MgO expansive cement and concrete in China: Past, present and future

Uniquely, China employs MgO already contained in cement clinker or as an expansive additive to compensate for the thermal shrinkage of mass concrete, particularly dam concrete, with almost 40 years' experience in both research activities and industrial applications. Compensating shrinkage with expansion produced by MgO has been proved to effectively prevent thermal cracking of mass concrete, and reduce the cost of temperature control measures and speed up the construction process. Moreover, the expansion properties of MgO could be designed flexibly, through adjusting its microstructure by changing the calcination conditions (calcining temperature and residence time). The collective knowledge and experience of MgO expansive cement and concrete is worthy of sharing with relevant engineers and researchers globally but dissemination has been hindered as most of the relevant literature is published in Chinese. This paper reviews the history, state-of-the-art progress and future research needs in the field of MgO expansive cement and concrete. © 2013 Elsevier Ltd.

Enhancing the carbonation of MgO cement porous blocks through improved curing conditions

The use of reactive magnesia (MgO) as the binder in porous blocks demonstrated significant advantages due to its low production temperatures and ability to carbonate, leading to significant strengths. This paper investigates the enhancement of the carbonation process through different curing conditions: water to cement ratio (0.6-0.9), CO2 concentration (5-20%), curing duration (1-7 days), relative humidity (55-98%), and wet/dry cycling frequency (every 0-3 days), improving the carbonation potential through increased amounts of CO2 absorbed and enhanced mechanical performance. UCS results were supported with SEM, XRD, and HCl acid digestion analyses. The results show that CO2 concentrations as low as 5% can produce the required strengths after only 1 day. Drier mixes perform better in shorter curing durations, whereas larger w/c ratios are needed for continuous carbonation. Mixes subjected to 78% RH outperformed all the others, also highlighting the benefits of incorporating wet/dry cycling to induce carbonation. © 2014 Elsevier Ltd.

Strength correlations of cement-mixed soils using data mapping

Development of comparisons and correlations between the unconfined compressive strength (UCS) and the undrained triaxial compressive strength, qu, is essential for generalising performance and optimising the design of cement-stabilised soils. This paper introduces current work in collecting and collating data from a number of research projects involving both laboratory strength tests performed on identical cement-stabilised soil samples. The research project on cement-stabilised Singapore marine clays at the National University of Singapore has been used as an example to explain the work on comparing and correlating results from both tests by normalising data and constructing contour plots. The effect of variables on strength comparison and correlations was evaluated. The variation in strength correlations was found to be dependent on a number of factors including: soil properties, cement content, curing time and stress, total water/cement ratio, confining stress and strain rate. The results showed that at ~ 100 kPa confining stress, UCS and qu, had similar magnitudes. Correlations between strengths and other design variables are discussed and presented.