Pipeline uplift response in thawed sandy backfills: Preliminary findings

Offshore and onshore buried pipelines under high operating temperature and pressures may lead to upheaval buckling (UHB) if sufficient soil cover is not present to prevent the upward movement of the pipeline. In regions where seasonal changes involve ground soil undergoing freezing-thawing cycles, the uplift resistance from soil cover may be minimum when the soil is undergoing thawing. This paper presents the results from 2 directly-comparable minidrum centrifuge tests conducted at the Schofield Centre, University of Cambridge, to investigate the difference in uplift resistance responses between fully-saturated and thawed sandy backfill conditions. Both tests were conducted drained at 30g using an 8.6 mm diameter aluminium model pipe, corresponding to a prototype pipe diameter of 258 mm. The soil cover/pipe diameter ratio, H/D, was kept at 1. Fraction E fine silica sand was used as the backfill. Preliminary experimental results indicated that the ultimate uplift resistance of a thawing sand backfill to be lower than that of a fully saturated sand backfill. This suggests that in regions where backfill soil undergoes freeze-thaw cycles, the thawing backfill may be more critical than fully saturated backfill for uplift resistance. The 2-dimensional displacement field during the experiment was accurately measured and analysed using the Particle Image Velocimetry technique. Copyright © 2011 by the International Society of Offshore and Polar Engineers (ISOPE).

A detailed chemistry multi-cycle simulation of a gasoline fueled HCCI engine operated with NVO

A previously developed Stochastic Reactor Model (SRM) is used to simulate combustion in a four cylinder in-line four-stroke naturally aspirated direct injection Spark Ignition (SI) engine modified to run in Homogeneous Charge Compression Ignition (HCCI) mode with a Negative Valve Overlap (NVO). A portion of the fuel is injected during NVO to increase the cylinder temperature and enable HCCI combustion at a compression ratio of 12:1. The model is coupled with GT-Power, a one-dimensional engine simulation tool used for the open valve portion of the engine cycle. The SRM is used to model in-cylinder mixing, heat transfer and chemistry during the NVO and main combustion. Direct injection is simulated during NVO in order to predict heat release and internal Exhaust Gas Recycle (EGR) composition and mass. The NOx emissions and simulated pressure profiles match experimental data well, including the cyclic fluctuations. The model predicts combustion characteristics at different fuel split ratios and injection timings. The effect of fuel reforming on ignition timing is investigated along with the causes of cycle to cycle variations and unstable operation. A detailed flux analysis during NVO unearths interesting results regarding the effect of NOx on ignition timing compared with its effect during the main combustion. © 2009 SAE International.

The production of separate streams of pure hydrogen and carbon dioxide from coal via an iron-oxide redox cycle

A chemical looping process using the redox reactions of iron oxide has been used to produce separate streams of pure H2 and CO2 from a solid fuel. An iron oxide carrier prepared using a mechanical mixing technique and comprised of 100wt.% Fe2O3 was used. It was demonstrated that hydrogen can be produced from three representative coals - a Russian bituminous, a German lignite and a UK sub-bituminous coal. Depending on the fuel, pure H2 with [CO] ≲50vol.ppm can be obtained from the proposed process. The cyclic stability of the iron oxide carrier was not adversely affected by contaminants found in syngas which are gaseous above 273K. Stable quantities of H2 were produced over five cycles for all three coals investigated. Independent of the fuel, SO2 was not formed during the oxidation with steam, i.e. the produced H2 was not contaminated with SO2. Since oxidation with air removes contaminants and generates useful heat and pure N2 for purging, it should be included in the operating cycle. Overall, it was demonstrated that the proposed process may be an attractive approach to upgrade crude syngas produced by the gasification of low-rank coals to pure H2, representing a substantial increase in calorific value, whilst simultaneous capturing CO2, a greenhouse gas. © 2010 Elsevier B.V.