辽东湾芦苇湿地对陆源营养物质净化作用的初步研究

通过廊道系统自净和lysimeter渗滤实验进行了辽东湾芦苇湿地对陆源营养物质净化作用的初步研究 .结果表明 ,营养物质N、P和CODcr在廊道系统中的自净率为 41.7%～ 64 .71% .不同深度的土壤 -芦苇系统对陆源营养物质N、P和CODcr的净化率为 60 .0 %～ 75 .92 % .N、P营养物质经湿地系统过滤后可满足海水水质 2类标准 .通过收获地上部分生物量可使营养物质在陆地和湿地之间形成良性循环 ,不会造成污染物在湿地系统的过度积累

辽宁省土地利用与生态环境协调发展研究

根据保护和改善生态环境的原则,围绕保障土地资源可持续利用的目标,本着"改善、协调、预防和减缓"的思想,为实现土地资源的可持续利用提供科学依据,依据土地资源评价诊断指标、土地类和土地等级的评价标准,确定辽宁土地资源评价因素及其划分指标,采用层次分析法和综合指标法对土地利用生态敏感性定量评价,进行土地利用生态敏感性分区、生态控制分区,提出了辽宁省统筹土地利用与生态环境建设的土地调控指标和建议。

使用GIS区划白河林业局森林经营类型(英文)

使用GIS区划了白河林业局森林经营类型,并和原有的森林经营类型进行了比较。在数字化区划的森林经营类型中,二级系统被采纳。首先,白河林业局被区划为林地和非林地,其中,总面积的96%为林地,然后,林地区划为重点公益林,一般公益林和商品林。在重新区划的森林经营类型中,商品林达到总面积的45.0%,是最主要的森林经营类型:重点公益林和一般公益林分别为总面积的21.2%和29.9%。两个区划结果有很大的不同,在数字化区划的森林经营类型中,各类型斑块数量较多,面积较小,这些不同主要由使用数据,区划单位和区划方法的不同引起的。研究表明,GIS在区划森林经营类型时是一种有效的方法,二类数据和其它类型数据的结合是必要的。图2表4参22。

我国区域发展中的生态环境特征分析

长期以来,区域发展更加关注经济发展效率和生活质量的提高。随着影响区域发展的传统要素作用的下降,以区域生态环境问题为代表的新的影响要素正在扩大影响。区域生态环境问题的区域特征主要表现为特征的区域差异性、要素的区域流动性和区域的空间类型。因此,针对不同的区域应实行不同的区域政策,建立区际之间的生态环境治理与保护合作机制,避免污染要素和污染产业的区际转移。

Selective hydrogenation of nitrobenzene to aniline in dense phase carbon dioxide over Ni/gamma-Al2O3: Significance of molecular interactions

The selective hydrogenation of nitrobenzene (NB) over Ni/gamma-Al2O3 Catalysts Was investigated using different media of dense phase CO2, ethanol, and n-hexane. In dense phase CO2, the total rate of NB hydrogenation was larger than that in organic solvents under similar reaction conditions; the selectivity to the desired product, aniline, was almost 100% over the whole conversion range of 0-100%. The phase behavior of the reactant mixture in/under dense phase CO2 was examined at reaction conditions. In situ high-pressure Fourier transform infrared measurements were made to study the molecular interactions Of CO2 with the following reactant and reaction intermediates: NB, nitrosobenzene (NSB), and N-phenylhydroxylamine (PHA). Dense phase CO2 strongly interacts with NB, NSB, and PHA, modifying the reactivity of each species and contributing to positive effects on the reaction rate and the selectivity to aniline. A possible reaction pathway for the hydrogenation of NB in/under dense phase CO2 over Ni/gamma-Al2O3 is also proposed.

Synthesis, structural and electrical characterizations of Sr2Fe1-xMxNbO6 (M = Zn and Cu) with double perovskite structure

Sr2Fe1-xZnxNbO6-x/2 (0 <= x <= 0.5) and Sr2Fe1-xCuxNbO6-x/2 (0.01 <= x <= 0.05) with the double perovskite structure have been synthesized. The crystal structures at room temperature were determined from Rietveld refinements of X-ray powder diffraction data. The plots of the imaginary parts of the impedance spectrum, Z '', and the electric modulus, M '', versus log (frequency), possess maxima for both curves separated by less than a half decade in frequency with associated capacities of 2 nF. The enhancement of the overall conductivity Of Sr2Fe1-xMxNbO6-x/2 (M = Cu and Zn) is observed, as increases from 2.48 (3) x 10(-4) S/cm for Sr2FeNbO6 to 3.82 (5) x 10(-3) S/cm for Sr2Fe0.8Zn0.2NbO5.9 at 673 K. Sr2Fe0.8Zn0.2NbO5.9 is chemically stable under the oxygen partial pressure from 1 atm to 10(-22) atm at 873 K. The p and n-type electronic conductions are dominant under oxidizing and reducing conditions, respectively, suggesting a small-polaron hopping mechanism of electronic conduction.

Electroactive gold nanoparticles protected by 4-ferrocene thiophenol monolayer

Numerous reports have focused on ferrocene-terminated electroactive self-assembled monolayers (SAMs) on a flat An surface but only a few on ferrocene SAMs on An colloid. In this paper, we employ 4-ferrocene thiophenol as a novel capping agent to produce electroactive gold nanoparticles in consideration of the peculiar pi-conjugated structure. Transmission electron microscopy shows the narrow-dispersed gold core with an average core diameter of ca. 2.5 nm. UV/vis spectra examine the pi-conjugated structure of 4-ferrocene thiophenol and surface plasmon absorbance of the indicated gold nanoparticles. X-ray photoelectron spectroscopy reveals electronic properties of the An core and thiol ligands. Electrochemical measurement shows that the oxidation peak current is proportional to the scan rate, indicating the electrode process is controlled by adsorbed layer reaction. The formal potential of the Fc-MPCs is compared with that of free ferrocene in MeCN solution and the Fc-SAMs. The shifts are attributed to the phenyl moiety in the 4-ferrocene thiophenol and dielectric constant of the solvation environment.