Studies on extraction and mass transfer of samarium and neodymium in hollow fiber membrane (HFM) with HEH/EHP

The membranes of polyvinylidene fluoride, which were synthesized by our laboratory, were used to study the transfer and extraction performances of Nd(III) and Sm(III) with the extraction system of HEH/EHP-kerosene. The results show that the membrane material was suitable to the study on membrane extraction, and could offer a good transfer performance in the membrane construction parameters selected, The extraction reaction in the membrane module was the same as that in liquid-liquid process, HEH/EHP ammoniated for increasing the mass transfer coefficient was almost the same with increasing the concentration of HEH/EHP, and H+ was still transferred first at higher pH range of feed solution when HEH/EHP was ammoniated, The controlling model of the membrane extraction process was the diffusion model accompanied by interfacial reaction, The controlling function of interfacial reaction would increase gradually with the increasing of the membrane pore size. The mass transfer coefficient increased when extraction and stripping were carried out simultaneously.

Proton transfer across conducting polypyrrole membrane separated by two electrolyte solutions

Electrochemical behavior of the transfer of H+ across polypyrrole membrane (PPM) was studied. The transfer process was quasi-reversible and mainly diffusion-controlled. PPM electropolymerized in water solution has better reversibility than that in CH3CN solution for the transfer of H+. The transfer process of H+ across the two kinds of PPM indicated that the PPM electrochemically polymerized was of asymmetry.

Permeation of nitrogen and water vapor through sulfonated polyetherethersulfone membrane

The novel polyetherethersulfone (PES-C) prepared from phenol-phthalein in our institute is an amorphous, rigid, tough material with good mechanical properties over a wide temperature range. To improve its water vapor permeability for the application of gas drying, the PES-C was sulfonated with concentrated sulfuric acid and transferred in sodium, cupric, and ferric salt forms. The sulfonation degree can be regulated by controlling the temperature and reaction time. Characterization of sulfonated PES-C in sodium form was made by IR. Some properties of the sulfonated PES-C, such as solubility, glass transition temperature, thermal stability, mechanical properties, and transport properties to nitrogen and water vapor have also been discussed. (C) 1997 John Wiley & Sons, Inc.

Plasma modification of aromatic polyamide reverse osmosis composite membrane surface

The surface of aromatic polyamide reverse osmosis composite membrane was modified by oxygen and argon plasma. The water permeability of oxygen-plasma-modified membrane increases, and the chlorine resistance of argon-plasma-modified membrane increases. The spectra of the attenuated total reflection-Fourier transform infrared and X-ray photoelectron spectroscopy and the contact angle of the water were analyzed to explain the improvement of the two performances of the composite membrane. The carboxyl groups were introduced when modified by oxygen plasma, and cross-linking occurred when modified by argon plasma. (C) 1997 John Wiley & Sons, Inc.

Study of the miscibility and thermodynamics of cellulose diacetate-poly(vinyl pyrrolidone) blends

The miscibility of blends of cellulose diacetate (CDA) and poly(vinyl pyrrolidone) (PVP) was extensively studied by means of differential thermal analysis and dynamic mechanical thermal analysis, tensile test, measuring viscosity of diluted and concentrated solutions of blends in acetone-ethanol mixture and morphological observations. A single glass transition temperature is observed, which is intermediate between the glass transition temperatures associated with each component and depends on composition. A synergism in mechanical properties of blends was found. The absolute viscosity and the intrinsic viscosity of solutions of blends are much higher than the weight average values of solutions of CDA and PVP. Optically clear and thermodynamically stable films were formed in the composition range of CDA/PVP = 100/0 to 50/50w/w. Fourier transform infrared was used to investigate the nature of CDA-PVP interaction. Hydrogen bonds were formed between hydroxyl groups of CDA and carbonyl groups of PVP. Heats of solutions of CDA/PVP blends and their mechanical mixtures were measured by using a calorimeter. Mixing enthalpy obtained with Hess's law approach was used to quantify interaction parameters of this blending system. It was found that mixing enthalpies and interaction parameters were negative and composition dependent. (C) 1997 Elsevier Science Ltd.

The transfer of chloride ion across an anion exchange membrane

The transfer of chloride ions into a low resistance anion exchange membrane (AEM) was investigated by cyclic voltammetry (CV) and electrochemical impedance spectra. In all cases, concentration polarization of Cl- ions is exterior to the membrane. It controls the flux and produces the limiting currents: either steady state or transient (peak type) current. In CV experiments, when the size of the holes in the membrane was much smaller than the distance between membrane holes, the Cl- anion transfer showed steady state voltammetric behavior. Each hole in the membrane can be regarded as a microelectrode and the membrane was equivalent to a microelectrode array in this condition. When the hole in the membrane was large or the distance between membrane holes was small, the CV curve of the Cl- anion transfer across the membrane showed a peak shape, which was attributed to linear diffusion. In AC impedance measurement, the impedance spectrum of the membrane system was composed of two semicircles at low DC bias, corresponding to the bulk characteristics of the membrane and the kinetic process of ion transfer, respectively. The bulk membrane resistance increases with increasing DC bias and only one semicircle was observed at higher DC bias. The parameters related to kinetic and membrane properties were discussed.

