method). It was found that the corrosion rate of steel in the sea bottom sediment with sulfate reducing bacteria (SRB) could be as high as ten times of that in sea bottom sediment without SRB. The experiments in simulated sea bottom sediments with different SRB contents by artificial culturing showed that the electrochemical behavior of steel in the sea bottom sediment with SRB was different from that without SRB. SRB altered the polarization behavior of steel significantly. The environment was acidified due to the activity of SRB and the corrosion of steel was accelerated. The corrosion of carbon steel in sea bottom sediment is anaerobic corrosion, and the main factor is anaerobe. There are SRB commonly in SBS, and the amount of SRB decreases along with the depth of sediment. Because of the asymmetry and variation of sea bottom sediment, the most dangerous corrosion breakage of steel in SBS is local corrosion caused by SRB. So the main countermeasure of corrosion protection of sea bottom steel facilities should be controlling of the corrosion caused by anaerobe.

反水雷与UxV

反水雷作战是一项极其危险的作战任务,而无人作战平台(UxV)的特点决定了其可以降低甚至消除这种危险性,因此在反水雷作战中使用UxV成为必然的发展趋势。本文分析了反水雷作战的特点、各种UxV的特点及其在反水雷作战中的优势,并根据反水雷的需求提出了在UxV中需重点解决的智能控制技术、精确导航与定位技术、传感器及信号处理技术等关键技术。

长白山火山成因—物理机制和化学演化

This thesis is one of the contributions to NSFC project, “The Changbaishan Volcanism and its Links to the Northeast Asia Tectonic System”. The thesis presents our most recent works on Changbaishan Volcanism, on two aspects as (1) the chemical evolution of the Cenozoic volcanism and the physical links of magma genesis, (2) the Holocene activity of the Tianchi Volcano and risks of potential eruption. 1. Chemical evolution and physical links to the Changbaishan Volcanism Physical links to the Chanbaishan Volcanism, just like origins of most of the volcanisms in eastern China, has long been an enigma. A large scale of volcanic activity has dominated many places of eastern China in Meso-Cenozoic. Activity of these volcanisms in eastern China covers several quite different blocks, covers variety of tectonics, and covers a period of time over 200 million years. Such a large-scale and long-lived volcanism in a continental area challenges our knowledge on dynamics of the Earth’s interior. Some works on “Diwa” hypothesis and “lithospheric thinning” hypothesis present possible links between volcanisms and dynamic evolutions of the earth’s interior, but still cannot interpret where are the sources of the heat and fluid, which are essential to the volcanisms. Based on the study of this thesis, we suggest that dynamics of the deep subduction of western Pacific Plate is the critical factor to the Changbaishan Volcanism and volcanisms in NE China, and maybe even essential to most of the Meso-Cenozoic volcanisms in eastern China. In NE China, stagnant slabs flatted in the mantle transition zone (MTZ, ca. 660 km deep) transport and release significant hydrous fluid to the upper mantle. Metamorphism of the deep-subducted slabs and hence a series of mineral phases play an important role in the water transport, exchange, restore, and release. Dehydrated fluid of the wet slab ascending from the MTZ fertile the upper mantle, and also provide upward heat flow which is essential to the magma genesis. Then magma and volcanism occur with the deep subduction from Mesozoic to mordern time in eastern China. To discribe the exact chemical characteristics of the deep subduction releated volcanics is very difficult, because few researches has contributed to the chemical behaviors of fluid and trace elments in the very deep interior of the Earth, such 660 km deep, 410km or 350km where the fluid may ascend and react. However we can still find some chemical characteristics of oceanic subduction. Basalts of the Changbaishan Volcanism have siginficant characteristics of potassium rich, and even can be called a potassic igneous province. If there are only two possible ways, recycled continentical crust or oceanic crust, to fertile the mantle potossium element as we know now, it’s easy to attribute this to the deep-subducted of the west Pacific Plate. To the eastern China, fluid inclusions in mantle xenoliths from the Cenozic basalts also reveal potassium-rich characteristics. This reveals that the same potassium feritle agents may occur in the mantle sources of eastern China. 2. Holocene activiy of the Tianchi Volcano As one of the large volcanic center and complex volcanic cone, the Tianchi Volcano is a dangerous active volcano, with several Holocene eruptions. Among these eruptions, the Millennium Eruption is regardede as one of the biggist eruptions in the world in the last 2000 years. To estimate the potential danger of volcanic eruption, we discuss two essential factors, as (i) volcanic history of Holocene eruptions, including volcanic geolgy, chronnology and chemistry, (ii) state, evolution and relationship of the magma chambers in mantle and crust beneath the Tianchi Volcano.

