云南哀牢山地区构造岩石地层单元及其构造演化

依据新获得的同位素年代学资料和构造岩石地层单元，重新认识了云南哀牢山造山带形成与演化历史。认为：在哀牢山地区元古界深变质岩系属基底的造层；前造山期岩石组合及构造演化为扬子地块西缘被动大陆边缘志留纪深水相碎屑岩→陆缘泥盆纪被动裂谷盆地中火山－沉积岩→石炭纪哀牢山有限洋盆及蛇绿岩石组合→晚二叠世－早三叠世哀牢山洋－陆碰撞成陆及弧火山岩－陆相碎屑岩组合。燕山期主造山期及岩石级合为晚三叠世－侏罗纪前陆盆地磨拉石建造－同造山期中酸性侵入岩－燕山期脆性剪切带及构造岩，喜马拉雅山期陆内造山成原的岩石组合为第三－第四纪陆内山间盆地中磨拉石建造－红河韧性剪切带及构造岩－富碱侵入岩和煌斑岩。

游离烃技术在沙漠覆盖区构造含油气评价中的应用

简述游离烃技术的方法及其特点,并介绍其在沙漠覆盖区构造含油气性评价中的应用实例。

贵州凉风洞石笋的古气侯记录与古生态环境意义

自20世纪60年代以来，探索全球性气候变化规律和环境变迁史的研究工作在世界各国广泛开展。大规模的深海岩芯的研究、中国北方黄土的系统研究、大型湖泊沉积岩芯的研究及对树木年轮、泥炭、珊瑚、冰芯等“自然环境历史档案”开展的研究工作，都为重建古气候和古生态环境提供了大量的资料。洞穴化学沉积物（石笋）由于其特有的微层结构及其内的稳定氧、碳同位素和微量元素所蕴含的古气候与古生态环境信息，并且具有分布广、时间长、信息保存完整等特点，因此，它是研究地球环境变化很好的自然环境历史档案。本论文通过对凉风洞洞穴体系的综合研究和对凉风洞石笋（微层）生长特征及石笋的碳、氧稳定同位素组成的研究，系统探讨了贵州凉风洞石笋的古气候记录和古生态环境意义，得出以下主要结论：1，地表植被的类型及生物量等信息可综合反映于洞穴体系的不同组．分（气样、土样、水样）中。而洞穴的水动力条件也能很好的被洞穴滴水中所含微量（常量）元素记录。根据分析，洞穴综合体系对外界气候与生态环境的响应关系存在一定规律性。通过对比说明，我们所选的凉风洞基岩的溶蚀和缓冲对水体中的信息影响不大，即洞穴滴水较好的继承了土壤水所携带的地表气候与生态环境信息，是理想的研究对象。2．凉风洞石笋具有多个沉积旋回，不同沉积旋回的纹层组合及纹层结构存在一定的差异，指示不同的沉积环境。根据年龄数据判断，旋回①至旋回⑧之间年龄跨度为1570-8000 aBP，以呈缓平顶（柱）对称叠复状的沉积形态组合为主，示洞顶滴水量较大，滴水点相对稳定，且均匀，与全新世较为稳定的气候与环境变化的主旋律相一致。旋回⑧以下至底部石葡萄状沉积物之上部分之间年龄跨度为8000-14220 aBP，期间经历末次冰期晚期向全新世大暖期过渡，受诸如新仙女木事件（Younger Dryas）等的影响，气候变化幅度大，且经历多次反复，石笋生长的沉积学特征表现为斜锥（柱）、尖顶锥不对称叠复纹层组合，示洞顶滴水水量较小但变化较大，且洞穴滴水不稳（固）定。与此时间段内不稳定的气候与环境变化的主旋律也相一致。3．凉风洞石笋上段微层具有典型南方石笋微层发育的特性：微层发育较差，层面多弯曲，层间界面模糊等。下段因为沉积间断较多、风化层面厚及受到若干时段内碳酸钙重结晶而导致晶体穿插层位生长的影响，尽管在某些层位有微层发育，但无法对石笋微层作连续观察记录。根据高精度的石笋TIMS、ICP-MS测年数据和在显微镜下所数石笋微层数量的对比，扣除若干个沉积间断及风化层导致的微层缺失，以及显微镜下肉眼对细小微层计数的误差，我们认为，凉风洞石笋微层是年生长层的可能性较大。4，由于部分测年数据仍在测试中，目前无法精确控制石笋中沉积间断的存在导致的信息缺失，因此，我们仅仅根据部分石笋测年数据，建立了凉风洞石笋在不同时段的生长速率。全新世以来石笋的生长速率在22μm／yr-51μm／yr之间，明显高于末次冰期晚期向全新世过渡这一时间段内的石笋生长速率（16μm／yr）。这些数据间接印证了石笋生长响应于外界气候，尤其是降雨的变化。5．通过对洞穴体系的综合分析对比，我们判断凉风洞洞穴综合体系相对完整，洞穴化学沉积物的6先值较为直接的响应了土壤c压的61t值变化，即反映了地表的植被（c3植物和c；植物）的组成状况。贵州地区降雨80％集中在5-10月份，在此期间，基本受西南季风和东亚季风所控制。西南季风盛行时贵州各地的降雨频繁，是一年中雨量最集中的时期，在东亚季风影响时期，贵州多晴少雨，往往形成干早的天气。