景观动态的Markov模型研究——以长白山自然保护区为例

在 Markov模型假设的基础上 ,利用长白山自然保护区 1975年 MSS、1985年和 1997年 TM卫星遥感数据 ,在遥感图象处理软件和 GIS软件协助下 ,对遥感影像的计算机监督分类结果 (共分为 13类 )进行处理 ,对 Markov模型的可利用性进行分析与检验 ,得出长白山自然保护区景观变化无后效性 ,符合 Markov模型条件。根据 1985～ 1997年转移概率计算步长 10 a(1985～ 1995年 )的转移概率矩阵 ,从 1975年计算 1985年各景观类型的面积与 1985年各景观类型的实际面积值对比 ,计算得 χ2 >χ20 .0 5(12 ) ;再分别用 1975～ 1985年和 1985～ 1997年的转移矩阵计算 1995年和 2 0 4 7年各景观类型的面积 ,分析得χ2 >χ20 .0 5(12 ) ;对两阶段的转移概率矩阵分析得到 χ2 >χ20 .0 5(14 4 ) ;说明两阶段的 Markov转移过程不具同一性 ,属于两个不同的 Markov过程。不同景观类型转移方式对χ2 值的贡献率可以说明其对景观动态的重要性 ,分析结果表明有重要贡献的类型分别为 :阔叶红松林 5 2 .0 0 % >山杨白桦林 2 4 .6 6 % >云冷杉林 11.4 2 % >落叶松林 2 .4 3% ,说明这 4种景观类型的转移方式对长白山自然保护区的景观动态起重要作用 ,尤其以阔叶松林的作用最大 ;同时对 Markov模型在长白山自然保护区长期景观变化预测的可

景观指数之间的相关分析

应用辽宁省1997~1998年的TM 5影像数据,编制了景观类型图,以78个县市区为单位,分割成78个景观,共计算39个景观格局指数,对它们进行了相关分析。总面积是最基本的景观指数,它决定景观总边界长度、斑块数、类型密度等基本指数,同时与多个指数有显著的相关关系(相关系数绝对值大于0.75)。形状指数的独立性强,极少数指数与其它指数有显著的相关关系;多样性指数和蔓延度指数之间信息重复量最多,都表示景观的异质性,但多样性指数以面积百分比表示景观异质性,而蔓延度指数以类型之间相邻边界的百分比表示景观异质性。研究发现,如果两个指数之间存在显著的相关关系,而由它们两个构成的指数与它们之间没有显著的相关关系。如果指数平均值之间存在显著的相关关系,则它们的变异系数之间不存在显著的相关关系。景观指数间的相关系数不仅与景观格局本身有关,还与空间尺度,分类系统、计算公式及其参数、计算单元和生态学意义关系密切。指数之间影响因子的相同之处越多,它们之间存在显著相关关系的概率越大。

25年来中国旅游容量研究的回顾与反思

20世纪80年代以来,中国旅游容量研究得到了较快发展。在回顾国内旅游容量研究的基础上,从理论和实践角度反思中国旅游容量研究25年的发展和问题,结论如下:我国旅游容量规划规范亟需补充完善;我国旅游容量管理方法亟需改进;国内学术界对旅游容量的认识尚存在若干误区。针对以上问题,通过综合分析国内外旅游容量的研究成果,深入探讨旅游容量的本质特征,对旅游容量的本质特征和旅游容量在实践中的发展方向形成如下基本认识:①旅游容量体现的是载体与被载体、容器与被容物之间的关系;②旅游容量反映的是景区系统中各种因子(尤其是限制性

Analysis of spatio-temporal dynamic pattern and driving forces of urban land in China in 1990s using TM images and GIS

China has witnessed fast urban growth in the recent decade. This study analyzes spatio-temporal characteristics of urban expansion in China using satellite images and regionalization methods. Landsat TM images at three time periods, 1990/1991, 1995/1996, and 1999/2000, are interpreted to get 1:100000 vector land use datasets. The study calculates the urban land percentage and urban land expansion index of every 1 km(2) cell throughout China. The study divides China into 27 urban regions to conceive dynamic patterns of urban land changes. Urban development was achieving momentum in the western region, expanding more noticeably than in the previous five years, and seeing an increased growth percentage. Land use dynamic changes reflect the strong impacts of economic growth environments and macro-urban development policies. The paper helps to distinguish the influences of newly market-oriented forces from traditional administrative controls on China's urban expansion. (c) 2005 Elsevier Ltd. All rights reserved.

Uncertainties in estimates of cropland area in China: a comparison between an AVHRR-derived dataset and a Landsat TM-derived dataset

The large uncertainties in estimates of cropland area in China may have significant implications for major cross-cutting themes of global environmental change-food production and trade, water resources, and the carbon and nitrogen cycles. Many earlier studies have indicated significant under-reporting of cropland area in China from official agricultural census statistics datasets. Space-borne remote sensing analyses provide an alternative and independent approach for estimating cropland area in China. In this study, we report estimates of cropland area from the National Land Cover Dataset (NLCD-96) at the 1:100,000 scale, which was generated by a multi-year National Land Cover Project in China through visual interpretation and digitization of Landsat TM images acquired mostly in 1995 and 1996. We compared the NLCD-96 dataset to another land cover dataset at I-km spatial resolution (the IGBP DIScover dataset version 2.0), which was generated from monthly Advanced Very High Resolution Radiometer (AVHRR)-derived Normalized Difference Vegetation Index (NDVI) from April, 1992 to March, 1993. The data comparison highlighted the limitation and uncertainty of cropland area estimates from the DIScover dataset. (C) 2003 Elsevier Science B.V. All rights reserved.

