铂族元素分析方法研究及其在有关地质问题中的应用

Characterization of Platinum Group Elements (PGE) has been applied to earth, space and environmental sciences. However, all these applications are based on a basic prerequisite, i.e. their concentration or ratio in the research objects can be accurately and precisely determined. In fact, development in these related studies is a great challenge to the analytical chemistry of the PGE because their content in the geological sample (non-mineralized) is often extremely low, range from ppt (10~(-12)g/g) to ppt (10~(-9)g/g). Their distribution is highly heterogeneous, usually concentrating in single particle or phase. Therefore, the accurate determination of these elements remains a problem in analytical chemistry and it obstructs the research on geochemistry of PGE. A great effort has been made in scientific community to reliable determining of very low amounts of PGE, which has been focused on to reduce the level of background in used reagents and to solve probable heterogeneity of PGE in samples. Undoubtedly, the fire-assay method is one of the best ways for solving the heterogeneity, as a large amount of sample weight (10-50g) can be hold. This page is mainly aimed at development of the methodology on separation, concentration and determination of the ultra-trace PGE in the rock and peat samples, and then they are applied to study the trace of PGE in ophiolite suite, in Kudi, West Kunlun and Tunguska explosion in 1908. The achievements of the study are summarized as follows: 1. A PGE lab is established in the Laboratory of Lithosphere Tectonic Evolution, IGG, CAS. 2. A modified method of determination of PGE in geological samples using NiS Fire-Assay with inductively coupled plasma-mass spectrometry (ICP-MS) is set up. The technical improvements are made as following: (1) investigating the level of background in used reagents, and finding the contents of Au, Pt and Pd in carbonyl nickel powder are 30, 0.6 and 0.6ng/g, respectively and 0.35, 7.5 and 6.4ng, respectively in other flux, and the contents of Ru, Rh, Os in whole reagents used are very low (below or near the detection limits of ICP-MS); (2) measuring the recoveries of PGE using different collector (Ni+S) and finding 1.5g of carbonyl nickel is effective for recovering the PGE for 15g samples (recoveries are more than 90%), reducing the inherent blank value due to impurities reagents; (3) direct dissolving nickel button in Teflon bomb and using Te-precipitation, so reducing the loss of PGE during preconcentration process and improving the recoveries of PGE (above 60% for Os and 93.6-106.3% for other PGE, using 2g carbonyl nickel); (4) simplifying the procedure of analyzing Osmium; (5)method detection limits are 8.6, 4.8, 43, 2.4, 82pg/g for 15g sample size ofRu, Rh, Pd, Ir, Pt, respectively. 3. An analytical method is set up to determine the content of ultra-trace PGE in peat samples. The method detection limits are 0.06, 0.1, 0.001, 0.001 and 0.002ng/mL for Ru, Rh, Pd, Ir and Pt, respectively. 4. Distinct anomaly of Pd and Os are firstly found in the peat sampling near the Tunguska explosion site, using the analytical method. 5. Applying the method to the study on the origin of Tunguska explosion and making the following conclusions: (1) these excess elements were likely resulted from the Tunguska Cosmic Body (TCB) explosion of 1908. (2) The Tunguska explosive body was composed of materials (solid components) similar to C1 chondrite, and, most probably, a cometary object, which weighed more than 10~7 tons and had a radius of more than 126 m. 6. The analysis method about ultra-trace PGE in rock samples is successfully used in the study on the characteristic of PGE in Kudi ophiolite suite and the following conclusions are made: (1) The difference of the mantle normalization of PGE patterns between dunite, harzburgite and lherzolite in Kudi indicates that they are residual of multi-stage partial melt of the mantle. Their depletion of Ir at a similar degree probably indicates the existence of an upper mantle depleted Ir. (2) With the evolution of the magma produced by the partial melt of the mantle, strong differentiation has been shown between IPGE and PPGE; and the differentiation from pyroxenite to basalt would have been more and more distinct. (3) The magma forming ophiolite in Kudi probably suffered S-saturation process.

水煤浆多级喷嘴的雾化和流动特性

研究了一种多级气动喷嘴对水煤浆燃料的喷雾特性的影响，采用实验方法研究了水煤浆性质、喷嘴操作工况和喷嘴几何结构对射流雾化细度的影响，对喷嘴出口附近的两相流场进行了数值计算，并针对相关结果进行了分析。研究结果证明，该喷嘴对水煤浆燃料有很好的雾化性能，并为喷嘴的进一步优化提供参考数据.

Comparison and combination of several stress relief methods for cubic boron nitride films deposited by ion beam assisted deposition

Cubic boron nitride (c-BN) films were prepared by ion beam assisted deposition (IBAD) technique, and the stresses were primary estimated by measuring the frequency shifts in the infrared-absorption peaks of c-BN samples. To test the possible effects of other factors, dependencies of the c-BN transversal optical mode position on film thickness and c-BN content were investigated. Several methods for reducing the stress of c-BN films including annealing, high temperature deposition, two-stage process, and the addition of a small amount of Si were studied, in which the c-BN films with similar thickness and cubic phase content were used to evaluate the effects of the various stress relief methods. It was shown that all the methods can reduce the stress in c-BN films to various extents. Especially, the incorporation of a small amount of Si (2.3 at.%) can result in a remarkable stress relief from 8.4 to similar to 3.6 GPa whereas the c-BN content is nearly unaffected, although a slight degradation of the c-BN crystallinity is observed. The stress can be further reduced down below I GPa by combination of the addition of Si with the two-stage deposition process. (c) 2008 Elsevier B.V. All rights reserved.

