Graphite intercalation compounds under pressure

Motivated by recent experimental work, we use first-principles density functional theory methods to conduct an extensive search for low enthalpy structures of C$_6$Ca under pressure. As well as a range of buckled structures, which are energetically competitive over an intermediate range of pressures, we show that the high pressure system ($\gtrsim 18$ GPa) is unstable towards the formation of a novel class of layered structures, with the most stable compound involving carbon sheets containing five- and eight-membered rings. As well as discussing the energetics of the different classes of low enthalpy structures, we comment on the electronic structure of the high pressure compound and its implications for superconductivity.

MEAN FLOW EFFECTS OF THE LOW-WAVENUMBER PRESSURE SPECTRUM ON A FLEXIBLE SURFACE.

The Lighthill theory is extended so that it may be used to determine the flow noise induced by a turbulent boundary layer over a plane homogeneous flexible surface. The influence of the surface properties and the mean flow on the sound generation is brought out explicitly through the use of a Green function. The form of the low-wavenumber wall-pressure spectrum on a rigid surface with an arbitrary mean flow profile is determined. The effect of a coating layer is investigated.

The effects of a trip wire and unsteadiness on a high speed highly loaded low-pressure turbine blade

This paper presents the effect of a single spanwise 2D wire upon the downstream position of boundary layer transition under steady and unsteady inflow conditions. The study is carried out on a high turning, high-speed, low pressure turbine (LPT) profile designed to take account of the unsteady flow conditions. The experiments were carried out in a transonic cascade wind tunnel to which a rotating bar system had been added. The range of Reynolds and Mach numbers studied includes realistic LPT engine conditions and extends up to the transonic regime. Losses are measured to quantify the influence of the roughness with and without wake passing. Time resolved measurements such as hot wire boundary layer surveys and surface unsteady pressure are used to explain the state of the boundary layer. The results suggest that the effect of roughness on boundary layer transition is a stability governed phenomena, even at high Mach numbers. The combination of the effect of the roughness elements with the inviscid Kelvin-Helmholtz instability responsible for the rolling up of the separated shear layer (Stieger [1]) is also examined. Wake traverses using pneumatic probes downstream of the cascade reveal that the use of roughness elements reduces the profile losses up to exit Mach numbers of 0.8. This occurs with both steady and unsteady inflow conditions.

Effects of silicon addition on the electrical and magnetic properties of copper-doped (La,Ca)MnO3 compounds

In this paper we report about the electrical properties of La 0.7Ca0.3MnO3 compounds substituted by copper on the manganese site and/or deliberately contaminated by SiO2 in the reactant mixture. Several phenomena have been observed and discussed. SiO2 addition leads to the formation of an apatite-like secondary phase that affects the electrical conduction through the percolation of the charge carriers. On the other hand, depending on the relative amounts of copper and silicon, the temperature dependence of the electrical resistivity can be noticeably modified: our results enable us to compare the effects of crystallographic vacancies on the A and B sites of the perovskite with the influence of the copper ions substituted on the manganese site. The most original result occurs for the compounds with a small ratio Si/Cu, which display double-peaked resistivity vs. temperature curves. © 2003 Elsevier B.V. All rights reserved.

Non-equilibirum condensation effects on the flow field and the performance of a low pressure steam turbine

The influence of non-equilibrium condensation on the flow field and performance of a three stage low pressure model steam turbine is examined using modern three dimensional CFD techniques. An equilibrium steam model and a non-equilibrium steam model, which accounts for both subcooling and condensation effects, are used, and have been verified by comparison with test data in an earlier publication [1]. The differences in the calculated flow field and turbine performance with these models show that the latent heat released during condensation influences both the thermodynamic and the aerodynamic performance of the turbine, leading to a change in inlet flow angles of about 5°. The calculated three dimensional flowfield is used to investigate the magnitude and distribution of the additional thermo-dynamic wetness loss arising from steam condensation under non-equilibrium flow conditions. Three simple methods are described to calculate this, and all show that this amounts to around 6.5% of the total losses at the design condition. At other load conditions the wetness losses change in magnitude and axial distribution in the turbine. © 2010 by ASME.