新增生岩石圈与软流圈的相互作用：来自地幔橄榄岩捕虏体的证据

The petrology and geochemistry of peridotites entrained in Beiyan Cenozoic alkaline basalts within the middle segment of Tan-Lu fault zone and clinopyroxene megacrysts in the late Mesozoic and Cenozoic alkaline basaltic rocks from the North China Craton, have been systematically investigated. The main conclusions are obtained as follows. The peridotites entrained in alkaline basalts at Beiyan, Shandong Province, China are comprised of dominantly spinel lherzolites and spinel wehrlites with porphyroclastic, granuloblastic textures to resorption textures. The xenoliths are fertile in major element compositions (High CaO, TiO2, Low MgO, Cr2O3). The olivine Fo (= 100×Mg / (Mg+Fe) possesses a low and very large range of 81.0 to 91.0. The peridotites contain high percentages (Lherzolites: 10 - 19% in volume; Wehrlites: 24 - 28% in volume) of clinopyroxene with spongy textures. The Sr and Nd isotopic ratios of clinopyroxene separates from peridotites and pyroxenite xenoliths have a depleted and small range fall within the area of MORB, similar to newly-accreted lithospheric mantle. However, the appearance of many wehrlites and highly enriched LREE pattern suggest that this newly-accreted lithospheric mantle was considerably modified and reconstructed recently through the peridotite-asthenospheric melt interaction. The upwelling of asthenosphere from late Cretaceous to Eogene and upper mantle shearing of the Tan-Lu fault played an important role in the modification and reconstruction of the newly-accreted lithospheric mantle. The clinopyroxene megacrysts in the late Mesozoic and Cenozoic alkaline basaltic rocks from the eatern North China Craton are different in aspects of major elements, trace elements and isotopic composition. The characteristics of texture, mineral compositions and geochemistry as well as the Fe-Mg partitioning between the crystal and the melt indicates that the Al-augites in the Cenozoic basalts represent high-pressure crystallization products of alkaline basaltic melts. Thus, both of clinopyroxene megacrysts and host basalts could be derived from a same primitive magma. However, the Al-augites in the late Mesozoic basaltic rocks represent accidentally-included xenocrysts of basaltic components which had crystallized in the depth from a previously melting episode. The more depleted Sr-Nd isotopic compositions of Cenozoic megacrysts compared with those of host alkaline basalts and tholeiites demonstrate that even the alkali basalts could not completely represent primitive magma initiating in asthenosphere. That is to say, the Cenozoic alkaline basalts were more or less modified by some enriched Sr-Nd isotopic components during their eruption. Meanwhile, the tholeiites were not the products formed only by fractional crystallization of alkaline basaltic magma or different degrees of partial melting. It may result from the contribution of lithospheric mantle materials or crust contamination in magma chamber to alkali basaltic magmas.