Electronic investigation of self-organized InAs quantum dots

Deep Level Transient Spectroscopy (DLTS) has been applied to investigate the electronic properties of self-organized InAs quantum dots. The energies of electronic ground states of 2.5ML and 1.7ML InAs quantum dots (QDs) with respect to the conduction band of bulk GaAs are about 0.21 eV and 0.09 eV, respectively. We have found that QDs capture electrons by lattice relaxation through a multi-phonon emission process. The samples are QDs embedded in superlattices with or without a 500 Angstrom GaAs spacing layer between every ten periods of a couple of GaAs and InAs layers. The result shows that the density of dislocations in the samples with spacer layers is much lower than in the samples without the spacer layers.

多粒度多维度软件过程度量和改进方法研究

随着软件对社会各领域、各层次的渗透，软件逐渐转变为一种对社会团体、 甚至对社会公众的服务，软件的规模越来越大、用户需求越来越多、功能和性能 要求也越来越复杂。因此，对软件的可用性、可靠性、可信性等质量要求不断提 高。伴随着软件业的逐渐发展，软件过程技术逐渐被应用于软件产品的开发当中。 “质量形成于产品的生产过程”这一理念逐渐被软件组织所接受。其核心思想体 现在通过对软件过程的策划、控制和改进来保证软件产品的质量，进而提高软件 组织的经营业绩。软件过程度量作为软件过程管理和过程改进的关键活动，越来 越为软件组织所重视。 通过实施过程管理，能够刻画项目或过程目标的满足程度，找到造成过程 或产品重大偏差的根本原因，进而实施过程改进。然而，在软件过程度量实施期 间，软件组织面对不同的软件开发过程、众多的过程性能度量指标、复杂的统计 分析方法，既要考虑量化管理方法的合理性和复杂程度，又要权衡量化管理的实 施成本，这使得实施有效的过程度量充满挑战。本文基于经验软件工程方法，提 出一种多粒度多维度软件过程度量框架，以及实现该框架的关键技术：软件过程 性能基线的建立和维护方法；同时介绍了该框架下的软件项目进度量化控制模 型，支持软件组织实施有效的过程管理和改进。 本文的主要贡献包括： 提出了一种多粒度多维度软件过程度量框架(Multi-granularity Multi-dimensional software Process Measurement Framework，M2-PMF)，该框架通 过综合考虑软件过程管理和改进的必要信息所属的特征维度和软件组织的过程 管理粒度，自底向上的通过实体层、度量分析层和目标层指导软件组织建立一套 可以覆盖软件全生命周期的、开放的、支持过程改进的综合指标体系和模型。支 持软件组织裁减和定制确定环境下的度量体系，清晰了解其软件过程能力和性 能，提高软件组织对软件过程的控制能力，保障软件开发过程和软件产品的质量。 提出了基于统计分析的过程性能基线的建立和改进方法（Baseline – Statistic - Refinement， BSR），该方法可以有效地建立和维护过程性能基线，支持软件 组织从定性管理提升到定量管理。该方法应用波动图，在过程尚不稳定、数据样 本不足的情况下尽可能多的获得过程改进信息，识别过程改进机会，确定过程改 进途径，帮助软件组织高效地改进其过程中明显的弱项。在过程逐步稳定之后， 利用控制图、排列图、因果图、散点图等统计工具，分析过程性能，建立过程性 多粒度多维度软件过程度量和改进方法研究 ii 能基线，并不断精化。 在M2-PMF 框架下，提出了基于统计过程控制（Statitical Process Control， SPC）和挣值管理（Earned Value Management，EVM）的项目进度量化控制模型 SEVM，该方法通过对项目进度指数的统计控制，分析其稳定性，并通过估算模 型，根据项目当前挣值数据推算项目总进度偏差，并加以控制。支持软件组织对 项目进度进行量化控制，提高了项目按期交付的可能性。 最后，介绍了本文提出的过程度量框架和量化管理方法在国内多家软件组 织中的实际应用。应用案例表明，本文的方法和模型具有广泛的适应性和高度的 可操作性。应用本文方法能够对项目进行有效的估算、度量和控制，进而提高产 品质量并改善客户满意度。

Electronic investigation of self-organized InAs quantum dots

Deep Level Transient Spectroscopy (DLTS) has been applied to investigate the electronic properties of self-organized InAs quantum dots. The energies of electronic ground states of 2.5ML and 1.7ML InAs quantum dots (QDs) with respect to the conduction band of bulk GaAs are about 0.21 eV and 0.09 eV, respectively. We have found that QDs capture electrons by lattice relaxation through a multi-phonon emission process. The samples are QDs embedded in superlattices with or without a 500 Angstrom GaAs spacing layer between every ten periods of a couple of GaAs and InAs layers. The result shows that the density of dislocations in the samples with spacer layers is much lower than in the samples without the spacer layers.

高效液相色谱-质谱联用法分析龙胆中的环稀醚萜类成分

A rapid method was developed to analyze the extract of the Gentiana scabra Bge. by using high performance liquid chromatograghy-electrospray ionization multi-stage tandem mass spectrometry (HPLC-ESI-MSn). 5 compounds in Gentiana scabra Bge. are identified in the positive and negative mode. The research results demonstrate that the HPLC-ESI-MSn can quickly identified the components in Gentiana scabra Bge. . It also can provide the information of the relative molecular mass and chemical structure of the compounds in the extract of the Gentiana scabra Bge. .