Influence of Contact Geometry on Hardness Behavior in Nano-indentation

In this paper the influence of contact geometry, including the round tip of the indenter and the roughness of the specimen, on hardness behavior for elastic plastic materials is studied by means of finite element simulation. We idealize the actual indenter by an equivalent rigid conic indenter fitted smoothly with a spherical tip and examine the interaction of this indenter with both a flat surface and a rough surface. In the latter case the rough surface is represented by either a single spherical asperity or a dent (cavity). Indented solids include elastic perfectly plastic materials and strain hardening elastic-plastic materials, and the effects of the yield stress and strain hardening index are explored. Our results show that due to the finite curvature of the indenter tip the hardness versus indentation depth curve rises or drops (depending on the material properties of the indented solids) as the indentation depth decreases, in qualitative agreement with experimental results. Surface asperities and dents of curvature comparable to that of the indenter tip can appreciably modify the hardness value at small indentation depth. Their effects would appear as random variation in hardness.

奇奇核~(90)Nb的高自旋态研究

用能量为80MeV的19F束通过反应76Ge(19F,5n)90Nb布居了90Nb的高自旋态.通过在束γ测量分析90Nb退激γ射线的符合级联关系,发现了19条新的属于90Nb的γ跃迁,建立了90Nb的高自旋态能级纲图.通过经验壳模型计算指定了部分能级的组态,并结合实验DCO比值和与相邻N=49核素的系统比较,确认了新能级的自旋和宇称.

Reconstructing the interaction between dark matter and holographic dark energy

We reconstruct the interaction rate between dark matter and the holographic dark energy with the parametrized equation of states and the future event horizon as the infrared cutoff length. It is shown that the observational constraints from the 192 type Ia Supernovae (SnIa) and baryon acoustic oscillation (BAO) measurement permit the negative interaction in the wide region. Moreover, the usual phenomenological descriptions cannot describe the reconstructed interaction well for many cases. The other possible interaction is also discussed.

Energy-level shifts of a stationary hydrogen atom in a static external gravitational field with Schwarzschild geometry

he first order perturbations of the energy levels of a stationary hydrogen atom in a static external gravitational field, with Schwarzschild metric, are investigated. The energy shifts are calculated for the relativistic 1S, 2S, 2P, 3S, 3P, 3D, 4S, 4P, 4D, and 4F levels. The results show that the energy-level shifts of the states with total angular momentum quantum number 1/2 are all zero, and the ratio of absolute energy shifts with total angular momentum quantum number 5/2 is 145. This feature can be used to help us to distinguish the gravitational effect from other effects.

The geometry of the NO2- anion: ab initio calculations and Franck-Condon analysis

Geometry optimization and harmonic vibrational frequency calculations have been performed on the (X) over bar (2)A(1) state of NO2 and (X) over bar (1)A(1) state of NO2-. Franck-Condon analyses and spectral simulations were carried out on the NO2((X) over bar (2)A(1))-NO2-((X) over bar (1)A(1)) photo detachment process. In addition, the equilibrium geometry parameters, r(NO)= 1.248 +/- 0.005 Angstrom and angle(ONO) 116.8 +/- 0.5degrees, of the (X) over bar (1)A(1) state of NO2-, are derived by employing an iterative Franck-Condon analysis procedure in the spectral simulation. Our conclusions regarding the anion geometry suggest a reinterpretation of the results of Woo et al. (C) 2004 Published by Elsevier B.V.

Stability shear stress and equilibrium cross-sectional geometry of sheltered tidal channels

This study relates tidal channel cross-sectional area (A) to peak spring discharge (Q) via a physical mechanism, namely the stability shear stress ( tau sub(S)) just necessary to maintain a zero gradient in net along-channel sediment transport. It is assumed that if bed shear stress ( tau ) is greater than tau sub(S), net erosion will occur, increasing A, and reducing tau similar to (Q/A) super(2) back toward tau sub(S). If tau < tau sub(S) there will be net deposition, reducing A and increasing tau toward tau sub(S). A survey of the literature allows estimates of Q and A at 242 sections in 26 separate sheltered tidal systems. Assuming a single value of tau sub(S) characterizes the entire length of a given tidal channel, it is predicted that along-channel geometry will follow the relation Ah sub(R) super(1) super(/) super(6) similar to Q. Along-channel regressions of the form Ah sub(R) super(1) super(/) super(6) similar to Q super( beta ) give a mean observed value for beta of 1.00 plus or minus 0.06, which is consistent with this concept. Results indicate that a lower bound on tau sub(S) (and an upper bound on A) for stable channels is provided by the critical shear stress ( tau sub(C)) just capable of initiating sediment motion. Observed tau sub(S) is found to vary among all systems as a function of spring tidal range (R sub(sp)) according to the relation tau sub(S) approximately 2.3 R sub(sp) super(0.79) tau sub(C). Observed deviations from uniform tau sub(S) along individual channels are associated with along-channel variation in the direction of maximum discharge (i.e., flood-versus ebb-dominance).

