Polysiloxane surfactants for the dispersion of carbon nanotubes in nonpolar organic solvents.

We develop two new amphiphilic molecules that are shown to act as efficient surfactants for carbon nanotubes in nonpolar organic solvents. The active conjugated groups, which are highly attracted to the graphene nanotube surface, are based on pyrene and porphyrin. We show that relatively short (C18) carbon tails are insufficient to provide stabilization. As our ultimate aim is to disperse and stabilize nanotubes in siloxane matrix (polymer and cross-linked elastomer), both surfactant molecules were made with long siloxane tails to facilitate solubility and steric stabilization. We show that the pyrene-siloxane surfactant is very effective in dispersing multiwall nanotubes, while the porphyrin-siloxane makes single-wall nanotubes soluble, both in petroleum ether and in siloxane matrix.

The influence of water-miscible solvents on the permeability of clay

Centrifuge tests were carried out to determine the effect of 5 different water-soluble chemicals on a thin consolidated disc of clay. The evolution of changes in the clay permeability with time was investigated and other structural changes due to chemical attack were monitored. The findings presented here demonstrate that the permeability of the clay appear to be generally related to the polarity of the chemicals and the dielectric constant, with the exception of Butanol. In the case of Butanol at low flow rate and low stress level, the action of the chemical caused the clay to crack, with a consequent large increase in flow.

Force ripple compensation in a tubular linear generator for marine renewable generation

Tubular permanent magnet linear generators are a promising generator technology for use in marine renewables. One aspect of their design relates to the conditions necessary for achieving a smooth thrust response from the generator, free from cogging and periodic variations due to spatial harmonics of the flux cutting the generator coils. This paper presents an experimental and finite element study of the sources of thrust ripple in a prototype linear generator for marine generation. A simple self-commutated control scheme is shown, which uses linear Hall-effect sensors and look-up-table based feed-forward compensation to derive the excitation currents required to drive the machine with constant force. Details of the controller's FPGA based implementation are given, including its strategy for detecting sensor failure. © 2011 IEEE.

The role for low carbon electrification technologies in poverty reduction and climate change strategies: A focus on renewable energy mini-grids with case studies in Nepal, Peru and Kenya

As a potential poverty reduction and climate change strategy, this paper considers the advantages and disadvantages of using renewable energy technologies for rural electrification in developing countries. Although each case must be considered independently, given a reliable fuel source, renewable energy mini-grids powered by biomass gasifiers or micro-hydro plants appear to be the favoured option due to their lower levelised costs, provision of AC power, potential to provide a 24. h service and ability to host larger capacity systems that can power a wide range of electricity uses. Sustainability indicators are applied to three case studies in order to explore the extent to which sustainable welfare benefits can be created by renewable energy mini-grids. Policy work should focus on raising awareness about renewable energy mini-grids, improving institutional, technical and regulatory frameworks and developing innovative financing mechanisms to encourage private sector investments. Establishing joint technology and community engagement training centres should also be encouraged. © 2011 Elsevier Ltd.

Thermal modelling of a tubular linear machine for marine renewable generation

A lumped parameter thermal model has been constructed for a tubular linear machine that has been designed for use in a marine environment. It shows good correlation to both steady state and transient experimental tests on the machine. The model has been developed for a stationary machine in a laboratory environment - the modelling techniques used and enhancements to enable the application of the model directly to marine scenarios are discussed.

Detailed thermal modelling of a tubular linear machine for marine renewable generation

A detailed lumped-parameter thermal model is presented for a tubular linear machine that has been designed for use in a marine environment. The model has been developed for a static machine, the worst-case thermal scenario, and is used to establish a rating for the machine. The model has been validated against a large range of experimental tests and shows good correlation to both steady-state and transient experimental results. The model was constructed from a mostly theoretical basis with very little calibration, suggesting that the techniques used are applicable in a more general sense. © 2013 IEEE.

Sensorless commutation of a two-phase linear machine for marine renewable power generation

A sensorless scheme is presented for a two-phase permanent-magnet linear machine targeted for use in marine wave-power generation. This is a field where system reliability is a key concern. The scheme is able to extract the effective inductance and back-emf of the machine's phases simultaneously from measurements of the current ripple present on the power electronic converter. These measurements can then be used to estimate position. An enhancement to the scheme in the presence of spatially-varying mutual inductance between phases allows more accurate and reliable tracking from indutance-based measurements than would otherwise be expected. This scheme is able to operate at any speed including, critically, when stationary. Experimental results show promise for the scheme, although some work to reduce the level of noise would be desirable. © 2013 IEEE.