内蒙古东部喀喇沁地区早中生代底侵作用

Mafic granulite xenoliths have been extensively concerned over the recent years because they are critical not only to studies of composition and evolution of the deep parts of continental crust but to understanding of the crust-mantle interaction. Detailed petrology, geochemistry and isotope geochronology of the Early Mesozoic mafic-ultramafic cumulate xenoliths and mafic granulite xenoliths and their host diorites from Harqin area, eastern Inner-Mongolia have been studied here. Systematic Rb-Sr isochron, ~(40)Ar-~(39)Ar and K-Ar datings for mafic-ultramafic cumulate xenoliths give ages ranging from 237Ma to 221Ma. Geochemical research and forming temperature and pressure estimates suggest that cumulates are products of the Early Mesozoic mantle-derived magmatic underplating and they formed in the magmatic ponds at the lowermost of the continental crust and are later enclaved by the dioritic magma. Detailed study on the first-discovered mafic granulite xenoliths reveals that their modal composition, mineral chemistry and metamorphic P-T conditions are all different from those of the Precambrian granulite exposed on the earth surface of the North China craton. High-resolution zircon U-Pb dating suggests that the granulite facies metamorphism may take place in 253 ～ 236Ma. Hypersthene single mineral K-Ar dating gives an age of 229Ma, which is believed to represent a cooling age of the granulite. As the host rock of the cumulate and granulite xenoliths, diorites intruded into Archean metamorphic rocks and Permian granite. They are mainly composed of grandodiorite, tonalite and monzogranite and show metaluminous and calc-alkaline features. Whole rock and single mineral K-Ar dating yields age of 221 ～ 223Ma, suggesting a rapid uplift in the forming process of the diorites. Detailed field investigation and geochemical characteristics indicate that these diorites with different rock types are comagmatic rocks, and they have no genetic correlation with cumulate and granulite xenoliths. Geochemical model simulating demonstrates that these diorites in different lithologies are products of highly partial melting of Archean amphibolite. It is considered that the Early Mesozoic underplating induced the intrusion of diorites, and it reflects an extensional geotectonic setting. Compression wave velocity V_P have been measured on 10 representative rock samples from the Early Mesozoic granulite and mafic-ultramafic cumulate xenoliths population as an aid to interpret in-situ seismic velocity data and investigating velocity variation with depth in a mafic lower crust. The experiments have been carried out at constant confining pressures up to 1000MPa and temperatures ranging from 20 ℃ to around 1300 ℃, using the ultrasonic transmission technique. After corrections for estimated in situ crustal pressures and temperatures, elastic wave velocities range from 6.5 ～ 7.4 km s~(-1). On the basis of these experimental data, the Early-Mesozoic continental compression velocity profile has also been reestablished and compared with those of the present and of the different tectonic environments in the world. The result shows that it is similar to the velocity structure of the extensional tectonic area, providing new constraints on the Early Mesozoic continental structure and tectonic evolution of the North-China craton. Combining with some newly advancements about the regional geology, the thesis further proposes some constraints on the Mesozoic geotectonic evolution history, especially the features of deep geology of the North China craton.

东南极格罗夫山地区的陨石回收与研究

Chinese National Antarctic Research Expedition (CHTNARE) has collected 4480 meteorite specimens in the Grove Mountains, East Antarctica, from 1998 to 2003. According to the location characteristics and the diversity of the classification, the paper concludes that the Grove Mountains is another important meteorite concentration area in the Antarctica. The Concentration mechanisms at the site could be related to the last glacier activity and katabatic wind. An empirical model was proposed: 1) Probably during the Last Glacial Maximum, ice flow overrided the Gale Escarpment range in the area. Formerly concentrated meteorites were carried by the new glacier and stayed in the terminal moraine when the glacier retreated. 2) Blown by strong katabatic wind, Newly exposed meteorites on the ablation zone were scattered on the blue ice at the lee side of the Gale escarpment. Some of them would be buried when they were moved further onto the firn snow zone. Many floating meteorites stopped and mustered at the fringe of the moraine. The chemical-petrographic of 31 meteorites were assigned based on electron probe microanalyses, petrography and mineralogy, including 1 martian lherzolitic shergottite, 1 eucrite, 1 extreme fine grain octahedron iron meteorite, and 28 ordinary chondrites (the chemical groups: 7 H-group, 13 L-group, 6 LL-group, 2 L/LL group; the petrographic types: 6 unequilibrated type 3 and 22 equilibrated type 4-6). GRV99028 meteorite has the komatiite-like spinifex texture consisting of acicular olivine crystals and some hornblende-family minerals in the interstitial region. Possibly it has crystallized from a supercooled, impact-generated, ultramafic melt of the host chondrite, then experienced the retrogressive metamorphism. Four typical chondrule textures were studied: porphyritic texture, radiative texture, barred texture and glass texture. The minerals are characteristically enriched in MgO content.

Synthesis of 2-butoxy ethanol with narrow-range distribution catalyzed by supported heteropolyacids

A supported heteropolyacid (HPA), H3PMo12O40/SiO2, calcined in vacuum at 150 degrees C, has been shown to be an efficient solid acid catalyst for the synthesis of 2-butoxy ethanol with high selectivity. (C) 2000 Elsevier Science B.V. All rights reserved.