Synthesis and Luminescent Properties of LaAlO3:RE3+ (RE = Tm, Tb) Nanocrystalline Phosphors via a Sol-Gel Process

LaAlO3:Tm3+ and LaAlO3:Tb3+ phosphors were prepared through a Pechini-type sol-gel process. X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), photoluminescence, and cathodoluminescence (CL) spectra were utilized to characterize the synthesized phosphors. The XRD results reveal that the fully crystalline pure LaAlO3 Phase can be obtained at 800 degrees C. The FE-SEM image indicates that the phosphor samples are composed of aggregated spherical particles with sizes ranging from 40 to 80 nm. Under the excitation of ultraviolet light (230 nm) and low-voltage electron beams (1-3 kV), the LaAlO3:Tm3+ and LaAlO3:Tb3+ phosphors show the characteristic emissions of Tb3+ (D-1(2)-> H-3(6,4),F-3(4) transitions) and Tm3+ (D-5(3,4)-> F-7(6,5,4,3) transitions) respectively. The CL of the LaAlO3:Tm3+ phosphors have high color purity and comparable intensity to the Y2SiO5:Ce3+ commercial product, and the CL colors of Tb3+-doped LaAlO3 phosphors can be tuned from blue to green by changing the doping concentration of Tb3+ to some extent.

Self-assembled 3D flowerlike Lu2O3 and Lu2O3 : Ln(3+) (Ln = Eu, Tb, Dy, Pr, Sm, Er, Ho, Tm) microarchitectures: Ethylene glycol-mediated hydrothermal synthesis and luminescent properties

Three-dimensional flowerlike Lu2O3 and Lu2O3:Ln(3+) (Ln = Eu, Th, Dy, Pr, Sm, Er, Ho, Tm) microarchitectures have been successfully synthesized via ethylene glycol (EG)-mediated hydrothermal method followed by a subsequent heat treatment process. X-ray diffraction, Fourier transform infrared spectroscopy, energy-dispersive X-ray spectra, thermogravimetric and differential thermal analysis, elemental analysis, inductively coupled plasma atomic absorption spectrometric analysis, ion chromatogram analysis, X-ray photoelectron spectra, scanning electron microscopy, transmission electron microscopy, photoluminescence spectra as well kinetic decays, and cathodoluminescence spectra were used to characterize the samples. Hydrothermal temperature, EG, and CH3COONa play critical roles in the formation of the lutetium oxide precursor microflowers. The reaction mechanism and the self-assembly evolution process have been proposed. The as-formed lutetium oxide precursor could transform to Lu2O3 With their original flowerlike morphology and slight shrinkage in the size after postannealing process.

Four New Lanthanide-Nitronyl Nitroxide (Ln(III)=Pr-III, Sm-III, Eu-III, Tm-III) Complexes and a Tb-III Complex Exhibiting Single-Molecule Magnet Behavior

Five new complexes based on rare-earth-radical [Ln(hfac)(3)(NIT-5-Br-3py)](2) (Ln=Pr (1), Sm (2), Eu (3), Tb (4), Tm (5); hfac = hexafluoroacetylacetonate; NIT-5-Br-3py = 2-(4,4,5,5-tetramethyl-3-oxylimidazoline-1-oxide)-5-bromo-3-pyridine) have been synthesized and characterized by X-ray crystal diffraction. The single-crystal structures show that these complexes have similar structures, in which a NIT-5-Br-3py molecule acts as a bridging ligand linking two Ln(III) ions through the oxygen atom of the N-O group and nitrogen atom from the pyridine ring to form a four-spin system. Both static and dynamic magnetic properties were measured for complex 4, which exhibits single-molecule magnetism behavior.

电感耦合等离子体质谱法测定高纯氧化钕中的稀土杂质

基于电感耦合等离子体四极杆质谱仪进行Nd2O3中稀土杂质测定,着重研究了碰撞反应池技术(CCT)用于基体Nd氧化物和氢氧化物干扰离子的消除。研究表明,以10%O2-10%Ar-80%He为碰撞反应气,保持反应气流速为0.1 mL/min,并通过调谐仪器参数,获得159Tb,165Ho,163Dy同位素的175TbO,179DyO和181HoO出现强氧化物峰,通过对这些氧化物离子进行检测而实现Tb,Dy,Ho的定量分析。在优化的条件下,基体导致的氧化物和氢氧化物质谱干扰可降低25～70倍。研究了CCT模式下不同内标元素用于基体效应的校正。结果表明,Re的校正效果最佳。其余La,Ce,Pr,Sm,Eu,Gd,Er,Tm,Yb和Lu等元素采用常规模式测定,其中Pr的测定采用高分辨以消除基体Nd前沿峰干扰。结合干扰系数校正,所建立的方法适用于99.999%Nd2O3的纯度分析,RSD小于5%,加入回收率令人满意。