20世纪90年代中国土地利用变化时空特征及其成因分析

在土地利用变化时空信息平台的支持下,本文对我国20世纪80年代末到90年代末的土地利用变化过程进行了全面分析,揭示了我国10年来土地利用变化的时空规律,分析了这些规律形成的主要政策、经济和自然成因。研究表明,20世纪90年代,全国耕地总面积呈北增南减、总量增加的趋势,增量主要来自对北方草地和林地的开垦。林业用地面积呈现总体减少的趋势,减少的林地主要分布于传统林区,南方水热充沛区造林效果明显。中国城乡建设用地整体上表现为持续扩张的态势。90年代后5年总体增速减缓,西部增速加快。20世纪90年代我国的土地利用变化表现出明显的时空差异,政策调控和经济驱动是导致土地利用变化及其时空差异的主要原因。据此,本文提出在今后的全国土地利用规划中,应充分考虑我国现代土地利用变化的区域分异规律。同时,在生态环境恢复与建设规划中也应强调自然地理地带的针对性,同时要改变传统的资源规划与管理思路,在基础设施日益完备的条件下,最大程度地发挥跨区域土地资源优化配置的综合优势

基于遥感与GIS的20世纪90年代中国城镇用地时空特征

文章利用20世纪90年代初期、中期和末期全国1∶100000土地利用动态变化数据提取城镇用地动态变化数据,利用单元自动机和人工神经网络模型对全国城镇用地进行了区划。在此基础上,研究了90年代两个阶段中国城镇用地时空格局。研究表明:90年代前5年东部沿海地区受经济高速发展和开放政策的影响,城镇用地扩展迅速,中西部地区城镇用地扩展较慢;90年代后5年国家加大了耕地资源保护力度,在政府宏观调控政策和耕地资源保护条例的影响下,东部沿海地区城镇用地扩展大幅回落,中部地区城镇扩展也有较大幅度回落,西部地区随着经济发展加快,城镇用地扩展回落较小。

20世纪90年代内蒙古自治区土地利用动态与风力侵蚀动态对比研究

内蒙古是我国风力侵蚀较为严重的地区之一,同时也是我国土地利用方式剧烈变化的地区之一。依据两期土地利用数据以及相应年代的土壤风力侵蚀数据,研究了20世纪90年代内蒙古自治区土地利用和风力侵蚀的静、动态格局。根据土地利用和风力侵蚀的空间分布及动态变化特点,设计了内蒙古土地利用—风力侵蚀动态区划,基于该区划详细讨论了内蒙古不同地区占主导地位的土地利用动态与风力侵蚀动态,由此揭示了两者之间存在的驱动——被驱动关系。研究发现,在过去10年里,内蒙古土地利用和风力侵蚀的基本格局没有太大变化,但风力侵蚀在总体上是增强了,而土地利用的变化主要反映为草地的退化和耕地的扩张。土地利用动态与风力侵蚀动态有着良好的时空对应关系草地的退化与耕地的扩张导致了显著的风力侵蚀增强,而草地的改善以及耕地的收缩对风力侵蚀的影响不是很大,这同时也表明了土地利用动态对风力侵蚀动态正、反向驱动力的不平衡性。

20世纪90年代LUCC过程对中国农田光温生产潜力的影响:基于气候观测与遥感土地利用动态观测数据

在20世纪90年代中国气候观测数据和遥感土地利用动态观测数据的支持下,计算了中国20世纪90年代农田光温生产潜力的变化.结果表明:20世纪90年代的LUCC过程直接导致了中国农田光温生产潜力总量和区域分布的变化,总体趋势是南减北增,总量净增加2622万吨;在各种土地利用类型之间的相互转变和转化过程中,耕地扩张和农田损失是导致全国农田光温生产潜力总量净变化的主要原因,耕地扩张使全国农田光温生产潜力总量净增加8335万吨,占全国农田光温生产潜力总量的3.50%,主要分布在东北、西北和华北等农林、农牧交错区和沙漠绿洲区,主要是由于该地区大面积的农田开垦所导致;农田损失使全国农田光温生产潜力总量净减少5713万吨,占全国农田光温生产潜力总量的2.40%,主要分布在黄淮海平原、长江三角洲、珠江三角洲、陇中、东南沿海、四川盆地东南部以及乌鲁木齐—石河子一带,主要是由于该区域经济发展较快,城市扩张明显,城乡建设用地大量侵占耕地的缘故.

Synthesis and crystal structure of 3-methoxycarbonylethyltin tetrachlorides anion

The anion of MeO2CCH2CH2SnCl4 - was obtained by decomposing the yellow solution of MeO2CCH2CH2SnCl3.(2-OHC6H4CH=NC6H5) by standing for 15 days, which is the product of 3-methoxy-carbonylethyltin trichlorides with Schiff base (2-OHC6H4CH=NC6H5). The title compound was characterized by elemental analysis, IR. H-1 NMR,C-13 NMR and X-ray diffraction analysis. The crystal of the title compound belongs to orthorhombic system, space group P2cn, a=7.852(2), b=12.236(1),c=16.952(4)Adegrees, V=1628.7 Angstrom(3), Z=4, D-c=1.79g/cm(3) F(000)=860, mu=22.2cm(-1), R=0.0449, Rw=0.0382. The title compound exists as a discrete molecule, and the tin atom attains a distorted octahedral geometry via the coordination of intramolecular carbonyl oxygen and chloride ion. The coordination number of tin atom is 6.

Synthesis and crystal structure of [Nd(eta(6)-1,3,5-C6H3Me3)(AlCl4)(3)]( C6H6) and structural comparison of Ln(eta(6)-arene)(AlCl4)(3)

Reaction of NdCl3, with AlCl3 and mesitylene in benzene gives complex [Nd(eta (6)-1,3,5-C6H3Me3) (AlCl4)(3)] (C6H6) (1) which was characterized by elemental analysis, IR spectra, MS and X-lay diffractions. The X-ray determination indicates that 1 has a distorted pentagonal bipyramidal geometry and crystallizes in the monoclinic, space group P2(1)/n with a = 0.9586(2), b = 1.1717(5), c = 2.8966(7) nm, beta = 90.85 (2)degrees, V = 3.2529(6) nm(3), D-c = 1.573 g/cm(3), Z = 4. A comparison of bond parameters for all the reported Ln(eta (6)-Ar) (AlCl4)(3) complexes indicates that the bond distance of Ln-C is shortened with the increasing of methyl group on benzene and with the decreasing of radius of lanthanide ions.