施氮及灌溉方式对玉米地土壤硝化潜势及微生物量碳的影响

研究了不同施氮量及灌溉方式下玉米地土壤的微生物量碳及硝化潜势。结果表明:未施氮肥条件下,喷灌比漫灌土壤平均硝化潜势低0.57~4.77 mg/(kg.d);不同时期喷灌施肥土壤平均硝化潜势变化量为2.18~4.77 mg/(kg.d),幅度较小;而漫灌施肥土壤硝化潜势的变化量为-0.57~28.4 mg/(kg.d),幅度较大。土壤微生物量碳的变化受施肥与灌溉方式的影响,9月份土壤微生物量碳均低于7月份,未施氮肥条件下,喷灌下降9.05 mg/kg,变化幅度较小;而漫灌下降176.52 mg/kg,变化幅度较大。施氮肥均降低土壤微生物碳量;不同时期漫灌施肥与漫灌未施肥、喷灌施肥与喷灌未施肥相比分别降低土壤平均微生物量碳108.78~0.57 mg/kg,58.82~86.71 mg/kg。

面向知识工作者的个人信息管理模型

为满足知识工作者对个人信息管理的灵活分类、时序管理和智能推荐的要求,提出一种个人信息管理系统模型。首先分析了知识工作者的个人信息管理特点,接着提出了模型的框架,描述了框架的层次结构。然后介绍了基于标签的个人信息推荐算法。最后对原型系统进行了评估。评估结果表明,该模型能够满足知识工作者对个人信息管理的要求。

我国北方农牧交错带生态经济型畜牧业发展对策:以河北省张北县试区为例

简析了北方农牧交错带区域主要畜种的生态、经济适应性,提出草畜一体化生产模式,即在沙化耕地、退化草滩发展以青刈莜麦为主的人工草地,舍饲圈养绒山羊。

Parallels plane projection and its geometric features

A new equivalent map projection called the parallels plane projection is proposed in this paper. The transverse axis of the parallels plane projection is the expansion of the equator and its vertical axis equals half the length of the central meridian. On the parallels plane projection, meridians are projected as sine curves and parallels are a series of straight, parallel lines. No distortion of length occurs along the central meridian or on any parallels of this projection. Angular distortion and the proportion of length along meridians (except the central meridian) introduced by the projection transformation increase with increasing longitude and latitude. A potential application of the parallels plane projection is that it can provide an efficient projection transformation for global discrete grid systems.

Constructing porous frameworks from one-dimensional cobalt-oxygen clusters and pyridinedicarboxylate ligands adopting two rare coordination modes

A porous material with cobalt-oxygen cluster framework has been synthesized hydrothermally, which possesses large and rigid channels and manifests strong antiferromagnetic interactions, and the pyridinedicarboxylate ligand exhibits two types of rare coordination modes.

The enhancement effect of Eu3+ on electro-oxidation of ethanol at Pt electrode

It is reported for the first time that the slow electrochemical kinetics process for the electro-oxidation of ethanol can be promoted by changing the electrochemical environment. The electro-oxidation of ethanol at a Pt electrode in the presence of Eu3+ cations was studied and an enhancement effect was exhibited. Cyclic voltammetry experiment results showed that the peak current density for the electro-oxidation of ethanol was increased in the presence of EU3+ in the ethanol solution. A preliminary discussion of the mechanism of the enhancement effect is given. This is based on a CO stripping experiment, which shows that either the onset potential or the peak potential of CO oxidation is shifted negatively after adding Eu3+ to the solution.

Preparation and electrical-magnetic properties of polyaniline doped with ionic ferrocenesulfonic acid

Conducting polyamline with electrical conductivity of 2.34 x 10(-1) S cm(-1) was obtained using ferrocenesulfonic acid as dopant. After the ferrocenesulfonic acid was oxidized with FeCl3, though the electrical conductivity of the doped polyaniline decreased by 1-2 orders of magnitude, the magnetic susceptibility (chi) increased with the increase of the oxidation degree of ferrocenesulfonic acid. EPR spectra showed not only a signal with a g value of around 2, but also a so-called half-field signal with a g value of about 4 even at room temperature. Coexistence of ferromagnetic intrachain interactions and antiferromagnetic interchain interactions in the materials has been suggested.

Structural determination of a new phase of monoclinic BaTb2Mn2O7

A new phase of monoclinic BaTb2Mn2O7 with extra superlattice lines in addition to the usual orthorhombic X-ray diffraction patterns was prepared and a Rietveld refinement was applied to analyze the crystal structure using X-ray powder diffraction data at room temperature. The refined lattice parameters were a = 0.54918(8) nm, b = 2.0149(5) nm, c = 0.54922(9) nm, and beta = 90.62degrees with the space group A2/m (no. 12). The MnO6 oxygen octahedron has distortion and tilts around a-axis by about 7degrees each other in the reverse direction.

Core-shell structured SiO2@YVO4 : Dy3+/Sm3+ phosphor particles: Sol-gel preparation and characterization

Spherical SiO2 particles have been coated with YVO4:Dy3+/Sm3+ phosphor layers by a Pechini sol-gel process, leading to the formation of core-shell structured SiO2@YVO4:Dy3+/Sm3+ particles. X-ray diffraction (XRD), Fourier-transform IR spectroscopy, field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), photoluminescence (PL) spectra as well as lifetimes were used to characterize the resulting SiO2 @YVO4:Dy3+/Sm3+ core-shell phosphors. The obtained core-shell phosphors have perfect spherical shape with narrow size distribution (average size ca. 300 nm), smooth surface and non-agglomeration. The thickness of shells could be easily controlled by changing the number of deposition cycles (20 nm for one deposition cycle). The core-shell particles show strong characteristic emission from Dy3+ for SiO2@YVO4:Dy3+ and from Sm3+ for SiO2@YVO4:Sm3+ due to an efficient energy transfer from YVO4 host to them. The PL intensity of Dy3+ and Sm3+ increases with raising the annealing temperature and the number of coating cycles.

Mass transfer kinetics of yttriium(III) using a constant interfacial cell with laminar flow. Part I. Extraction with Cyanex 302

The interfacial tension is measured for Cyanex 302 in heptane and adsorption parameters are calculated according to Gibbs equation and Szyskowski isotherm. The results indicate that Cyanex 302 has a high interfacial activity, allowing easy extraction reaction to take place at the liquid-liquid interface. The extraction kinetics of yttrium(III) with Cyanex 302 in heptane are investigated by a constant interfacial cell with laminar flow. The effects of stirring rate, temperature and specific interfacial area on the extraction rate are discussed. The results suggest that the extraction kinetics is a mixed regime with film diffusion and an aqueous one-step chemical reaction proposed to be the rate-controlling step. Assuming the mass transfer process can be formally treated as a pseudo-first-order reversible reaction with respect to the metal cation, the rate equation for the extraction reaction of yttrium(III) with Cyanex 302 at pH <5 is obtained as follows:R-f = 10(-7.85)[Y(OH)(2)(+)]((a))[H(2)A(2)]((o))(1.00)[H+]((a))(-1.00)Diffusion parameters and rate constants are calculated through approximate solutions of the flux equation.