Relationships between precipitation, soil water and groundwater at Chongling catchment with the typical vegetation cover in the Taihang mountainous region, China

Vegetation cover plays an important role in the process of evaporation and infiltration. To explore the relationships between precipitation, soil water and groundwater in Taihang mountainous region, China, precipitation, soil water and water table were observed from 2004 to 2006, and precipitation, soil water and groundwater were sampled in 2004 and 2005 for oxygen-18 and deuterium analysis at Chongling catchment. The soil water was sampled at three sites covered by grass (Carex humilis and Carex lanceolata), acacia and arborvitae respectively. Precipitation is mainly concentrated in rainy seasons and has no significant spatial variance in study area. The stable isotopic compositions are enriched in precipitation and soil water due to the evaporation. The analysis of soil water potential and isotopic profiles shows that evaporation of soil water under arborvitae cover is weaker than under grass and acacia, while soil water evaporation under grass and acacia showed no significant difference. Both delta O-18 profiles and soil water potential dynamics reveal that the soil under acacia allows the most rapid infiltration rate, which may be related to preferential flow. In the process of infiltration after a rainstorm, antecedent water still takes up over 30% of water in the topsoil. The soil water between depths of 0-115 cm under grass has a residence time of about 20 days in the rainy season. Groundwater recharge from precipitation mainly occurs in the rainy season, especially when rainstorms or successive heavy rain events happen.

Land use and water quality response in the northern region of Changxing County

In this paper, taking the northern region of Changxing County for example, with ammonia nitrogen as a pollution assessment index, we used an improved export coefficient method for estimate polluting load of non-point source pollution (NSP) and the social pollution survey data in the study area to estimate point source pollution. By comparing the total pollution output and the national surface water environmental quality standards find that the whole study area achieves the second water quality standard. However, Jiapu Township exceeds the water quality standards seriously because of the superfluous point source pollution. The water quality of other Townships is good. Further analysis showed that different types of land use and proportions in the northern region of Changxing County have a significant impact on the non-point source pollution, the general law is farmland contributes the largest share of the non-point source pollution output, followed by residential area and bare land, besides, with the increase in the proportion of forest and the decrease of farmland and residential area, the non-point source pollution reduces gradually. © 2010 IEEE.

The characteristics of land cover and macroscopical ecology changes in the source region of three rivers in Qinghai-Tibet plateau during last 30 years

We obtained four phases of land cover spatial data sets by interpreting MSS images of middle and late 1970s and three phases of TM images of late 1980s, 2004 and 2008 based on field investigation in Three Rivers' Source Region. We analyzed the temporal and spatial characteristics of land cover and macro ecological changes in Three Rivers' Source Region in Qinghai-Tibet plateau since middle and late 1970s. Indicated by land cover condition index change rate and land cover change index, land cover and macroscopical ecological condition degenerated (7090 period Zc -0.63, LCCI -0.58)-obviously degenerated (9004 period, Zc -0.94, LCCI -1.76)-slightly meliorated (0408 period, Zc 0.06, LCCI 0.33). This course was jointly driven by climate change, grassland stocking pressure and implement of ecological construction project.

STRUCTURAL EVOLUTION AND COMPOSITION CHANGE IN THE SURFACE REGION OF POLYPROPYLENE/CLAY NANOCOMPOSITES ANNEALED AT HIGH TEMPERATURES

A model experiment was done to clear the formation mechanism of protective layers during combustion of polypropylene (PP)/organically modified montmorillonite (OMMT) nanocomposites. The investigation was focused on the effects of annealing temperature on the structural changes and protective layer formation. The decomposition of OMMT and degradation of PP/OMMT nanocomposites were characterized by means of thermogravimetric analysis (TGA). The structural evolution and composition change in the surface region of PP/OMMT nanocomposites during heating were monitored by means of X-ray photoelectron spectroscopy (XPS), ATR-FTIR and field emission scanning electron microscopy (FESEM).

Luminescent properties of RE3+-activated CaAl2B2O7 (RE = Tb, Ce) in VUV-visible region

RE3+-activated alpha- and beta-CaAl2B2O7 (RE = Tb, Ce) were synthesized with the method of high-temperature solid-state reaction. Their VUV excitation and VUV-excited emission spectra are measured and discussed in the present article. The charge transfer band of Tb3+ and Ce3+ is respectively calculated to be at 151 +/- 2 and 159 +/- 3 nm. All the samples show an activator-independent excitation peak at about 175 nm and an emission peak at 350-360 nm ascribed to the host absorption and emission band, respectively.