基于流域—库区—坝区模型“三重边界嵌套”方法的河南济源蟒河口水库渗漏数值模拟研究

Constructing reservoir in mountain area, in order to avoid dangerous reservoir and ensure long-term stable reservoir storage, study on reservoir leakage has been one of research hotspots. How to accurately predict the capacity of leakage and the effect of anti-seepage after reservoir impoundment under different anti-seepage measures is one of the most difficult problems of study on reservoir leakage. The paper took Manghekou Reservoir as a case study, which is located in Jiyuan City, Henan Province, China. Based on the system analysis of the geological and hydrogeological characters in the research area, the hydrogeological conceptual model was established. Then, according to the triplex boundary nested grid model method, using three-dimensional numerical simulation technique, the 3-D groundwater seepage flow numerical model was established in the study area. Based on the model, the change of seepage flow field, the capacity of leakage and the effect of anti-seepage are predicted after Manghekou reservoir impoundment under different condition. The reasonable and reliable anti-seepage measure is selected according to the model. All these provides scientific basis for the design and assessment of anti-seepage measure for the reservoir in mountain area.

西江流域环境河水地球化学研究

River is a major component of the global surface water and CO2 cycles. The chemistry of river waters reveals the nature of weathering on a basin-wide scale and helps us understand the exogenic cycles of elements in the continent-river-ocean system. In particular, geochemical investigation of large river gives important information on the biogeochemical cycles of the elements, chemical weathering rates, physical erosion rates and CO2 consumption during the weathering of the rocks within the drainage basin. Its importance has led to a number of detailed geochemical studies on some of the world's large and medium-size river systems. Flowing in the south of China, the Xijiang River is the second largest river in the China with respect to its discharge, after the Yangtze River. Its headwaters drain the YunGui Plateau, where altitude is approximately 2000 meters. Geologically, the carbonate rocks are widely spread in the river drainage basin, which covers an area of about 0.17xl06 km2, i.e., 39% of the whole drainage basin. This study focuses on the chemistry of the Xijiang river system and constitutes the first geochemical investigation into major and trace elements concentrations for both suspended and dissolved loads of this river and its main tributaries, and Sr isotopic composition of the dissolved load is also investigated, in order to determine both chemical weathering and mechanical erosion rates. As compared with the other large rivers of the world, the Xijiang River is characterized by higher major element concentration. The dissolved major cations average 1.17, 0.33, 0.15, and 0.04 mmol I"1 for Ca, Mg, Na, and K, respectively. The total cation concentrations (TZ+) in these rivers vary between 2.2 and 4.4 meq I'1. The high concentration of Ca and Mg, high (Ca+Mg)/(Na+K) ratio (7.9), enormous alkalinity and low dissolved SiO2/HCO3 ratio (0.05) in river waters reveal the importance of carbonate weathering and relatively weak silicate weathering over the river drainage basin. The major elements in river water, such as the alkalis and alkaline-earths, are of different origins: from rain water, silicate weathering, carbonate and evaporite weathering. A mixing model based on mass budget equation is used in this study, which allows the proportions of each element derived from the different source to be calculated. The carbonate weathering is the main source of these elements in the Xijiang drainage basin. The contribution of rainwater, especially for Na, reaches to approximately 50% in some tributaries. Dissolved elemental concentration of the river waters are corrected for rain inputs (mainly oceanic salts), the elemental concentrations derived from the different rock weathering are calculated. As a consequence, silicate, carbonate and total rock weathering rates, together with the consumption rates of atmospheric CO2 by weathering of each of these lithologies have been estimated. They provide specific chemical erosion rates varying between 5.1~17.8 t/km2/yr for silicate, 95.5~157.2 t/km2/yr for carbonate, and 100.6-169.1 t/km2/yr for total rock, respectively. CO2 consumptions by silicate and carbonate weathering approach 13><109and 270.5x10 mol/yr. Mechanical denudation rates deduced from the multi-year average of suspended load concentrations range from 92-874 t/km2/yr. The high denudation rates are mainly attributable to high relief and heavy rainfall, and acid rain is very frequent in the drainage basin, may exceed 50% and the pH value of rainwater may be <4.0, result from SO2 pollution in the atmosphere, results in the dissolution of carbonates and aluminosilicates and hence accelerates the chemical erosion rate. The compositions of minerals and elements of suspended particulate matter are also investigated. The most soluble elements (e.g. Ca, Na, Sr, Mg) are strongly depleted in the suspended phase with respect to upper continent crust, which reflects the high intensity of rock weathering in the drainage basin. Some elements (e.g. Pb, Cu, Co, Cr) show positive anomalies, Pb/Th ratios in suspended matter approach 7 times (Liu Jiang) to 10 times (Nanpan Jiang) the crustal value. The enrichment of these elements in suspended matter reflects the intensity both of anthropogenic pollution and adsorption processes onto particles. The contents of the soluble fraction of rare earth elements (REE) in the river are low, and REE mainly reside in particulate phase. In dissolved phase, the PAAS-normalized distribution patterns show significant HREE enrichment with (La/Yb) SN=0.26~0.94 and Ce depletion with (Ce/Ce*) SN=0.31-0.98, and the most pronounced negative Ce anomalies occur in rivers of high pH. In the suspended phase, the rivers have LREE-enriched patterns relative to PAAS, with (La/Yb) SN=1 -00-1 .40. The results suggest that pH is a major factor controlling both the absolute abundances of REE in solution and the fractionation of REE of dissolved phase. Ce depletion in river waters with high pH values results probably from both preferential removal of Ce onto Fe-Mn oxide coating of particles and CeC^ sedimentation. This process is known to occur in the marine environment and may also occur in high pH rivers. Positive correlations are also observed between La/Yb ratio and DOC, HCO3", PO4", suggesting that colloids and (or) adsorption processes play an important role in the control of these elements.

