Carboxyl-cored dendrimer and toluene-assisted fabrication of uniform platinum nanodendrites at a water/oil interface and their potential application as a catalyst

Uniform platinum nanodendrites have been prepared at a water/oil interface by a facile catalyst-free method at room temperature. This is carried out by introducing NaBH4 into the platinum precursor solution in the presence of the second generation of carboxyl-cored dendrimer ([G-2]-CO2H dendrimer) and toluene to act as a protective agent and a linker, respectively. The average fractal dimension of 1.61 of the obtained platinum nanodendrites is calculated by analysing the transmission electron micrographs using the programs Fractal Dimension Version 1.1 and Fractal Dimension Calculator. Control experiments show that the fabrication of platinum nanodendrites can be operated with a wide parameter window, which undoubtedly raises the degree of control of the synthesis process. The potential application of such a nanostructure as a catalyst is investigated, and the results reveal that they show highly efficient catalytic properties for the typical redox reaction between hexacyanoferrate (III) and thiosulfate ions at 301 K.

Analysis of chemical constituents of essential oil in purple magnolia leaves by gas chromatography-mass spectrometry

The essential oil in purple magnolia leaves was extracted by steam distillation approaches. The oil obtained was dried with anhydrous magnesium sulfate. According to the analysis of gas chromatography/mass spectrometry, more than 40 peaks were separated and 32 compounds were identified. The identified constituents represent 95% of the peak area of the essential oil. The main compounds were germacrene-D, santolina triene, caryophyllene, 1,3,7-octatriene, 3,7-dimethyl, and camphene, etc.

Prevention of fish oil rancidity by phlorotannins from Sargassum kjellmanianum

Known only in the Phaeophyceae, phlorotannins (brown algal polyphenols) are a class of natural products with potential uses in pharmacology. This study reports that phlorotannins from Sargassum kjellmanianum can prevent fish oil from rancidification; the antioxidation activity was about 2.6 times higher than that of 0.02% BHT (tertbutyl-4-hydroxytoluene).

CHINESE NITRARIA TANGUTORUM BOBR。： CHEMICAL CONSTITUENTS OF SEED OIL EXTRACTED BY SFE-CO_2

In order to develop and make good use of Nitraria tangutorum Bobr. in Qinghai-Tibetan Plateau for its ecological and medicinal values, the seed oil was extracted by SFE-CQ2 and the chemical constituents was analyzed by GC/MS. The component relative contents were determined by area nomalization. 28 components were separated from the extracts of SFE-CQj and 12 of them, which accounted for 85.99% were identified. They were(Z, Z)-9, 12-octadecadienoic acid (linoleic acid), bicyclo[ 10. 1. 0] tridec-1-ene, 7-pentadecyne, gamma-sitosterol, gamma-tocopherol, 1, -8,Z-10-hexadecatriene,9,12-octadecadienal, 24-methyl-5-cholestene-3-ol,(Z)-9,17-octadecadienal, stigmastan-3,5-dien, eicosane and so on. Among them, the relative content of (Z, Z)-9,12-octadecadienoic acid is the highest, accounting for 65.85% of the total area. It is concluded that N. tangutorum Bobr. seed oil is a rich source of linoleic acid.

Effect of graded levels of rapeseed oil in isonitrogenous diets on the development of the gastrointestinal tract, and utilisation of protein, fat and energy in broiler chickens

The effect of feeding 0, 4, 8 and 16% rapeseed oil from 12-42 days of age was studied in broiler chickens on performance, digestibility of nutrients, and development of gastrointestinal tract, protein and energy metabolism. Thirty six female chickens (Ross 208) with initial body weight average 246 g were allocated to the four groups and kept pair-wise in metabolism cages. The chickens were fed similar amounts of metabolisable energy (ME) per day and similar amounts of essential amino acids relative to ME by adjusting with crystalline amino acids. The chickens were subjected to four balance periods each of five days with two 24 h measurements of gas exchange in two open-air-circuit respiration chambers inserted on the second and third day of each period. The addition of rapeseed oil increased the amount of gutfill indicating a reduced rate of passage and causing a hypertrophy of the gastrointestinal tract. There was a positive effect on feed utilisation as well as on digestibility especially of dietary fat together with higher utilisation of protein with addition of rapeseed oil. The partial fat digestibility of rapeseed oil estimated by regression was 91.1% and the partial metabolisability (ME/GE) of the rapeseed oil was estimated to 85% yielding an apparent metabolisable energy value of 34.30 MJ/kg.

