Study of adsorption of methylene blue and new methylene blue in liquid-solid interface by slab optical waveguide spectroscopy

A slab optical waveguide (SOWG) has been used for study of adsorption of both methylene blue (MB) and new methylene blue (NMB) in liquid-solid interface. Adsorption characteristics of MB and NMB on both bare SOWG and silanized SOWG by octadecyltrichlorosilane (ODS) were compared. Effect of pH on adsorption on MB and NMB was investigated. Binding rate constant analysis showed that both MB and NMB on bare SOWG demonstrates larger association constants than those on ODS-SOWG. Interactions of NIB and NMB on bare SOWG and ODS-SOWG were analyzed by molecular mechanics calculation method. The binding energy change was in the following order: ENMB-bare > EMB-bare > ENMB-ODS > EMB-ODS. (c) 2004 Elsevier B.V. All rights reserved.

Morphological Evolution During Synthesis of New AlPO4 Center dot H2O Crystal

A new crystal of aluminophosphate, AIPO(4)(.)H(2)O, is synthesized from two-batch aqueous solution under hydrothermal conditions. Three types of the crystal habits, i.e. the tetragonal double pyramid, the tetragonal prism and the plate-type tetragonal prism, are found from batch-A solution. Two types of the crystal habits, i.e. the hexagonal pyramid and the strip-type tetragonal prism, are found from batch-B solution. The change of crystal morphology is originated from the fluctuation of the synthesis conditions, such as the supersaturation, the temperature and the impurity content. It causes change of the step energies, the defect density and the step roughness, and further, change of the growth rates. Since the crystal morphology is sensitive to the mass transport mechanism, the crystal habits could be changed under the microgravity.

单渥拉斯顿稜镜激光差分干涉仪

<正> 激光具有高度的时间和空间相干性,如果用它作为光源,可用一块渥拉斯顿稜镜(Wollaston Prism)代替纹影系统中的刀口机构,这样就形成了一台所谓的单渥拉斯顿稜镜(以下简称W稜镜)激光差分干涉仪。根据实验结果,

利用块状介质进行飞秒强激光脉冲的腔外压缩

高强度飞秒激光脉冲的腔外压缩是获得高次谐波阿秒脉冲驱动源的必要手段。实验研究了超强超短飞秒激光脉冲在经过块状介质后的光谱展宽和色散补偿压缩现象。单脉冲能量0．26mJ，脉宽50fs的激光脉冲经透镜在空气中聚焦后再入射到块状材料上，出射脉冲光谱被展宽到接近40nm。由于在块状材料中的自聚焦效应，出射光束质量变好并保持较小的空间啁啾。利用熔融石英棱镜对补偿带有正色散的出射脉冲，最后得到〉0．1mJ，19fs的压缩脉冲。利用SPIDER装置测量了出射脉冲的脉宽和光谱相位。整个系统的能量效率大约为35％，压缩后的

Transmission spectrum of a double quantum-dot-nanocavity system in photonic crystals

We investigate the optical transmission properties of a combined system which consists of two quantum-dot-nanocavity subsystems indirectly coupled to a waveguide in a planar photonic crystal. A Mollow-like triplet and the growth of sidebands are found, reflecting intrinsic optical responses in the complex microstructure.

Modified formula of Malus' law for Glan-Taylor polarizing prisms

A simple three-axis model has been developed, which has been successfully applied to the analysis of the light transmittance in spatial incident angle and the simulation of modified formula of Malus' law for Glan-Taylor prisms. Our results indicate that the fluctuations on the cosine squared curve are due to specific misalignments between the axis of the optical system, the optical axis of the prism and the mechanical axis (rotation axis) of prism, which results in the fact that different initial relative location of the to-be-measured-prism in the testing system corresponds to different shape of Malus' law curve. Methods to get absolutely smooth curve are proposed. This analysis is available for other kinds of Glan-type prisms. (C) 2004 Elsevier B.V. All rights reserved.

Fabrication of microfluidic optical waveguides on glass chips with femtosecond laser pulses

We describe the fabrication of microfluidic channel structures on the surface of a borosilicate glass slide by femtosecond laser direct writing for optical waveguide application. Liquid with a variable refractive index is fed into the microchannel, serving as the core of the waveguide. We demonstrate that either a multimode or a single-mode waveguide can be achieved by controlling the refractive index of the liquid. (C) 2007 Optical Society of America

离焦系统下的单分子三维取向研究

提出了一种新思路来确定单分子的三维取向,在全内反射荧光显微成像的基础上,在显微镜的油镜上加一个水层,水和油的折射率不同造成光程差,产生离焦,利用全内反射产生隐失波激发了单分子的纵向分量,并在探测器前增加了一个分光镜,把光路分成偏振方向相互垂直的两束光,使得探测器上的光场分布包含单分子三维取向的信息。推导了隐失场激发的偶极矩光场在探测器上的光强分布表达式,通过分析偏振方向相互垂直的两束光在探测器上的不同的强度分布,来判断单分子偶极矩的三维取向。