又西南季风控制区大气降雨创的值的加权平均值明显低于东亚季风控制区大气降雨δ18O值的加权平均值。因此，贵州地区年均降雨量和年均降雨δ18O值主要取决于西南（印度洋）季风的强弱：西南季风加强，降雨量增加，年均降雨剐、值偏负；西南季风减弱，降雨量减少，年均降雨δ18O值偏正。洞穴滴水的6旧O值变化基本继承了大气降水的别勿值变化。因此，对地处我国西南地区贵州南部的凉风洞，源于洞穴滴水的凉风洞石笋的别勺值变化直接响应了外界的大气降雨量的变化和西南季风与东亚季风相互的强弱交替。6．对凉风洞石笋碳、氧同位素组成的时间序列曲线作20点移动平均，发现，特别是进入全新世后，石笋的引3c值和扩、值几乎具有完全一致的同步变化，只是在变化幅度上在某些时段存在差异。说明在凉风洞石笋反映的14220-1570 aBP时间段内，尤其是10500-1570 aBP期间，本区域气候具有雨热（或干冷）同期的气候特征：在气温较高时间段，西南季风增强，气候湿润多雨，更有利于地表。植物的生长。气温降低时，随着东亚季风增强，西南季风减弱，气候干旱少雨，地表C；植物的生长占有一定的比例。据此重建和恢复了本地区14220-1570 aBP期间的古气候和古生态环境：（1）．14220-10500aBP，处于末次冰期晚期，气温较低。凉风洞石笋此时段的司、值都大于-9.8‰，最小值为-9.31‰，最大值达-7.290‰，平均值为-8.552‰。说明凉风洞洞穴地表的生长植被。植物占有一定的组分，石笋的δ18C值受C3植物和C4植物的共同影响。此时段内石笋6、值也存在一定的波动（-5.651‰－6.942‰），考虑到末次冰期晚期先全新世过渡期间气温变幅较大，O'Neil等（1969）所建立的氧同位素平衡分馏方程中的温度变化已不能忽略，并且大气降雨的温度效应作用也比较明显，因此我们对此时段的季风和大气降雨量的变化不作讨论。（2）. 10500-9300 aBP，新仙女木事件结束，进入全新世，气温逐渐回升。凉风洞石笋此时段的扩3c值大都小于-9.8‰，最小值为-10.377‰，最大值为-9.267‰，平均值为-9.910‰。凉风洞洞穴地表植被已逐渐由C3植物占主导。此时段石笋δ18C值明显卜降，最小值为-7.420‰，最大值为-6.077‰，平均值为-6.854‰。反映在全新世早期夏季风盛行，降雨量较大，西南季风对本地区全年降雨贡献率大。（3）．9300-8300 aBP，经历一段明显温度波动变化。仟3c值在-9.8‰上下波动，最小值为-10.155‰，最大值为-9.096‰，平均值为-9.712‰。凉风洞洞穴地表植被C4植物所占比例存在反复。此时段石笋岁a0值变化幅度不是很大，最小值为-6.796‰，最大值为-6.260‰，平均值为-6.490‰。受冬季风影响，夏季风有一定的减弱，总体降雨量一般，东亚季风对本地区全年降雨贡献率比全新世初期有所增大。（4）．8300-3l000BP，俗称全新世大暖期，此时段全球气温明显回升，石笋δ18C值总体逐渐降低，最小值为-n．926编，平均值为-10.496‰。凉风洞洞穴地表植被基本由C3植物所控制。但在扩飞值总体逐渐降低的趋势一F，也存在若干扩3c值明显增大时段，如7700-6700 aBP时段，61七值最大值达-8.110‰，地表C4植物所占比例已不能忽略。此时段石笋6150值变化幅度较大，最小值为-7.373‰，最大值为-5.047‰，平均值为-6.261‰。反映在全新世大暖期的大背景下西南季风和东亚季风的交替以及大气降雨量的变化存在较大的波动，说明了季风气候的不稳定性。（5）．3100-1570 aBP，在3100aBP前后，凉风洞石笋的δ18C值和δ18O值均急剧上升，标志进入晚全新世。此时段气温变幅很大，δ18C值总体虽然仍偏低，平均值为-10.275‰，但刻畜介于-6.495-12.097‰之间；δ18C值平均值为-6.184‰，变幅介于-4.677-8.65‰之间，均超过以往任何时段。此时段凉风洞洞穴地表植被基本上仍然由C。植物所控制，始于3100 aBP的急速降温事件使得在全新世晚期开始时段C4植物所占比例有一定的上升。此时段内西南季风和东亚季风反复多次交替，大气降雨量存在较大幅度的变化，说明了季风气候在此时段的很不稳定性。对于169于巧70 oBP百年时间段内石笋的δ18C值和司、值巨大幅度的急剧升高，有待进一步研究，也不排除石笋表层长期裸露受外界污染所致。