Extraction of Nitraria tangutorum seed oil by supercritical carbon dioxide and determination of free fatty acids by HPLC/APC/IMS with fluorescence detection

The seed oil from Nitraria tangutorum samples was obtained by supercritical carbon dioxide extraction methods. The extraction parameters for this methodology, including pressure, temperature, particle size and extraction time, were optimized. The free fatty acids in the seed oil were separated with a pre-column derivation method and 1,2-benzo-3,4-dihydrocarbazole-9-ethyl-p-toluenesulfonate (BDETS) as a labeling regent, followed by high-performance liquid chromatography (HPLC) with fluorescence detection. The target compounds were identified by mass spectrometry with atmospheric pressure chemical ionization (APCI in positive-ion mode). HPLC analysis shows that the main compositions of the seed oil samples were free fatty acids (FFAs) in high to low concentrations as follows: linoleic acid, oleic acid, hexadecanoic acid and octadecanoic acid. The assay detection limits (at signal-to-noise of 3:1) were 3.378-6.572 nmol/L. Excellent linear responses were observed, with correlation coefficients greater than 0.999. The facile BDETS derivatization coupled with mass spectrometry detection allowed the development of a highly sensitive method for analyzing free fatty acids in seed oil by supercritical CO2 extraction. The established method is highly efficient for seed oil extraction and extremely sensitive for fatty acid profile determination. (C) 2007 Elsevier B.V. All rights reserved.

油田高含水期剩余油分布规律研究

After systemic investigation of the techniques，route lines and mechanisms about the remaining oil，the dynamic migration and congregation behavior of the remaining oil are discussed on base of interaction between flowing and enriching of water and oil.After the micro-scope modeling of the fluid flow in porous media and the changes in petrol-physical properties of the flowing system, the characters of fluid fields and the dynamic distribution of oil are discussed, among which the preference-flowing is focused on. Based on the preference-flowing in porous media, the concept of the preference-flowing channels is developed. According to above, heterogeneous distribution of water and oil in the field and dynamic mechanism of remaining oil are all obvious. media can be divided into three kinds, directional, stochastic, arbitrary porous media. The main research results are as following: 1. Treating the characteristic parameters such as permeability, porosity and wettability as regional parameter, the fluid field with high water-cut has been established by geostatistical method, among which the difference of flowing pores and the changes of its petrol-physical properties during flooding are studied. 2. The flow process of water and oil are recurrent in physical simulation experiments, in which the mechanisms and phenomena are caught and analyzed. Fluid flow mechanics in porous media with preference-flowing channels have been studied. 3. The mutual coupling between water and oil is induced and the mathematical evolution equations including this interaction were built. . 4. Through coupling effect between flowing water and oil, the dynamic migration and congregation behavior of remaining oil depend upon this coupling. 5. Coupling between water and oil act as driving force and trapping force for the remaining oil. The coupling model of thesis has been verified by simplified the numerical model and compared results with Ng35 oil reservoir in Gudao oil field, it has important theoretical and application values for improving precision of remaining oil and production performance prediction, and is a new method for studying the mechanics of remaining oil in channeled porous media has been established. Key words：flow field，high water-cut，coupling，dominant flow in porous media，remaining oil