The luminescence of CaYBO4 : RE3+ (RE=Eu, Gd, Tb, Ce) in VUV-visible region

Phosphors CaYBO4:RE3+ (RE = Eu, Gd, Tb, Ce) were synthesized with the method of solid-state reaction at high temperature, and their vacuum ultraviolet (VUV)-visible luminescent properties in VUV-visible region were studied at 20 K. In CaYBO4, it is confirmed that there are two types of lattice sites that can be substituted by rare-earth ions. The host excitation and emission peaks of undoped CaYBO4 are very weak, which locate at about 175 and 350-360nm, respectively. The existence of Gd3+ can efficiently enhance the utilization of host absorption energy and result in a strong emission line at 314 nm. In CaYBO4, Eu3+ has typical red emission with the strongest peak at 610 nm; Tb3+ shows characteristic green emission, of which the maximum emission peak is located at 542 nm. The charge transfer band of CaYBO4:Eu3+ was observed at 228 nm; the co-doping of Gd3+ and Eu3+ can obviously sensitize the red emission of Eu3+. The fluorescent spectra of CaYBO4:Ce3+ is very weak due to photoionization; the co-addition of Ce3+-Tb3+ can obviously quench the luminescence of Tb3+.

Improved efficiency by a graded emissive region in organic light-emitting diodes

Electrical and optical properties of organic light-emitting diodes (OLEDs) with a stepwise graded bipolar transport emissive layer for a better control of charge transport and recombination are presented. The graded bipolar transport layer was formed by co-evaporating a hole-transporting material N,N-'-diphenyl-N,N-'-bis(1,1(')-biphenyl)-4,4(')-diamine (NPB) and an electron-transporting/emissive material tris-(8-hydroxyquinoline) aluminum (Alq(3)) in steps, where each step has a different concentration ratio of NPB to Alq(3). Compared to a conventional heterojunction OLED, electroluminescence efficiency was enhanced by a factor of more than 1.5, whereas the turn-on voltage remained unchanged in the graded structure.

Stimulated emission in the blue wavelength region from a copolymer containing PPV segment

The lasing properties of a soluble conjugated polymer, Poly[1,8-octanedioxy-2,6-dimethoxy-1,4-phenylene-1,2-ethenylene-1,2-phenylene-1,2-ethenylene-3,5-dimethoxy-1,4-phenylene] (CNMBC-Ph) in chloroform solution were investigated. The third harmonic radiation of a Nd:YAG laser was used as the pump light. The stimulated emission with a linewidth of 15 nm was observed in the blue wavelength region with the peak at 450 nm. The threshold pulse peak power was about 2.8 MW/cm(2). The energy conversion yield of the laser was estimated to be about 3.4%. The maximum peak power of the laser output pulse reached 40 kW. (C) 2000 Published by Elsevier Science S.A. All rights reserved.

Luminescent properties of Gd3PO7 : Eu in UV/VUV region

The luminescent properties of Gd3PO7:Eu were investigated in W and VUV regions. This phosphor has such strong emissions around 618.5 nn under UV excitation, especially around 209nn, that it has a better colour saturation than that of Y2O3:Eu. It could be a new potential red phosphor for lamp and other applications with W-excitation source or even for displaying devices. In the VUV excitation spectrum of Eu3+ emissions, energy absorptions by Gd3+, Gd-O and PO43- have been observed, on which it can be inferred that there are three kinds of energy transferring processes to Eu-3(+) ions. The energy absorptions of Gd3+, Gd-O and PO43- are induced by 4f --> 4f transitions, a bandgap transition of Gd3PO7 and intramolecular (2t(2) --> 2a, 3t(2)) transition, respectively. The energy transfer efficiency of the PO43- intramolecular transition is lower compared with that of the bandgap transition (Gd-O).

Stimulated emission in blue wavelength region from a copolymer

A dye laser based on the soluble conjugated polymer, Poly[1,8-octanedioxy-2,6-dimethoxy-1,4-phenylene-1,2-ethenylene-1, 4-phenylene-1,2-ethenylene-3,5-dimethoxy-1,4-phenylene], has been fabricated. The laser was pumped by light pulses from the third harmonic radiation of an Nd:YAG laser. The lasing was observed in the blue wavelength region with the peak at 450 nm. The threshold energy is about 19 mu J. The energy conversion yield of the laser is about 3.4%. The maximum peak power of the laser output pulse arrives at about 20 kW.