EDTA-controlled one-pot preparation of novel shaped gold microcrystals and their application in surface-enhanced Raman scattering

We report a one-pot preparation method for a series of novel shaped gold microcrystals by simply mixing HAuCl4 with disodium salt of ethylenediaminetetraacetic acid (Na(2)EDTA). Under the different reaction temperatures, spinous structures, multipod microspheres, and rough surfaced microspheres were obtained. These microcrystals exhibit high surface-enhanced Raman scattering (SERS) activity.

Nonvolatile memory devices based on gold nanoparticle and poly (N-Vinylcarbazole) composite

A rewritable polymer memory device based on gold nanoparticle doped poly (N-vinylcarbazole) (PVK), which can be easily fabricated by simple spin coating, has been described. An electrical bistable phenomenon is observed in the current-voltage characteristics of this device, and it is found that the electrical bistability is repeatable by proper writing voltage and erasing voltage. The unique behavior of the devices provides an interesting approach such that doping nanoparticles in polymer can be used to realize high performance nanovolatile polymer memory devices.

Electropolymerization and catalysis of well-dispersed polyaniline/carbon nanotube/gold composite

Polyaniline/multi-walled carbon nanotube/gold (PANI/MWNT/Au) composite film was synthesized via a two-step electrochemical process. First the mixture of aniline and MWNT was heated at refluxing and was electropolymerized. Then, the An nanoparticles were dispersed into the film of PANI/MWNT by electrochemical reduction of HAuCl4. The morphology of sample was analyzed by scanning electron microscopy (SEM). Raman measurement indicates a well electrochemical deposition of PANI on MWNT, and XPS result confirms the formation of Au-0 nanoparticles. Further, cyclic voltammograms show that the film exhibits a good electrochemical activity and electrocatalysis towards ascorbic acid. Based on these investigations, a formation mechanism of the PANI/MWNT composite film was proposed.

One-step synthesis of gold-polyaniline core-shell particles

A one-step method has been developed for synthesizing gold-polyaniline (Au@PANI) core-shell particles by using chlorauric acid (HAuCl4) to oxidize aniline in the presence of acetic acid and Tween 40 at room temperature. SEM images indicated that the resulting core-shell particles were composed of submicrometre-scale Au particles and PANI shells with an average thickness of 25 nm. Furthermore, a possible mechanism concerning the growth of Au@PANI particles was also proposed based on the results of control experiments.

Thionine-interlinked multi-walled carbon nanotube/gold nanoparticle composites

Multi-walled carbon nanotube (MWCNT)/thionine/gold nanoparticle composites were prepared by binding gold nanoparticles to the surfaces of thionine-coated carbon nanotubes. TEM images show gold nanoparticles distributed uniformly on nanotube walls and ends. UV-Vis, Raman, FT-IR, and zeta potential measurements were used to examine the properties of the resulting products. The composites demonstrate significant electrocatalytic activity for oxygen reduction. Although only gold nanoparticles were investigated here, the method could be easily extended to attach other metallic nanoparticles to the sidewalls of carbon nanotubes.

Synthesis, characterization, and self-assembly of protein lysozyme monolayer-stabilized gold nanoparticles

Lysozyme monolayer-protected gold nanoparticles (Au NPs) which are hydrophilic and biocompatible and show excellent colloidal stability at low temperature, ca. 4 degrees C, were synthesized in aqueous medium by chemical reduction of HAuCl4 with NaBH4 in the presence of a familiar small enzyme, lysozyme. UV-vis spectra, transmission electron microscopy (TEM), atomic force microscopy, and X-ray photoelectron spectroscopy characterization of the as prepared nanoparticles revealed the formation of well-dispersed An NPs of ca. 2 nm diameter. Moreover, the color change of the An NP solution as well as UV-vis spectroscopy and TEM measurements have also demonstrated the occurrence of Ostwald ripening of the nanoparticles at low temperature. Further characterization with Fourier transform infrared spectroscopy (FTIR) and dynamic light scattering indicated the formation of a monolayer of lysozyme molecules on the particle surface. FTIR data also indicated the intactness of the protein molecules coated on An NPs. All the characterization results showed that the monodisperse An NPs are well-coated directly with lysozyme. Driven by the dipole-dipole attraction, the protein-stabilized Au NPs self-assembled into network structures and nanowires upon aging under ambient temperature.

Large-scale, uniform DNA network on 11-mercaptoundecanoic acid modified gold (111) surface: Atomic force microscopy study

Large-scale, uniform plasmid deoxyribonucleic acid (DNA) network has been successfully constructed on 11-mercaptoundecanoic acid modified gold (111) surface using a self-assembly technique. The effect of DNA concentration on the characteristics of the DNA network was investigated by atomic force microscopy. It was found that the size of meshes and the height of fibers in the DNA network could be controlled by varying the concentration of DNA with a constant time of assembly of 24 h.

Self-assembled gold nanoparticle chains in presence of silver ions

A simple method has been developed to assemble gold nanoparticles to generate 1D assemblies by the assistance of silver ions. The lengths of nanoparticle chains can be controlled by adjusting the content of silver ions in the system. The assembly procedure of gold nanoparticles chains requires no template. The gold nanoparticle chains were characterized using TEM and XPS techniques.

A simple and effective route for the preparation of poly(vinylalcohol) (PVA) nanofibers containing gold nanoparticles by electrospinning method

Poly(vinyl alcohol) (PVA) nanofibers containing gold nanoparticles have been simply obtained by electrospinning a solution containing gold nanoparticles without the additional step of introducing other stabilizing agents. The optical property of gold nanoparticles in PVA aqueous solution was observed by UV-visible absorption spectra. Morphology of the Au/PVA nanofibers and distribution of the gold nanoparticles were characterized by transmission electron. microscopy (TEM). The structure transformation was characterized from PVA to PVA/Au composite by Fourier transform infrared spectroscopy (FTIR).

Interfacial supramolecular self-assembled monolayers of C-60 by thiolated beta-cyclodextrin on gold surfaces via monoanionic C-60

The supramolecular self-assembled monolayers (SAMs) of C-60 by thiolated beta-cyclodextrin (CD) on gold surfaces were constructed for the first time using C-60 monoanion. The results indicate that monoanionic C-60 plays a crucial role in the formation of the C-60-containing self-assembled monolayers. The generation of C-60 monoanion and the formation process of C-60 SAMs were monitored in-situ by UV-visible and near-IR spectroscopy. The resulting C-60 SAMs were fully characterized by spectroscopic ellipsometry (SE), cyclic voltammetry, X-ray photoelectron spectroscopy (XPS), and water contact angle measurements. After the immobilization of C-60 by the SAMs of thiolated beta-CD, the film thickness increased by approximately 1 nm from 0.8 to 1.8 nm as determined by SE, demonstrating the formation of the supramolecular self-assembled monolayers of thiolated beta-CD/C-60. The new C-60 SAMs exhibited one quasi-reversible redox couple at half wave potential of -0.57 V vs SCE in aqueous solution containing 0.1 M KCl. The surface coverage of C-60 on the gold surfaces was estimated to be 1.1 x 10(-10) mol cm(-2). The XPS showed the assembly of C-60 over the thiolated beta-CD SAMs.