Innovative fabrication of PZT pillar arrays by a colloidal approach

An innovative approach for fabricating pillar arrays for ultrasonic transducer applications is disclosed. It involves the preparation of concentrated piezoelectric lead zirconate titanate (PZT) suspensions in aqueous solutions of epoxy resin and its polymerization upon adding a polyamine based hardener. Zeta potential and rheological measurements revealed that 1wt.% dispersant, 20wt.% of epoxy resin and a hardener/epoxy resin ratio of 0.275mLg -1, were the optimized contents to obtain strong PZT samples with high green strength (35.21±0.39MPa). Excellent ellipsoidal and semi-circle shaped pillar arrays presenting lateral dimensions lower than 10μm and 100μm height were successfully achieved. The organics burning off was conducted at 500°C for 2h at a heating rate of 1°Cmin -1. Sintering was then carried out in the same heating cycle at 1200°C for 1h. The microstructures of the green and sintered ceramics were homogeneous and no large defects could be detected. © 2011 Elsevier Ltd.

The use of centrifuge tests in the study of arching

The horizontal arching mechanism transfers horizontal earth pressures acting on flexible retaining wall panels to stiffer neighbouring elements via soil shear stresses. In this research, the horizontal arching mechanism and lateral displacements of fixed cantilever walls in a model basement are investigated using centrifuge tests. A series of six tests was carried out at 45 gravities where the panel widths and thicknesses around the model basement were varied, so that the effects of panel geometry and stiffness on horizontal arching could be studied. It is shown that panel crest displacements and base bending moments of the most flexible, narrow panels can be an order of magnitude smaller than conventional active earth pressure calculations would allow. It is suggested that the reduction of earth pressure acting on a panel is directly correlated to the mobilized soil shear strength and hence, soil shear strain. Earth pressure coefficients K are plotted against panel displacements normalized by the panel width, u/B, to simulate the reduction of K with increasing soil strain.An idealized K-u/B curve is introduced, characterised by a reference distortion (u/B) ref beyond which fully plastic soil arching can be inferred, and which is related to the corresponding reference shear strain γ ref at which soil strength is fully mobilized in element tests. © 2006 Taylor & Francis Group, London.

Scalar gradient behaviour in MILD combustion

The results of three-dimensional Direct Numerical Simulation (DNS) of Moderate, Intense Low-oxygen Dilution (MILD) and conventional premixed turbulent combustion conducted using a skeletal mechanism including the effects of non-unity Lewis numbers and temperature dependent transport properties are analysed to investigate combustion characteristics using scalar gradient information. The DNS data is also used to synthesise laser induced fluorescence (LIF) signals of OH, CH2O, and CHO. These signals are analysed to verify if they can be used to study turbulent MILD combustion and it has been observed that at least two (OH and CH2O) LIF signals are required since the OH increase across the reaction zone is smaller in MILD combustion compared to premixed combustion. The scalar gradient PDFs conditioned on the reaction rate obtained from the DNS data and synthesised LIF signals suggests a strong gradient in the direction normal to the MILD reaction zone with moderate reaction rate implying flamelet combustion. However, the PDF of the normal gradient is as broad as for the tangential gradient when the reaction rate is high. This suggests a non-flamelet behaviour, which is due to interaction of reaction zones. The analysis of the conditional PDFs for the premixed case confirms the expected behaviour of scalar gradient in flamelet combustion. It has been shown that the LIF signals synthesised using 2D slices of DNS data also provide very similar insights. These results demonstrate that the so-called flameless combustion is not an idealised homogeneous reactive mixture but has common features of conventional combustion while containing distinctive characteristics. © 2013 The Combustion Institute.