LIQUID-PHASE EPITAXY GROWTH AND PROPERTIES OF GAINASSB/ALGAASSB/GASB HETEROSTRUCTURES

The GaInAsSb/AlGaAsSb/GaSb heterostructures were grown by the liquid phase epitaxy (LPE) technique. The materials were characterized by means of optical microscopy, electroprobe microanalysis (EPMA), double-crystal X-ray diffraction, capacitance-voltage (C-V) and Van der Pauw measurments, infrared absorption spectra, photoluminescence and laser Raman scattering. The results show that the materials have fine surface morphology, low lattice mismatch and good homogeneity. Room-temperature light-emitting diodes with an emission wavelength of 2.2-mu-m were obtained by using the GaInAsSb/AlGaAsSb DH structures.

番茄专用肥肥效初步研究

番茄专用肥肥效初步研究刘子江，崔桂霞，武冠云（中国科学院沈阳应用生态研究所）赵彩霞，张玉兴王述麟，王阳（沈阳市于洪区畜牧副食局）（沈阳市东陵区畜牧副食局）随着农业生产的发展和科学施肥技术的实施，专用肥的应用愈来愈广泛。专用肥的使用效果，是肥料研究领域...

土壤——作物体系黄曲霉产毒特征分析

本文利用大米培养基,对黄曲霉菌株进行了产毒试验,利用薄层层析法进行了检测,分析了辽宁地区土壤——作物体系中黄曲霉的产毒特征。结果表明黄曲霉菌株平均产毒率为40%,黄曲霉S品系都是产毒品系,大部分L品系菌株属于不产毒品系。S品系在黄曲霉构成中的比重,将在极大程度上决定和反映了黄曲霉菌株产毒率的大小。试验中未检出强产毒菌株,说明辽宁地区土壤——作物体系中黄曲霉菌株具有较低的产毒潜力。

Observation of twisting growth of branched polyethylene single crystals formed from the melt

The twisting growth of a branched polyethylene single crystal formed from the melt was observed directly by means of transmission electron and atomic force miscroscopy. The surface stress asymmetry arising from the asymmetry of the surface-fold structure and, chain tilting resulted in the twisting growth of the single crystals. The handedness of the twisting lamellae was consistent With the chain-tilting direction. When multilayer lamellae piled up in a thicker film, the lamellar twist would be inevitably causing screw dislocations.

Organic template-directed crystallization of the complex fluoride NH4MnF3 with perovskite structure

(100)-oriented NH4MnF3 perovskite with different morphologies have been obtained in situ via an organic template; experimental results can be rationalized in terms of electrostatic interactions and lattice matching between the organic template and the ions undergoing nucleation.

Synthesis and structure of alpha-B-Keggin type heteropoly complex K5H[Co-4(VW9O33)(2)]center dot 5H(2)O

A new complex K5H[Co-4(VW9O33)(2)]. 5H(2)O was prepared and its structure was determined by X - ray diffraction analysis. The anion has alpha - beta - Keggin structure. Two (VW9O33)(7-) moieties (alpha - B isomers) are linked via four Co(11)O-6 groups. The single crystal of the title complex is monoclinic P2(1/n) with a = 1.2307(3) nm, b = 2.1250(4) nm, c = 1.5817(3) nm, beta = 91.86(3)degrees, V = 4.1343 (14) nm(3), R = 0.0895, R-w = 0.2180.

α-B-Keggin型杂多化合物K_5H[Co_4(VW_9O_(33))_2]·5H_2O的合成和结构

合成了新化合物K_5H[Co_4(VW_9O_(33))·5H_2O,并运用IR,UV-ViS,DTA和单晶X射线衍射对其结构进行了表征.测定结果证实标题化合物具有α-B-Keggin型结构,两个(VW_9O_(33)~(7-)结构单元由四个Co(Ⅱ)O_6 八面体连接.杂多化合物属单斜晶系P2_(1/n),a=1.2307(3)nm,b=2.1250(4)nm,c=1.5817(3)nm,β=91.86(3)°,V=4.1343(14)nm~3,R=0.0895,R_w=0.2180.

PREPARATION AND MICROSTRUCTURAL CHARACTERIZATION OF SURFACE-MODIFIED NANOSIZED SNO2 PARTICLES

Nanosized stannic oxide particles modified with a layer of DBS were successfully prepared through the colloidal chemical method and their microstructures were characterized. FTIR and XPS were used for the determination of the main components. It can be proved that the nanosized SnO2 particles were capped by DBS. The sizes of particle were determined by TEM and XRD. By the investigation of XPS, we can conclude that there are a lot of oxygen vacancies in the surface of the nanoparticulates. Based on this conclusion, the ESR signal of the sample can be explained.

表面修饰的二氧化锡纳米粒子的制备及微结构表征

采用胶体化学法制得表面包覆有ＤＢＳ的二氧化锡纳米粒子，并运用一系列手段对其微结构进行了表征。结果表明：样品为表面包覆有ＤＢＳ的二氧化锡纳米粒子的集合体，粒度表面有大量氧空位，粒度分布均匀且单分散性好，其平均粒径为１．５ｎｍ，表面修饰以后的二氧化锡纳米粉体是以无定形结构为主的纳米微晶结构，体相二氧化锡为抗磁性物质，而表面修饰后的纳米微晶的顺磁共振谱中出现一条顺磁信号，根据纳米微晶的结构特点对此信号进行了解释。

数字模拟在电化学中的应用

本文通过列举大量文献评述了数字模拟在电化学中的进展,包括了模拟的基本方法,边界值的处理及其在电化学中的应用情况。数字模拟已成为了解电化学过程的极好方法。

自旋置换对称体系多脉冲及二维核磁共振实验的密度算符描述(Ⅱ)——多量子积算符方法

在对称化乘积算符(简称SAPO)方法基础上提出了多量子积算符(简称MQCPO)方法。改进的密度算符理论对I_nS(I=1/2,S=1/2;n为任意正整数)自旋体系多脉冲及二维核磁共振实验的描述普遍适用。MQCPO与SAPO从不同角度反映了自旋体系的对称性,故它们之间存在简单线性关系。文中给出I_n(I=1/2,n=2,3)自旋体系MQCPO的SAPO表示。MQCPO有利于自由演化过程的描述,而脉冲作用的描述则是SAPO为佳;利用MQCPO与SAPO的线性关系及SAPO笛卡儿分量的坐标轮换性质,“z”表象下脉冲作用的描述变得简单而直观。对异核谱剪辑及自旋拓扑滤波(spin topology filtration)等实验脉冲序列的分析,该方法是方便的。