室内海底沉积物热导率测量的原理与方法——以TK04热导率测量系统为例

沉积物热导率是计算海底热流的一个重要参数。文中以TK04热导率测量系统为

纳米硅薄膜制备及HIT太阳能电池

在较高工作气压(332.5～399Pa)下,采用等离子增强化学气相沉积(PECVD)工艺制备了优质的本征纳米硅薄膜及掺磷的纳米硅薄膜,并采用X射线衍射(XRD)、拉曼散射(Raman) 测试技术对其进行了测试和分析.结果表明纳米硅薄膜的XRD谱中存在(111)、(220)和(331)峰位;Raman谱中显示出其薄膜中的晶粒的大小(2～5nm)符合纳米晶的要求.将制备的纳米硅薄膜初步用于栅极/ITO/n-nc-Si∶H/i-nc-Si∶H/p-c-Si/Al/Ag结构的异质结(HIT)太阳能电池,开路电压(Voc)达404mV,短路电流密度(Jsc)可达到34.2mA/cm2(AM1.5,100mW/cm~2,25℃).

美国的土壤侵蚀与防治

<正> 美国是世界农业大国,除遇特大自然灾害外,农业生产一直保持长期稳定发展的态势.1990年谷物的生产量达到3.13亿t,预测到2000年谷物产量可达4.53亿t,1985～2000年谷物平均增长速度为1.8%.美国的农业生产之所以能取得如此辉煌的成就有多种原因,其中政府重视土壤保护是最主要的原因之一.80年代初期,美国的农业科学家皮门特尔就曾向全世界发出警告,指出土壤侵蚀已成为全世界第一号环境问题,呼吁人们注意土壤侵蚀给农业生产带来的严重危害.而当时的美国同样面临着土壤侵蚀的严峻形势.深入的研究表明,土壤侵蚀恶性发展的根本原因不在气候变异、水旱等自然灾害,造成土壤侵蚀的根本原因来自人类对自然界的干扰,其中包括不合理的土地利用、滥砍滥伐、破坏森

基于县域要素的三江源地区旅游扶贫模式探讨

随着我国旅游业的兴起,人们越来越认识到旅游在消除贫困上的潜力和能力,然而,要让旅游真正朝着有利于消除贫困的方向发展,必须对旅游的发展方式加以调整,因地制宜地选择旅游扶贫的模式。本文构建了三江源地区各县贫困程度和旅游资源禀赋评价指标体系,定量测度了各评价区的贫困度和旅游资源禀赋综合得分,并采用四象限法划分出资高贫低、双高、双低、资低贫高4种旅游扶贫类型区,在此基础上,提出适用于整个三江源地区的旅游扶贫基本模式为政府主导模式,以及各类型区的旅游扶贫辅助模式,即资高贫低区的政企合作模式,双高区的项目推动模式,双

Layer-by-layer assembly of single-charged ions with a rigid polyampholyte

A novel method to produce multilayer films has been developed by layer-by-layer assembly of single-charged ions and a rigid polyampholyte containing unbalanced charges in each of its repeat units.

Synthesis and characterization of electroactive and biodegradable ABA block copolymer of polylactide and aniline pentamer

A triblock copolymer PLA-b-AP-b-PLA (PAP) of polylactide (PLA) and aniline pentamer (AP) with the unique properties of being both electroactive and biodegradable is synthesized by coupling an electroactive carboxyl-capped AP with two biodegradable bihydroxyl-capped PLAs via a condensation reaction. Three different molecule weight PAP copolymers are prepared. The PAP copolymers exhibit excellent electroactivity similar to the AP and polyaniline, which may stimulate cell proliferation and differentiation. The electrical conductivity of the PAP2 copolymer film (similar to 5 x 10(-6) S/cm) is in the semiconducting region. Transmission electron microscopic results suggest that there is microphase separation of the two block segments in the copolymer, which might contribute to the observed conductivity. The biodegradation and biocompatibility experiments in vitro prove the copolymer is biodegradable and biocompatible. Moreover, these new block copolymer shows good solubility in common organic solvents, leading to the system with excellent processibility. These biodegradable PAP copolymers with electroactive function thus possess the properties that would be potentially used as scaffold materials for neuronal or cardiovascular tissue engineering.

Isotope effect in proton-transfer and association-dissociation reactions for butylamine by ultrasonic relaxation methods

Ultrasonic absorption coefficients were measured for butylamine in heavy water (D2O) in the frequency range from 0.8 to 220 MHz and at concentrations from 0.0278 to 2.5170 mol dm(-3) at 25 degrees C; two kinds of relaxation processes were observed. One was found in relatively dilute solutions (up to 0.5 mol dm(-3)), which was attributed to the hydrolysis of butylamine. In order to compare the results, absorption measurements were also carried out in light water (H2O). The rate and thermodynamic parameters were determined from the concentration dependence of the relaxation frequency and the maximum absorption per wavelength. The isotope effects on the diffusion-controlled reaction were estimated and the stability of the intermediate of the hydrolysis was considered while comparing it with the results for propylamine in H2O and D2O. Another relaxation process was observed at concentrations greater than 1 mol dm(-3) in D2O. In order to examine the solution characteristics, proton NMR measurements for butylamine were also carried out in D2O. The chemical shifts for the gamma- and delta-proton in butylamine molecule indicate the existence of an aggregate. From profiles of the concentration dependence of the relaxation frequency and the maximum absorption per wavelength of sound absorption, the source of the relaxation was attributed to an association-dissociation reaction, perhaps, associated with a hydrophobic interaction. The aggregation number, the forward and reverse rate constants and the standard volume change of the reaction were determined. It was concluded from a comparison with the results in H2O that the hydrophobic interaction of butylamine in D2O is stronger than that in H2O. Also, the isotope effect on this reaction was interpreted in terms of the solvent structure.