Effective interface of a composite membrane serving as an ideally ultrathin barrier layer

A novel idea relating to the selective barrier layer of a composite membrane is described. The effective interface of the composite membrane could act as a barrier layer which could be controlled to an ideally ultrathin thickness. A new type of polyamide composite membrane was prepared according to this idea, which possessed permeability and chemical resistance more than one magnitude greater than those of ordinary polyamide composite membranes. Copyright (C) 1996 Elsevier Science Ltd.

Truly chlorine-resistant polyamide reverse osmosis composite membrane

Truly chlorine-resistant polyamide reverse osmosis composite membranes were prepared by cross-linking the interface of the composite membrane. Such membranes possessed chlorine resistance one order of magnitude more than those of the commercially used polyamide composite membranes. The effect of the degree of cross-linking on chlorine resistance was also described. (C) 1996 John Wiley & Sons, Inc.

APPLICATION OF POLYBUTADIENE-BASED POLYMERIC SURFACTANTS IN LIQUID MEMBRANE SEPARATION

New polybutadiene-based surfactants (LYF) were synthesized by sulfonation of liquid polybutadiene with acetal sulfate at an elevated temperature, and their properties in a liquid surfactant membrane (LSM) separation process were examined by comparison with the two polyisobutylene-based surfactants ECA4360 and EM301. It was found that LYF surfactants had satisfactory overall properties as regards stability, swelling, and demulsification Of the W/O emulsion in the cases of both acidic and caustic internal aqueous phases.

VOLTAMMETRY OF CYTOCHROME-C ENTRAPPED IN HYDROGEL MEMBRANE ON GRAPHITE ELECTRODE

The voltammetric behavior of cytochrome c entrapped in hydrogel membranes at paraffin wax-impregnated spectroscopic graphite electrodes (WISGE) was studied in this paper. A pair of well-defined peaks appeared at +70 mV (vs. Ag/AgCl). Beside these two peaks, another pair of peaks emerged at around +225 mV. Further investigations suggested that at least three states of cytochrome c existed in the membranes due to the special structure of the hydrogel. The native conformation of cytochrome c molecules was stabilized by the hydrophilic environment that was formed by the hydroxyl structure of the membranes and facilitated the cytochrome c electron transfer reaction at +70 mV. The molecules directly adsorbed on the surface of the graphite electrode were responsible for the redox peaks at around +225 mV. Whether the adsorption peaks were detectable or not was related to the thickness of membranes and the pre-retaining time before the formation of membranes.

IMPROVEMENT OF OXYGEN NITROGEN PERMSELECTIVITY OF POLY[1-(TRIMETHYLSILYL)-1-PROPYNE] MEMBRANE BY PLASMA POLYMERIZATION

The oxygen permselectivity of a poly[1-(trimethylsilyl)-1-propyne) (PTMSP) membrane was drastically improved by plasma polymerization of fluorine-containing monomers. The effects of such plasma polymerization conditions as deposition time, plasma power an

PREFERENTIAL SORPTION OF MODIFIED PVA MEMBRANE IN PERVAPORATION

The swelling processes of an annealed poly (vinyl alcohol) membrane, a NaOH-crosslinked poly (vinyl alcohol) membrane, a poly (vinyl alcohol)-N,N'-methylene bisacrylamide irradiation-crosslinked membrane and a poly (vinyl alcohol)/poly(AMcoAANa) blend membrane were investigated. Water was preferentially sorbed by all four membranes. The selective sorption factor alpha(s) and the selective diffusion factor alpha(d) were defined, and were used to characterize the effects of sorption and diffusion on selectivity. The results have shown that preferential sorption has a marked effect on selectivity. The mean diffusion coefficients and pervaporation properties of the four membranes are also discussed.

AN EXPERIMENTAL-STUDY ON MEMBRANE DISTILLATION CRYSTALLIZATION FOR TREATING WASTE-WATER IN TAURINE PRODUCTION

The solution of non-volatile solutes can be concentrated to saturation by membrane distillation. If the solute is easy to crystalize, the membrane distillation-crystallization phenomenon will appear during the membrane distillation of saturated solutions. It is possible that crystalline products are separated from concentrated solutions by a membrane process. In this work the PVDF capillary membrane, which was improved on hydrophobicity by using LiCl instead of a water-soluble polymer as an additive, has been used for treating the waste water of taurine. The crystalline product has been obtained from the waste water by the membrane distillation-crystallization technique. The results have shown good prospects for a membrane distillation application for treatment of industrial waste water.