高邮凹陷陈堡及陈堡东地区油气成藏规律研究

With the development of petroleum exploration in Gaoyou Depression, both old and new areas have been the active exploration targets, so the study of petroleum accumulation is significant to the petroleum exploration in the study area and the integrated oil and gas accumulation theory. Based on hydrocarbon accumulation theory and systematical research methods and combined with the structural characteristics of Gaoyou Depression, Chenbao and East of Chenbao were selected as the study areas in this dissertation, oil and gas migration pathways, accumulation periods, as well as accumulation models were studied, and favorable exploration targets were proposed. There develop three sets source rocks, which are Tai-2 Member, Fu-2 Member and Fu-4 Member respectively. Tai-2 Member is the predominant source rock in the eastern part. Fu-2 Member mainly occurs in the northern slope, while Fu-4 Member develops in the deep depression. In the study area, oil mainly comes from Fu-2 Member of Liuwushe subsag. The lower limit of TOC is 0.4%, and active source rock mostly distributed in the south fault-step zone. The source rock in Liuwushe subsag began to generate hydrocarbon in the late of Dainan depositional stage and the threshold was 2300m. The macro and micro characteristics of reservoirs and the reservoir heterogeneity characteristics of the Fu-1 Member were studied systematicly. The results show that Fu-1 Member, which has better reservoir properties, are medium porosity-medium permeability reservoir. The reservoir permeability has good correlation with porosity connectivity. The reservoirs have strong dissolution, pores are mainly thin to medium throat, and throat radii are distributed concentratedly, the sorting is good and pore structures are homogeneous. Sandstone reservoirs whether in the plan view, interlayer or in layers have a certain degree of heterogeneity, in particular, the heterogeneity in layers directly affect and control the oil and gas migration and accumulation. By analyzing the lithology correlation of the fault walls, shale smear, cross section stress, the configuration of fracture active periods and hydrocarbon generation and expulsion periods and fuzzy comprehensive evaluation, the main faults sealing were evaluated. The results show that the faults in Chenbao and East of Chenbao had poor sealing properties in Sanduo period and could be used as the migration pathways at that time. After Sanduo period, the tectonic stress fields in the area changed largely, and, consequently, the fault properties converted from tensional shear to compressive shear, the faults changed progressively from close to open, so the faults sealing became better and were conducive to the preservation of oil and gas reservoirs. According to the seismic event suspension modes and profile configurations above and under the unconformities, combined with tectonic evolutions of the study areas, the unconformity types can be classified into truncation unconformity, overlapped unconformity and parallel unconformity and the distribution characteristics of unconformities in the plan view was also studied. The unconformity structure was divided into basal conglomerate, weathered clay and semi-weathered layer vertically in the study area and this kind of structure make unconformities to be effective oil and gas migration pathways and is significant to hydrocarbon accumulation in a parts of areas. With the analyses of typical oil and gas reservoirs in the study area, combined with the research results of pathway systems, hydrocarbon accumulation models were established and the oil and gas accumulation laws in Chenbao and East of Chenbao analyzed. The oil and gas came from Liuwushe subsag and Liuliushe subsag. The oil and gas from Liuwushe subsag mainly migrated from the structural high parts into the fault-step zone along strata in northeast direction, a part of them migrated upward into the fault-step zone and the Wubao low uplift along Wu-1 Fault in northeast direction. The oil and gas from Liuliushe subsag mainly migrated into the upper reservoirs through Wu-2 fault, and lesser oil and gas migrated into the fault-step zone because of the controls of cross-section orientation, depression center and the hydrocarbon formation tendency. The favorable exploration targets in Chenbao and East of Chenbao have been concluded: the southern fault-step zone is a favorable oil and gas accumulation zone of Liuwushe subsag, and they are fault block reservoirs where fault acted as the barriers, the main target intervals are Fu-1 Member and Fu-3 Member in palaeocene; Oil and gas in the middle and northern fault-step zone mainly laterally migrated from the south areas, and the main target interval is Fu-3 Member in palaeocene; Fu-1 Member and the reserviors above the Wubao subsag are still the focuses in future explorations. The results of this study have important guiding significance for the future oil and gas exploration.

整合多尺度地球物理数据建立高分辨率储层模型的方法及应用

Most of the fields in China are in the middle-late development phase or are mature fields. It becomes more and more difficult to develop the remaining oil/gas. Therefore, it is import to enhance oil/gas recovery in order to maintain the production. Fine scale modeling is a key to improve the recovery. Incorporation of geological, seismic and well log data to 3D earth modeling is essential to build such models. In Ken71 field, well log, cross-well seismic and 3D seismic data are available. A key issue is to build 3D earth model with these multi-scales data for oil field development.In this dissertation, studies on sequential Gaussian-Bayesian simulation have been conducted. Its comparison with cokriging and sequential Gaussian simulation has been performed. The realizations generated by sequential Gaussian-Bayesian simulation have higher vertical resolution than those generated by other methods. Less differences between these realization and true case are observed. With field data, it is proved that incorporating well log, cross-well seismic and 3D seismic into 3D fine scale model is reliable. In addition, the advantages of sequential Gaussian-Bayesian simulation and conditions for input data are demonstrated. In Ken71 field, the impedance difference between sandstone and shale is small. It would be difficult to identify sandstone in the reservoir with traditional impedance inversion. After comparisons of different inversion techniques, stochastic hillclimbing inversion was applied. With this method, shale content inversion is performed using 3D seismic data. Then, the inverted results of shale content and well log data are incorporated into 3D models. This demonstrates a procedure to build fine scale models using multi scale seismic data, especially 3D seismic amplitude volume.The models generated through sequential Gaussian-Bayesian simulation have several advantages including: (1) higher vertical resolution compared with 3D inverted acoustic impedance (AI); (2) consistency of lateral variation as 3D inverted AI; (3) more reliability due to integration cross-well seismic data. It is observed that the precision of the model depends on the 3D inversion.