Capillary electrophoresis study of human serum albumin binding to basic drugs

The applicability of capillary electrophoresis/frontal analysis (CE/FA) for determining the binding constants of the drugs propranolol (PRO) and verapamil (VER) to human serum albumin (HSA) was investigated. After direct hydrodynamic injection of a drug-HAS mixture solution into a coated capillary (32 cm x 50 mu m i.d.), the basic drug was eluted as a zonal peak with a plateau region under condition of phosphate buffer (pH 7.4; ionic strength 0.17) at 12 kV positive running voltage. The unbound drug concentrations measured from the plateau peak heights had good correlation coefficients, r > 0.999. Employing the Scatchard plot, the Klotz plot and nonlinear regression, the drug protein binding parameters, the binding constant and the number of binding sites on one protein molecule, were obtained. The binding constant obtained was compared to a reported equilibrium dialysis result and they are basically in good agreement.

Low-temperature heat capacity and phase transition of n-hexatriacontane

The heat capacities of crystalline and liquid n-hexatriacontane were measured with an automatic adiabatic calorimeter over the temperature range of 80-370 K. Two solid-to-solid phase transitions at the temperatures of 345.397 and 346.836 K, and a fusion at the temperature of 348.959 K have been observed. The enthalpies and entropies of these phase transitions as well as the chemical purity of the substance were determined on the basis of the heat capacity measurements. Thermal decomposition temperatures of the compound were measured by thermogravimetric analysis. (C) 1999 Elsevier Science B.V. All rights reserved.