Highly uniform and monodisperse beta-NaYF4 : Ln(3+) (Ln = Eu, Tb, Yb/Er, and Yb/Tm) hexagonal microprism crystals: Hydrothermal synthesis and luminescent properties

beta-NaYF4:Ln(3+) (Ln = Eu, Tb, Yb/Er, and Yb/Tm) hexagonal microprisms with remarkably uniform morphology and size have been synthesized via a facile hydrothermal route. X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HRTEM), and photoluminescence (PL) spectra as well as kinetic decays were used to characterize the samples. It is found that sodium citrate as a shape modifier introduced into the reaction system plays a critical role in the shape evolution of the final products. Furthermore, the shape and size of the products can be further manipulated by adjusting the molar ratio of citrate/RE3+ (RE represents the total amount of Y3+ and the doped rare earth elements such as Eu3+, Tb3+, Yb3+/Er3+, or Yb3+/Tm3+). Under the excitation of 397 nm ultraviolet light, NaYF4:xEu(3+) (x = 1.5, 5%) shows the emission lines of Eu3+ corresponding to D-5(0-3) -> F-7(J) (J = 0-4) transitions from 400 to 700 nm (whole visible spectral region) with different intensity, resulting in yellow and red down-conversion (DC) light emissions, respectively.

Thermoluminescence studies of LiBa2B5O10 : RE3+ (RE = Dy, Tb and Tm)

LiBa2B5O10:RE3+ (RE = Dy, Tb and Tm) was synthesized by the method of high-temperature solid-state reaction and the thermoluminescence (TL) properties of the samples under the irradiation of the gamma-ray were studied. The result showed that Dy3+ ion was the most efficient activator. When the concentration of Dy3+ was 2 mol%, LiBa2B5O10:Dy3+ exhibited a maximum TL output. The kinetic parameter of LiBa2B5O10:0.02Dy was estimated by the peak shape method, for which the average activation energy was 0.757 eV and the frequency factor was 1.50 x 10(7) s(-1). By the three-dimensional (3D) TL spectrum, the TL of the sample was contributed to the characteristic f-f transition of DY3+. The dose-response of LiBa2B5O10:0.02Dy to gamma-ray was linear in the range from 1 to 1000 mGy. In addition, the decay of the TL intensity of LiBa2B5O10:0.02Dy was also investigated.

Structural and magnetic properties of Sr2Fe1−xGaxMoO6 (0≤x≤0.25)

We have investigated the structure, magnetization and magnetoresistance (MR) of the double perovskite compounds Sr2Fe1−xGaxMoO6 (0≤x≤0.25). Rietveld refinement results show that the anti-site defects (ASDs) concentration increases with x, giving rise to highly disordered samples at the B/B positions, for the highest doping levels. The evolution of bond lengths and ions oxidation states could be understood by the distribution of trivalent Ga ions at the B/B positions, which leads to the formation of more disorder structure. The saturation magnetization and Curie temperature decreased with the Ga content increases in the samples, and their origin was found that the cations disorder for the Ga-doped compounds is annihilating double exchange mechanism due to the presence of significant amounts of Fe and Ga cations on the B site. The low-field magnetoresistance of Sr2FeMoO6 (SFMO) can be greatly enhanced by replacing the Fe by the nonmagnetic Ga ion up to a temperature of 300 K,since Ga ions may act as a barrier for electron transport along the chain in the ferromagnetic segregation and weaken the ferromagnetic exchange.

An investigation of low-field magnetoresistance in the double perovskites Sr2Fe1-xZnxMoO6, x=0, 0.05, 0.15 and 0.25

The electrical, magnetic and transport properties of Zn doped polycrystalline samples of Sr2Fe1-xZnxMoO6 ( x = 0, 0.05, 0.15 and 0.25) with the double perovskite structure have been investigated. The subtle replacement of Fe3+ ions by Zn2+ ions facilitates the formation of a more ordered structure, while further substitution leads to disordered structure because of the presence of a striped phase. Analysis of the x-ray powder diffraction patterns based on Rietveld analysis indicates that the replacement of Fe3+ by Zn2+ ions favours the formation of Mo6+ ions. The spin-glass behaviour can be explained on the basis of the competition between the antiferromagnetic superexchange and the ferromagnetic double-exchange interaction. The low-field magnetoresistance was moderately enhanced at x = 0.05, and its origin was found to be the competition between the decrease of the concentration of the itinerant electrons and the weaker antiferromagnetic superexchange in the antiphase boundaries. An almost linear negative magnetoresistance in moderate field has been observed for x = 0.25. A possible double-exchange mechanism is proposed for elucidating the observations; it also suggests a coexistence of (Fe3+, Mo5+) and (Zn2+, Mo6+) valence pairs.