中低纬度变化磁场的暴时特征研究

Magnetic storm is a kind of severe disturbances in the whole solar-earth electromagnetic space. It has significant effects on communication, electric power, oil transport pipe and human activities in space. Therefore, magnetic storms are worth for applications systems, not only being a favorable issue for scientists. In this paper, the spatial and temporal distributions of the magnetic fields produced by the magnetosphere-ionosphere current systems during storms are studied. Four parts are included in this paper decomposion of different disturbances with different origins, topological structure of the ring current, the asymmetric characteristics of the ring current, and the statistic peculiarities of the day-to-day variability (DTD) of Sq. 1 The decomposition of magnetic disturbances at mid-low latitudes and its evolutions during storms Transient variations in the geomagnetic field recorded at mid-low latitudes mainly include the storm-time variation (Dst), solar quiet daily variation (Sq) and disturbance daily variation (SD). With the data of the geomagnetic meridian chain observatories in China, 25 storms during the period of 1997 to 1999 have been analyzed. According to the features of different variations, a method of “three-steps decomposition” is developed by using the method of Natural Orthogonal Components (NOC), Correlation Analysis and Fourier Analysis to separate those three components in turn. The results show that, the first eigenmode by the MNOC clearly describing the special distribution and temporal evolution of storm-time variation, in addition, Correlation Analysis and Fourier Analysis offer a useful method to extract the Sq and SD variations. The latitudinal shift of the Sq current focus seems to be the principal reason of the day-to-day variaitons in the daily range of Sq. The magnitude of SD reaches a maximum during the main phase, and then gradually decreases. 2 The topology structure of the ring current during storms Both the mechanism of the ring current and the geomagnetic data suggest that the central plane of the ring current is declining to the geomagnetic equator plane with a tilt angle δ. Using the H and Z component data at two stations in a meridian chain, we deduce a new parameter describing the invariable peculiarity of different storms. Then the δ angle is calculated by using the data from a meridian chain and tested with the ERC model. Finally the deduced tilt angles are used to modify Dst index. 3 The asymmetric characteristics of the ring current during storms The variations of the geomagnetic field at mid-low latitudes show a significant dawn-dusk asymmetry, resulting from the superposition of the fields from the symmetric ring current and the partial ring current. On the basis of the data from the 20°E, 30°E meridian chains and 30°N latitudinal chain, the dawn-dusk asymmetry is investigated by using three methods, namely, statistic analysis, ring current model calculation and typical event analysis. This characteristic implies the asymmetry of the spatial distribution of the ring current. In addition, during the main phase after the sudden commencement (SC), H field increases and reaches maximum around noontime, implying the effect of the Chapman-Ferraro current. 4 The statistic characteristics of the day-to-day variability and its mechanism The day-to-day variability of the geomagnetic Sq field is studied by using the magnetic data from a meridian chain of magnetometers along 120° E longitude. The method of NOC is applied to separate the Sq variation from complicated disturbances. The first eigenmode with the largest eigenvalue represents fairly well the Sq variation with a conspicuous day-to-day variability in the daily range. For the stations on the same north- or south-side of the Sq current system focus, the day-to-day variations show a positive correlation. In contrast, for the stations on the different sides of the Sq focus, they show a negative correlation, suggesting an important role of latitudinal shift of the Sq current system focus to the day-to-day variability of the Sq daily range. The Sq daily range is correlated with the magnetic indices Ap and Dst in a peculiar way: on some severe disturbed days, noticeably enhancements of the Sq are observed, implying increases of the ionospheric conductivities and/or tidal wind velocities; on other severe disturbed days, however, dramatically reduced Sq variations occur, suggesting dominant effects of the ‘disturbance dynamo’ process.