163 resultados para 1,10-Phenanthroline


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La0.8Sr0.2Mn1.1O3 (LSM1.1)-10 mol% Sc2O3-Stabilized ZrO2 co-doped with CeO2 (ScSZ) composite cathodes were investigated for anode-supported solid oxide fuel cells (SOFCs) with thin 8 mol% Y2O3-stabilized ZrO2 (YSZ) electrolyte. X-ray diffraction (XRD) results indicated that the ScSZ electrolytes displayed good chemical compatibility with the nonstoichiometric LSM1.1 against co-firing at 1300 degrees C. Increasing the CeO2 content in the ScSZ electrolytes dramatically suppressed the electrode polarization resistance, which may be related to the improved surface oxygen exchange or the enlarged active area of cathode. The 5Ce10ScZr was the best electrolyte for the composite cathodes, which caused a small ohmic resistance decrease and the reduced polarization resistance and brought about the highest cell performance. The cell performances at lower temperatures seemed to rely on the electrode polarization resistance more seriously, than the ohmic resistance. Compared with the cell impedance at higher temperatures, the higher the 5Ce10ScZr proportion in the composite cathodes, the smaller the increment of the charge transfer resistance at lower temperatures. The anode-supported SOFC with the LSM1.1-5Ce10ScZr (60:40) composite cathode achieved the maximum power densities of 0.82 W/cm(2) at 650 degrees C and 2.24 W/cm(2) at 800 degrees C, respectively. (c) 2005 Elsevier B.V. All rights reserved.

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利用表面机械研磨处理(SMAT)技术在Zr片状拉伸样品表面施加剧烈变形,获得超细/纳米晶粒组织的变形细化表层,其中Zr板厚度1 mm,两侧变形层厚度均为100μm.拉伸实验结果表明,表层细化组织提高了屈服强度和抗拉强度,使加工硬化能力及伸长率下降.应变速率在10~(-4)~10~(-3)s~(-1)范围时,拉伸强度随应变速率的提高而提高;应变速率增大至10~(-2)s~(-1)量级时,抗拉强度下降.扫描电镜观察显示出韧性韧窝状断裂特征.

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A simple two-dimensional square cavity model is used to study shock attenuating effects of dust suspension in air. The GRP scheme for compressible flows was extended to simulate the fluid dynamics of dilute dust suspensions, employing the conventional two-phase approximation. A planar shock of constant intensity propagated in pure air over Aat ground and diffracted into a square cavity filled with a dusty quiescent suspension. Shock intensities were M-s = 1.30 and M-s = 2.032, dust loading ratios were alpha = 1 and alpha = 5, and particle diameters were d = 1, 10 and 50 mum. It was found that the diffraction patterns in the cavity were decisively attenuated by the dust suspension, particularly for the higher loading ratio. The particle size has a pronounced effect on the flow and wave pattern developed inside the cavity. Wall pressure historics were recorded for each of the three cavity walls, showing a clear attenuating effect of the dust suspension.

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从系统构成和通信软件两方面介绍了一种基于RS-485网络的集散型控制系统。该系统的RS-485网络由1台工控机和10台可编程控制器构成。工控机通过RS-485网络控制10台独立的3自由度数控液压小车。本文提出了一种RS-485网络通信协议。

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用微型电探针技术和φ800mm高温激波管中电子密度的标定技术相结合,获得了高温高速气 流中低电子密度的一种测量方法,可用于n_e≈1*10~9个/cm~3条件下电子密度的测量。该法有较好的空间分辨能力,且其探测灵敏度比常规的8mm微波干涉仪提高了两个数量级。

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本文在探讨工程爆破物理过程的基础上,分析了在何种条件下几何相似律与能量准则成立的条件。对硐室爆破、深孔爆破及水下爆破都分别作出了相应的爆破模型律,并给出了在实验室内做模型试验时选择模型材料的方法。

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本文对强激光造成靶材破坏机理进行了评述,将激光破坏机理在I-r平面内分为冲击破坏、热烧蚀破坏和非熔化条件下的热应力破坏三个区域,并分别对各区激光-靶材相互作用过程及破坏方式进行了评述,给出了国内外的最新研究成果及研究展望。

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本文从连续介质假设、守恒方程、本构关系和固壁上的边界条件等方面的分析出发,指出二相流体动力学虽是流体力学的一个分支,但在研究内容上与流体力学有较大差异,从分析二相流特点与稀薄气体、稠密气体、非平衡流动和可压缩流动特点之间的相似性出发,指出二相流研究可借鉴相关学科的研究成果和研究方法。本文用弛豫时间概念解释了二相混合物与均相混合物在运动特征上的差异,以及在描写运动的方法上(双流体模型和单流体模型等)的相应差异。最后以风沙运动、泥沙运动和泥石流运动为例,说明在二相流研究中突出主要因素进行合理简化的重要性,并指出:对于不同类型的二相流、对于具有不同流动参数的同类二相流、对于同一二相流的不同区域或不同的研究目的,简化的方法都会有所不同。

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谐波增量平衡法在描述非线性力时计及多谐分量,是处理强非线性的一个有效方法.在本文中,此法被推广于分析局部非线性结构的稳态响应.被分析的结构分解为若干子结构,所有非线性元件均位于子结构的分界面上.系统的响应用谐波增量平衡法(Incremental Harmonic Balance Method,简称I.H.B法)结合F.F.T.(快速福里哀变换)技术与状态空间的模态综合法分析之.

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本文简要说明现代力学的由来,提出现代力学学科发展的纲目划分的设想,扼要评述现代力学学科中作为纲的学科的现况和发展。在此基础上提出现代力学的特点、发展动力和对力学工作者的要求。

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本文报道了在不同温度和不同应变率下天然淡水冰单轴压缩强度的实验结果。指出S—l型柱状晶粒冰的压缩强度随着温度的降低而增加,极限压缩强度在应变率为10~(-4)S(-1)时有一个最大值。本实验的应变率范围是10~(-5)—10~0s~(-1)。10~(-1)—10~0s~(-1)的应变率范围是在冲击速度lm/s左右的实验条件下获得的,这个速度接近于浮冰与海上结构物相撞的情况。以本实验为基础,有希望发展对海冰的实验技术。

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本文采用涡量-向量势表示的不可压缩三维流动的基本方程及其边界条件。针对小曲率弯管流,忽略主流方向的扩散项而使基本方程抛物化并利用流量守恒条件确定轴向压力分布。为避免横向速度向量散度不为零所带来的麻烦,本文提出两种计算方案。计算结果证明:用于求解三维抛物化方程组的这两种方案都是方便可行的。