矩阵理论在半导体激光器耦合中的应用

傍轴近似下的光学矩阵理论，可以简化光束传输计算过程，使光学系统设计更为方便。将ABCD变换矩阵方法引入到耦合光学系统的设计中，运用高斯光束的ABCD法则，详尽地给出了某一耦合方式下的半导体激光器耦合入单模光纤系统的设计；另一方面，对系统的耦合损耗与耦合距离的关系进行了理论计算，并把计算结果与最近的实验报道做了比较，它们基本相吻合，说明此方法是可行的、合理的。从整个设计及理论计算来看，ABCD矩阵方法减少了复杂的计算，从而简化了设计过程，与通常的衍射计算相比，它不失为一种方便、有效的方法，同时它对生产半导体

溶胶-凝胶光波导环形谐振腔的挥发性有机化合物传感特性

采用溶胶-凝胶法制作波导环形谐振腔, 讨论了环形谐振腔器件的传输特性。测量了在不同物质、不同体积分数的挥发性有机化合物(VOC)蒸气气氛下器件的传输光谱的敏感性。结果表明, 谐振波长随甲醇、乙醇、丙醇等醇类化合物, 以及丙酮、甲醛等蒸气体积分数的上升而向长波方向移动, 具有高的灵敏度, 且两者基本呈线性关系。其中, 对丙醇最敏感, 灵敏度达到1.403 pm/10-6。对甲烷和二甲苯也有微弱反应, 但是其灵敏度很低。也测量了水蒸气对传输谱特性的影响。观察到传输谱衬比度对不同挥发性有机化合物物质蒸气的不同敏

溶胶-凝胶条波导Sagnac环的乙醇蒸气传感特性

采用有机/无机混合溶胶-凝胶法制作条形光波导,并将条波导接入光纤Sagnac 环中,测量了输出光功率随环境气氛中乙醇蒸气体积分数变化的特性,表明在实验研究的范围内,输出信号与乙醇蒸气体积分数呈正弦变化。根据Sagnac环结构输出特性的基本关系,反映了溶胶-凝胶条波导在乙醇蒸气气氛下产生了双折射效应。观察到双折射相移与乙醇体积分数的亚线性关系。对实验数据拟合,计算了偏振相移的线性项和二次项系数,得到所制备的条波导的双折射对乙醇体积分数的响应为Δn≈4.4×10-2。测量了信号变化的时间演变特性,典型的上升和

长周期光纤光栅波导色散因子和有效折射率热光系数的测量

对串联的长周期光纤光栅(CLPFG)的透射谱特性进行了理论分析和实验研究。分析表明，长周期光纤光栅中纤芯模和包层模之间的马赫-曾德尔干涉效应导致在长周期光纤光栅谐振峰内的梳状滤波结构特性；其峰值位置和峰间距同串联区光纤的长度以及光纤的波导色散因子有关。测量了长周期光纤光栅的透射谱，并研究了其温度特性。根据测量数据，得到对应于1554nm波长处，所用单模光纤HE14模的波导色散因子γ为0．874；纤芯／包层有效折射率差的热光系数为4．8×10^-5℃^-1。并对这一测试方法和结果，以及长周期光纤光栅的应用进

基于3×3耦合器的马赫-曾德尔干涉仪的光纤光栅波长解调技术

介绍了一种基于3×3和2×2光纤耦合器构成的非平衡马赫-曾德尔干涉仪的波长解调方案。理论分析和数据对比表明，相对于由两个2×2光纤耦合器构成的马赫-曾德尔干涉仪，本干涉仪具有宽谱的灵敏度、能跟踪波长的变化方向和相位展开的优点，实验方案用于测量固定在悬臂梁上的传感光纤布拉格光栅（FBG）的峰值波长变化，获得了±1pm的静态波长解调精度，在10Hz处的动态分辨率为27nε/√Hz。相位展开算法使得应变测量范围达到了2014με，对应的相位变化为3．22π。

基于多台阶反射光栅的飞秒脉冲压缩装置

反射式光栅对是一种具有负色散性质的器件,可用于飞秒激光脉冲的压缩和展宽,具有无材料色散的优点。给出了一种基于多台阶反射光栅的脉冲压缩装置。该装置为倍密度光栅结构,由两个周期分别为40μm和20μm的四台阶反射式光栅组成。实验得到的衍射效率可以达到70%以上,输入脉冲经过两个光栅的衍射后会按原路返回,从而达到色散补偿的效果。利用此压缩装置,脉冲宽度为66.8 fs的输入脉冲压缩至接近傅里叶变换极限脉冲,即46.6 fs,由此证明只要多台阶光栅效率足够高,此装置就有可能成为不同于棱镜对进行飞秒脉冲腔内和腔外压缩的另一种途径。

Experimental study of nonlinear switching characteristics of conventional 2×2 fused tapered couplers

The nonlinear switching characteristics of fused fiber directional couplers were studied experimentally. By using femtosecond laser pulses with pulse width of 100 fs and wavelength of about 1550 nm from a system of Ti:sapphire laser and optical parametric amplifier (OPA), the nonlinear switching properties of a null coupler and a 100% coupler were measured. The experimental results were coincident with the simulations based on nonlinear propagation equations in fiber by using super-mode theory. Nonlinear loss in fiber was also measured to get the injected power at the coupler. After deducting the nonlinear loss and input efficiency, the nonlinear switching critical peak powers for a 100% and a null fused couplers were calculated to be 9410 and 9440 W, respectively. The nonlinear loss parameter P_(N) in an expression of α_(NL)=αP/P_(N) was obtained to be P_(N)=0.23 W.