An augmented method for free boundary problems with moving contact lines

An augmented immersed interface method (IIM) is proposed for simulating one-phase moving contact line problems in which a liquid drop spreads or recoils on a solid substrate. While the present two-dimensional mathematical model is a free boundary problem, in our new numerical method, the fluid domain enclosed by the free boundary is embedded into a rectangular one so that the problem can be solved by a regular Cartesian grid method. We introduce an augmented variable along the free boundary so that the stress balancing boundary condition is satisfied. A hybrid time discretization is used in the projection method for better stability. The resultant Helmholtz/Poisson equations with interfaces then are solved by the IIM in an efficient way. Several numerical tests including an accuracy check, and the spreading and recoiling processes of a liquid drop are presented in detail. (C) 2010 Elsevier Ltd. All rights reserved.

化学不稳定性和同位素分布的同位旋效应

采用同位旋相关的量子分子动力学模型 ,研究了在轰击能量为 40MeV u和 10 0MeV u时 ,1 1 2 Sn +1 1 2 Sn和1 2 4Sn +1 2 4Sn反应产物的同位素分布 .发现在 40MeV u时 ,同位素分布与入射体系的同位旋密切相关 ;而在 10 0MeV u时 ,对这两种不同同位旋体系给出几乎相同的同位素分布 .这种同位素分布的能量依赖性为研究化学不稳定性及其与力学不稳定性的竞争提供了新途径

Separation and identification of compounds in Rhizoma chuanxiong by comprehensive two-dimensional liquid chromatography coupled to mass spectrometry

A comprehensive two-dimensional liquid chromatographic separation system based on the combination of a CN column and an ODS column is developed for the separation of components in a traditional Chinese medicine (TCM) Rhizoma chuanxiong. Two columns are coupled by a two-position, eight-port valve equipped with two storage loops and controlled by a computer. The effluent is detected by both the diode array detector and atmospheric pressure chemical ionization (APCI) mass spectrometer. More than 52 components in the methanol extract of R. chuanxiong were resolved and 11 of them were preliminary identified according to their UV and mass spectra. (C) 2004 Elsevier B.V. All rights reserved.

黄河三角洲湿地生态系统的形成及其保护

通过对黄河三角洲新生湿地的野外调查,利用TM陆地卫星影像图的判读,结合黄河尾闾变动的历史资料分析,结果表明,黄河三角洲新生湿地是多泥沙的黄河淤积和海岸蚀退所形成.受区域气候、地貌、地质沉积、土壤、植被的相互作用和互相影响,形成4.5×105hm2的湿地,其中有6.84×104hm2的人工湿地.湿地生态类型随着黄河尾闾摆动和海退陆进程度而变化,自海洋向陆地依次为潮下带水生生态系统潮间带湿地生态系统潮上带盐生生态系统芦苇獐茅湿地生态系统草甸湿地生态系统陆上农田生态系统.该系统资源丰富,共有野生动物1524种,鸟类300种,鱼类1040种.石油开发和近年来黄河断流对湿地产生一定影响,应在开发利用中加强管理和保护

石灰性土壤供氮能力几种化学测定方法的评价研究

以采自于黄土高原差异较大的25个农田耕层石灰性土壤为供试土样,以淋洗和未淋洗土壤起始NO3--N小麦和玉米两季盆栽试验作物累积吸氮量为参比,对8种反映旱地土壤供氮能力的化学方法进行比较研究。结果表明,在一定程度上,可用有密切关系的土壤全氮或有机质,反映有机氮或全氮存在较大差异的土壤供氮能力,但其灵敏性较差。石灰性土壤矿质氮,特别是NO3--N与未淋洗土壤起始NO3--N作物吸氮量之间有较高相关性(r=0.884,P<0.01),而与淋洗土壤起始NO3--N作物吸氮量间相关系数仅为0.472(P<0.05),说明矿质氮可反映土壤当前供氮水平,而不能反映土壤潜在供氮能力;石灰性土壤起始NO3--N对各化学方法与作物吸氮量之间相关性影响较大。酸性高锰酸钾法既可反映土壤潜在供氮能力,也可反映土壤总供氮能力;酸性高锰酸钾法的修订方法,即硫酸—高锰酸钾法提取出的NH4+-N值接近于KCl水浴法提取出的NH4+-N值,该方法在反映土壤总供氮能力方面与酸性高锰酸钾法相当,但在反映土壤潜在供氮能力方面不及酸性高锰酸钾法优越。KCl水浴法在评价石灰性土壤供氮能力方面,与酸性高锰酸钾法的效果基本相同;沸水浸取法和NaHCO3-UV...

黄土高原旱区长期不同轮作施肥对土壤供氮能力的影响

自 1 98 4年开始的长期不同轮作与施肥试验表明 :种植作物可提高土壤供氮能力 6.88%～ 36.58%,以种植苜蓿提高幅度最大 ,是裸地的 1 .37倍。长期施用氮肥、磷肥、有机肥及三者配施可提高土壤供氮能力 9.8%～ 1 33.98%,其中以施氮、磷及有机肥玉米连作提高幅度最大。不同轮作系统中土壤供氮能力 :粮草 3年轮作 >粮草 8年轮作 >粮豆 3年轮作 >粮饲豆 4年轮作 ;种植作物可有效增加土壤有机氮水平 ,提高剖面土壤供氮能力。施用有机肥可有效地增加深层土壤供氮潜力并在 1 0 0 cm处出现迅速减小的现象

乌丹地区文冠果生物学特性及物候观测

通过野外定枝追踪,对乌丹地区文冠果年生长周期的物候、生殖过程进行连续观测,研究了文冠果的果实生长进程与有效积温的关系、数量动态和落花落果率.结果表明:文冠果物候变化与有效积温之间存在极显著的线性函数关系;雄花花丝的伸长和花药的开裂在时间上具有先后性;文冠果果实生长发育过程中经历3次落果,授粉率为26.4,落花率达73.6,落果率可达92.9,落花、落果现象十分严重;6月上中旬果实的纵径生长较快,6月中下旬果实横径生长较快,纵横径比可达2.17;个体间物候有一定的差异,不利于文冠果异株授粉和授粉率的提高.

Two novel molybdenum complexes containing [Mo2O2S2](2+) fragment: synthesis, crystal structures and catalytic studies

Mo2O2S2(HGly)(GlY)(2) 1 and K-6[Mo2O2S2(nta)(2)][Mo2O2S2(ntaH)(2)]center dot 4H(2)O 2 were synthesized by the reactions of (NH4)(2)MoS4 and amino acids L (L = glycine, nitrilotriacetic acid) in ethanol-water medium at ambient temperature. The two complexes were characterized by elemental analysis, infrared spectra, UV-visible spectra, TG-DTA and XPS.

Review on study of resonance electron capture mass spectrometry

Resonance electron capture mass spectrometry, in which an additional information coordinate, the energy of electron capture, is applied, has a high sensitivity and a high specificity. It is extensively used to study the structure elucidation, the mechanism of ion formation and the detection, identification and quantification of organic substances in mixture.

共振电子捕获质谱研究进展

利用额外的信息坐标——电子捕获的能量的共振电子捕获质谱具有高灵敏度和高专一性．在进行结构分析、离子形成机理研究及混合物中某种特定化合物的检测方面，共振电子捕获质谱都有广泛的应用