Synergistic extraction of rare earths by mixture of bis(2,4,4-trimethylpentyl)phosphinic acid and Sec-nonylphenoxy acetic acid

Synergistic extraction of trivalent rare earths (RE=Sc, Y, La, Gd, Yb) from hydrochloride medium using mixture of bis(2,4,4-trimethylpentyl)phosphinic acid (HL, Cyanex272) and Sec-nonylphenoxy acetic acid (HA, CA-100) in n-heptane has been studied. The synergistic enhancement coefficients were observed for La (1.30), Gd (1.97), Y (3.59), Yb (8.21) and Sc (14.41). The results indicated yttrium was extracted into n-heptane as YH(5)A(4)L(4) mixed species instead of Y(HL2)(3), Y(OH)(2)A(HA)(3) which were extracted by Cyanex272 and CA-100, respectively. A cation exchange mechanism was proposed and further clarified by IR spectra. The equilibrium constants, formation constants and thermodynamic functions such as Delta G, Delta H and Delta S were determined. The Cyanex272 + CA-100 system not only enhanced the extraction efficiency of RE but also improved the selectivities significantly. The mutual separation factors of these ions suggested the mixture system would be of practical value in extraction and separation of rare earths.

Interfacial activity of sec-nonylphenoxy acetic acid and kinetics of yttrium extraction

The interfacial behavior of sec-nonylphenoxy acetic acid (CA-100) at various diluents/(H, Na)Cl interfaces was examined using the Du Nouy ring method. Different adsorption isotherms such as the Gibbs and Szyszkowski were in good agreement with the experimental data. The values of interfacial excess at saturated interface increase in the following order: n-heptane > kerosene > cyclohexane > CCl4 > toluene > benzene > chloroform. The effects of temperature, acidity, and ionic strength of the aqueous phase on the interfacial activity of CA- 100 were also examined. The interfacial-activity data were used to discuss the mechanism and kinetics of yttrium (Y) extraction.

20～21���纪的力学

<正> 一、力学发展的趋势 1.20世纪力学的巨大成就 本世纪初边界层理论的提出,对力学的发展起了划时代的作用。从此,流体力学能够成功地解释流动对物体的阻力与升力,为航空、航天的发展奠定了科学基础。这个典型也影响与推动了其他力学分支的发展,使力学研究的内涵有了空前的充实、扩大与深化。早在20年代初便形成了活跃于整个20世纪内容广泛的应用力学,成为工程与应用科学的支柱。人们把空气动力学的研究看作是本世纪以科学为基础将航

21���纪初的力学发展趋势

回顾力学发展史，阐明在科技发展过程中力学对于认识自然规律和解决工程技术问题中的地位和作用；提出在固体力学、流体力学、一般力学以及有关力学的若干交叉学科领域中的一些重要研究课题；展望２１世纪（特别是２１世纪前期）的力学发展趋势．

21���纪初的力学发展趋势

回顾力学发展史，阐明在科技发展过程中力学对于认识自然规律和解决工程技术问题中的地位和作用；提出在固体力学、流体力学、一般力学以及有关力学的若干交叉学科领域中的一些重要研究课题；展望２１世纪（特别是２１世纪前期）的力学发展趋势。

21���纪初的力学发展趋势

回顾力学发展史,阐明在科技发展过程中力学对于认识自然规律和解决工程技术问题中的地位和作用,提出在固体力学、流体力学、一般力学以及有关力学的若干交叉学科领域中的一些重要研究课题;展望21���纪(特别是21���纪前期)的力学发展趋势。

血栓形成研究的进展及对21���纪的展望

扼要地介绍了自1976年以来,在血栓形成研究中的进展及其对21���纪的展望。

21���纪初的力学发展趋势

<正>力学是力与运动的科学,它研究的对象主要是物质的宏观机械运动,它既是基础科学,又是众多应用科学,特别是工程技术的基础。它过去建立在牛顿定律和经典热力学的基础上,现在则扩大到量子力学描述的微观层次。力学和天文学、微积分学几乎同时诞生,曾在经典物理的发展中起关键作用。20世纪力学在推动地球科学,如大气物理、海洋科学等的定量化方面,作出了重大贡献。近年来还在材料科学、生物学、医学等科学分支中起着越来越重要的作用。

力学: 迎接21���纪新的挑战

A novel fusion gene, TRIMS-Cyclophilin A in the pig-tailed macaque determines its susceptibility to HIV-1 infection

Objective: In Old World monkeys, the tripartite motif Sec (TRIM5 alpha) protein confers resistance to HIV-1 infection following virus entry into host cells. However, the pig-tailed macaque (Macaca nemestrina) is an exception and is susceptible to HIV-1 in

Crossmodal effects of Guqin and piano music on selective attention: An event-related potential study (vol 466, pg 21, 2009)

Special thanks to Christopher Blair and Mumtaz Baig for their suggestions. This work was supported by National Basic Research Program of China (973 Program, 2007CB411600), National Natural Science Foundation of China (30621092), and Bureau of Science and Technology of Yunnan Province.

白鱀豚人工饲养21���

<正> 世界鲸类动物的人工饲养已经有100多年的历史,鲸类动物的人工饲养不但为人们提供了一种非常有趣的娱乐项目,而且为深入研究、繁殖和保护鲸类动物提供了很好的条件。我国鲸类动物的人工饲养于1965年由青岛海产博物馆从饲养江豚开始