军队医学科技人员身心健康与影响因素的研究

To study the relationship between mental-physical health and coping behavior,job stress and job motivation in medical laboratory scientists and technicians. A cross-section survey was conducted,using the anxiety rating scale(SAS), depression rating scale(SDS), coping behavior rating scale,self-rating subhealth scale,self-rating stress scale,and self-rating job motivation scale among 289 medical laboratory scientists and technicians with analysis of ANOVA and Regression. The study was carried out in three steps:step1 is to analyze the general situation of the mental-physical health.Step 2 is to analyze the features of the main influencial facotors.Step 3 is to study the influence of the relative factors on mental-physical health.The following are the results: 1.The anxiety and depression scores of the medical researchers and technicians were 30±6 and 37±8 respectively,both significantly lower than those of the national norm（34±6 and 42±11 respectively,both P<0.01）,which are of significant difference. The depression score of the associate chief technician was 42±7, significantly higher than those of the medical researchers and technicians with any other professional titles (all P<0.05）, and the anxiety score of the associate chief technicians was 32±7, significantly higher than that of the research fellows（28±4, P<0.05），with no significant difference to the score of the medical researchers and technicians with other professional titles. The depression score,anxiety score and the subhealth score of the age group of 36～49 were 39±9,31±7 and 32±9 respectively, both higher than that of the age group of 20～35 （36±8,29±6 and 29±7 respectively,both P<0.05）,while there is much diference among other age groups. And the subhealth status has nothing to do with marital status,education background and professional titles. 2.The coping behaviors,job stress and motivation of the military medical laboratory scientists and technicians. 1）Coping behaviors:The seeking help score of the associate chief technicians was 2.8±0.5,not significantly different from that of the associate research fellows（2.8±0.5）,but significantly lower than those of the medical researchers and technicians with other professional titles(all P<0.01),and whose self-blame score was higher than that of the research fellows,which is of significant difference.The self-blame score and the imagination score of the associate research fellows were 2.0±0.5 and 2.4±0.5 respectively, significantly higher than that of the research fellows(1.6±0.4, 2.1±0.4,both P<0.01). The seeking help score of the females was 3.1±0.5, significantly higher than that of the males(2.9±0.5, both P<0.01),and the solving problem score was 3.4±0.6,significantly lower than the male(3.6±0.7, both P<0.01).There is no any significant difference in coping behaviors among researchers and technicians of different marital status,education background and age groups. 2)Job stress: The score of job stress of the age group of 35~49 and 50~60 were 23±8 and 25±6 respectively,significantly higher than that of the 20~35(21±7,both P<0.05). There is no any significant difference in job stress among researchers and technicians of different marital status,gender,professional titles and education background. 3)The score of meeting personal desire for reputation and interests of the males was 19.6±5.4，significantly higher than that of the females(18.4±5.0, both P<0.05), while there is no significant difference in job motivation among researchers and technicians of different titles,education,age and marital status. 3.The relationship of the mental-physical health of the military medical laboratory scientists and technicians with their coping behaviors,job stress and motivations 1) Coping behaviors:Regression analysis showed that, the best predictors of subhealth were anxiety,depression and escaping (β=-0.40,β=0.23, β=0.14, both P<0.01).the best predictors of anxiety and depression were active coping behaviors and negative coping behaviors (β=-0.40,β=0.40, both P<0.01).The moderate(rational) coping behaviors is the best predictor only of anxiety and of significant difference. 2)job stress : Regression analysis demonstrated that anxiety,depression,job stress 2 and job stress 4 are the best predictor for subhealth;job stress 12 is the best retro-predictor for depression; job stress 3 and 8 are the best predictor for depression;and job stress 2 and 9 are the best predictor for anxiety ,which are of significant difference. 3)Motivation:Regression analysis demonstrated that depression is the best predictor for subhealth while motivation itself doesn't predict subhealth;with respect to the specific contents of motivation,"probing unknown rules and making contributions to the human society "is the best retro-predictor for depression and has nothing to do with anxiety prediction. 4) The combined influences of coping behaviors,job stress and motivations: Regression analysis showed that, the best predictors for subhealth were anxiety,depression and job stress(β=0.41,β=0.24, β=0.19, both P<0.01).the best predictors for anxiety and depression were active coping behaviors and negative coping behaviors (β=-0.40,β=0.40, both P<0.01).The moderate(rational) coping behaviors is the best predictor only for anxiety and of significant difference. CONCLUSIONS: Regression analysis showed that the best predictors for anxiety and depression were active coping behaviors and negative coping behaviors, the best predictors for subhealth were anxiety,depression and job stress.Coping behaviors, job stress and motivations have significant influences on the mental-physical health of the military medical researchers and and technicians. Among them,coping behavior is the most important factor while job stress and motivation follow. Seeking help more often,less self-blame ,imagination and job stress could help release the anxiety, depression and improve the subhealth of the medical researchers and technicians. The findings of this study indicate we should address the physical and mental health of the military laboratory researchers and technicians.

High-throughput screening of HZSM-5 supported metal-oxides catalysts for the coupling of methane with CO to benzene and naphthalene

High-throughput screening of HZSM-5 supported metal-oxides catalysts were carried out for the coupling reaction of methane with CO to aromatics in a multi-stream reactor system. Zn/HZSM-5 and Mo/HZSM-5 were observed to be rather effective for the catalytic formation of aromatics from the coupling reaction of methane with CO. Temperature-programmed reaction has further proven the efficiency of the coupling of methane and CO over Zn/HZSM-5 catalyst. The results were also validated in a conventional fixed-bed reactor coupled with GC. The results propose that the coupling methane with CO toward benzene and naphthalene can be catalyzed by Zn/HZSM-5 at 500 &DEG; C. Both methane and CO are needed for the formation of reactive coke on the catalyst, and the reactive coke may be the initial product in the producing of hydrocarbons. © 2005 Elsevier B.V. All rights reserved.