川西呷村银多金属矿床成矿流体性质及成矿机理

“三江”地区是我国主要的火山岩型块状硫化物矿床成矿区域之一，产于赠科-乡城矿带的呷村矿床是我国典型的含金富银的块状硫化物矿床。矿床位于义敦古岛弧主弧带北段的昌台火山-沉积盆地中。该盆地上三叠统自下而上分为根隆组、呷村组和勉戈组，相应形成三个火山旋回，成矿作用发生在每个火山旋回末期。在呷村旋回的流纹质火山活动末期，形成呷村、嘎衣穷、夏塞等银多金属矿床。

中国煤矿废弃物环境效应研究进展

简述煤矿废弃物的环境地球化学效应和治理方法。分别论述了煤矸石山的自燃、淋滤和煤矿矿井水的环境效应。研究发现，煤矸石自燃会释放出SO2、CO、H2S、CO2、NOx、CH4、多环芳烃(PAHs)等多种有毒有害物质；煤矸石中的有害元素As、Cd、F、Hg、Mo、Pb等含量多与硫化物、硫酸盐等正相关，连续化学浸取能将很大部分毒害元素溶出；矿井水直接排放会引起地下水位下降和环境污染。目前我国对煤矿废弃物的环境效应研究已经很重视，但煤矸石和矿井水资源化治理还存在一些问题。

牢山金矿带成矿流体稀土元素地球化学

本项研究测定了矿石、蚀变围岩和相应未蚀变岩石的稀土元素组成。通过对这些地质体稀土元素地球化学特征的对比研究发现，在成矿流体的演化过程中，镇沅和墨江两个金矿床成矿流体的稀土模式具明显的变化，而大坪金矿成矿流体的稀土模式则保持相对不变。因此，大坪金矿的稀土模式（轻稀土高度富集、弱负Ｅｕ异常和较强负Ｃｅ异常）可以代表初始成矿流体的稀土模式。研究表明，具有这种稀土模式的流式，可能是由地幔去气作用产生的地幔.

天然气气源对比研究方法进展

一直以来同位素地球化学在气源对比研究中发挥着重要作用，天然气组分碳、氢稳定同位素已经用于判别天然气的烃源岩、源岩热演化程度和成藏过程，稀有气体同位素也已经广泛运用于天然气的来源判别。近年来，又发展了诸如流体包裹体气源对比方法，利用苯、甲苯、二甲苯、甲基环己烷等轻烃单体碳同位素气源对比方法，天然气组分的详细解剖与气源直接对比方法和气源动态综合对比方法等，这些方法促进了天然气气源对比的深入研究。比较系统地介绍了气源对比方法上的发展、创新和今后发展的一些趋势。

The formation of Co2C species in activated carbon supported cobalt-based catalysts and its impact on Fischer-Tropsch reaction

The cobalt carbide (Co2C) species was formed in some activated carbon supported cobalt-based (Co/AC) catalysts during the activation of catalysts. It was found that the activity of Fischer-Tropsch reaction over Co-based catalysts decreased due to the formation of cobalt carbide species. Some promoters and pretreatment of activated carbon with steam could restrain the formation of cobalt carbide.

Measurements of the heat capacity of an azeotropic mixture of water and n-butanol from 78 to 320 K

Molar heat capacities of n-butanol and the azeotropic mixture in the binary system [water (x=0.716) plus n-butanol (x=0.284)] were measured with an adiabatic calorimeter in a temperature range from 78 to 320 K. The functions of the heat capacity with respect to thermodynamic temperature were established for the azeotropic mixture. A glass transition was observed at (111.9 +/- 1.1) K. The phase transitions took place at (179.26 +/- 0.77) and (269.69 +/- 0.14) K corresponding to the solid-liquid phase transitions of. n-butanol and water, respectively. The phase-transition enthalpy and entropy of water were calculated. A thermodynamic function of excess molar heat capacity with respect to temperature was established, which took account of physical mixing, destructions of self-association and cross-association for n-butanol and water, respectively. The thermodynamic functions and the excess thermodynamic ones of the binary systems relative to 298.15 K were derived based on the relationships of the thermodynamic functions and the function of the measured heat capacity and the calculated excess heat capacity with respect to temperature.

Insight into permeability of protein through microcapsule membranes

The objective of this paper is to analyze the characteristics of protein permeability in alainate-polylysine-alginate (APA) and alginate-chitosan-alginate (ACA) microcapsules by mathematical models based on the balance of chemical potential. The comparison between calculated results and experimental data shows that the models can describe the process of protein diffusion from microcapsule and protein release into microcapsule successfully. The influences of membrane composition on the permeability of ACA microcapsule have been investigated and analyzed. The effect of resistance on the mass transfer is further analyzed theoretically with the aid of mathematical modeling. (c) 2005 Elsevier B.V. All rights reserved.