On the acid-base stability of Keggin Al-13 and Al-30 polymers in polyaluminum coagulants

The acid-base stabilities of Al-13 and Al-30 in polyaluminum coagulants during aging and after dosing into water were studied systematically using batch and flow-through acid-base titration experiments. The acid decomposition rates of both Al-13 and Al-30 increase rapidly with the decrease in solution pH. The acid decompositions of Al-13 and Al-30 with respect to H+ concentration are composed of two parallel first-order and second-order reactions, and the reaction orders are 1.169 and 1.005, respectively. The acid decomposition rates of Al-13 and Al-30 increase slightly when the temperature increases from 20 to ca. 35 A degrees C, but decrease when the temperature increases further. Al-30 is more stable than Al-13 in acidic solution, and the stability difference increases as the pH decreases. Al-30 is more possible to become the dominant species in polyaluminum coagulants than Al-13. The acid catalyzed decomposition and followed by recrystallization to form bayerite is one of the main processes that are responsible for the decrease of Al-13 and Al-30 in polyaluminum coagulants during storage. The deprotonation and polymerization of Al-13 and Al-30 depend on solution pH. The hydrolysis products are positively charged, and consist mainly of repeated Al-13 and Al-30 units rather than amorphous Al(OH)(3) precipitates. Al-30 is less stable than Al-13 upon alkaline hydrolysis. Al-13 is stable at pH < 5.9, while Al-30 lose one proton at the pH 4.6-5.75. Al-13 and Al-30 lose respective 5 and 10 protons and form [Al-13] (n) and [Al-30] (n) clusters within the pH region of 5.9-6.25 and 5.75-6.65, respectively. This indicates that Al-30 is easier to aggregate than Al-13 at the acidic side, but [Al-13] (n) is much easier to convert to Alsol-gel than [Al-30] (n) . Al-30 possesses better characteristics than Al-13 when used as coagulant because the hydrolysis products of Al-30 possess higher charges than that of Al-13, and [Al-30] (n) clusters exist within a wider pH range.

30.4nm极紫成像探测器实验研究

中国科学院知识创新方向性项目(061Z291213) 资助课题

近30年来陕北黄土高原土地利用动态变化分析

基于1975年的LandsatMSS影像,1986年、1997年和2006年的Landsat TM影像,利用遥感影像的计算机自动分类和目视解译,得到这4a的土地利用信息。利用ERDAS中的GIS分析模块和统计方法对这4a的土地利用图进行统计分析,得到1975-1986年、1986-1997年和1997-2006年这3个时间段的土地利用变化的数量、速度、幅度、空间格局特征。结果表明:耕地经历了一个先增加后减少的过程,草地、林地先减少后增加,居民地一直处于增加状态,未利用地从整体上来说处于减少状态,只不过在中期有一定数量的波动;在前期和中期土地利用类型间的相互转化基本一致,后期土地利用类型间的相互转化有所增强;耕地、草地、林地和未利用地是该地区土地利用变化的主导类型,主要是耕地、草地与其它土地利用类型间的相互转化。

纳秒激光诱导C_(60)分子碎裂中轻碎片离子C_n~+(n<30)的产生机理研究

采用飞行时间质谱计测量了纳秒激光诱导C60分子碎裂中轻碎片离子Cn+(n≤11)的初始平均动能,结果显示轻碎片离子具有相同的初始平均动能(约为0.34 eV),并且该动能在一定范围内不随激光通量的变化而明显改变.结合前人的实验结果,对纳秒激光诱导C60分子碎裂中轻碎片离子Cn+(n<30)的主要产生模式作了新的阐述,即C60分子级联发射15个C2分子和一个电子形成自身不稳定的C3+0离子,在皮秒时间尺度内C3+0离子的笼形结构塌陷,进而轻碎片离子产生.