滚石机理及滚石灾害评价研究

Rockfall is a geological evolution process involving detachment of blocks or boulders from a slope face, then their free falls, bouncing, rolling or sliding, and finally deposition near the toe of the slope. Many facts indicate that the rockfall can cause hazards to peoples, and it can be regarded as a geological hazard. A rockfall event may only involve a boulder or rock, and also several ones. When there are peoples, buildings, or other man-made establishments within the scope of rockfall trajectory, losses will be possibly induced in tenns of human lives or damages to these facilities. Researches into mechanism, kinematics, dynamics, hazard assessment, risk analysis, and mitigation measures of rockfalls are extremely necessary and important. Occurrence of rockfall is controlled by a lot of conditions, mainly including topographical, geomorphic, geological ones and triggering factors. The rockfall especially in mountainous areas, has different origins, and occurs to be frequent, unexpected, uncertain, in groups, periodic and sectional. The characterization and classification of the rockfalls not only increase knowledge about rockfall mechanism, but also can instruct mitigation of the hazards. In addition, stability of potential rockfalls have various sensitivity to different triggering factors and changes of geometrical conditions. Through theoretical analyses, laboratory experiments and field tests, the author presents some back-analysis methods for friction coefficients of sliding and rolling, and restitution coefficients. The used input data can be obtained economically and accurately in the field. Through deep studies on hazard assessment methods and analysis of factors influencing rockfall hazard, this paper presents a new assessment methodology consisting of preliminary assessment and detailed one. From the application in a 430 km long stretch of the Highway, which is located between Paksho and Nyingtri in Tibet, the methodology can be applicable for the rockfall hazard assessment in complex and difficult terrains. In addition, risk analyses along the stretch are conducted by computing the probability of encountering rockfalls and life losses resulting from rockfall impacts. Rockfall hazards may be mitigated by avoiding hazardous areas, clearness of dangerous rocks, reinforcement, obstructing the rockfalls, leading the rockfalls, warning and monitoring for rockfalls, etc. Seen from present remedial level of rockfall hazards, different mitigation measures, economical and effective buffering units, monitoring tecliniques and consciousness of environmental protection for rockfall mitigations should be further developed.