Effect of deposition conditions on the chemical bonding in sputtered carbon nitride films

A balanced planar r.f. powered magnetron sputter source has been used to deposit carbon nitride films from a graphite target under various conditions. Sample temperature, bias voltage and nitrogen content in the gas mixture were varied. The effects of oxygen, methane and ammonia on the film growth were also studied. Special attention was paid to the effects of the deposition parameters on the structure of the films, in particular the hybridisation of the carbon and nitrogen bonding. The chemical bonding of the carbon and nitrogen atoms was studied by electron energy loss spectroscopy (EELS). The chemical composition was evaluated by Rutherford back-scattering. The intensity of transitions to π antibonding orbitals, as revealed by EELS, was found to increase with the nitrogen content in the films. Ion bombardment of the films during growth and the addition of oxygen or hydrogen-rich gases further increased the proportion of π bonds of both the carbon and nitrogen atoms. It is suggested that the increase in the transitions to μ antibond orbitals is to be explained by increased sp2 or possibly sp hybridisation of the carbon and nitrogen. Also, the effect of annealing on the bonding of nitrogen rich films after deposition was tested. The changes caused by nitrogen and deposition conditions are consistent with previous reports on the formation of paracyanogen structures.

DEVELOPMENT OF THE WAVE CONTOURING RAFT.

The wave contouring raft system is the outcome of ideas initiated and developed by Sir Christopher Cockerell from 1972 onwards. His objective was to develop a wave energy device which is within the bounds of current technology. It should consist of simple, relatively small units, amenable to quantity production, which would enable a power generating system to be built up and commissioned in stages according to needs and production capability. This thinking led to the investigation of chains of pontoons, hinged together so that the passage of a wave down the chain causes the pontoons to oscillate relative to one another. Energy is extracted from the sea by applying a torque about the hinges to damp the motion. The work has involved extensive model testing in wave tanks and the building and testing of a 3-unit 1/10 scale power generating installation in the Solent, as well as design studies for a full size installation for Atlantic conditions.

Superconducting properties of Gd-Ba-Cu-O single grains processed from a new, Ba-rich precursor compound

Gd-Ba-Cu-O (GdBCO) single grains have been previously melt-processed successfully in air using a generic Mg-Nd-Ba-Cu-O (Mg-NdBCO) seed crystal. Previous research has revealed that the addition of a small amount of BaO 2 to the precursor powders prior to melt processing can suppress the formation of Gd/Ba solid solution, and lead to a significant improvement in superconducting properties of the single grains. Research into the effects of a higher Ba content on single grain growth, however, has been limited by the relatively small grain size in the earlier studies. This has been addressed by developing Ba-rich precursor compounds Gd-163 and Gd-143, fabricated specifically to enable the presence of greater concentrations of Ba during the melt process. In this study, we propose a new processing route for the fabrication of high performance GdBCO single grain bulk superconductors in air by enriching the precursor powder with these new Ba rich compounds. The influence of the addition of the new compounds on the microstructures and superconducting properties of GdBCO single grains is reported. © 2008 IOP Publishing Ltd.

Cementation liquefaction remediation for existing buildings

Many typical liquefaction remediation techniques are not appropriate for application under existing buildings and more novel techniques are required. This paper describes centrifuge tests investigating the performance of cementation as a liquefaction remediation method. Two soil profiles with the same superstructure were tested under earthquake shaking. The first profile consisted of a deep layer of loose, liquefiable sand. The second comprised a shallow layer of loose sand overlying dense sand. Centrifuge tests were carried out with a cemented zone underneath the structure, through the full depth of the liquefiable layers and also partial depth. The superstructure was modelled as a single-degree-offreedom system. It is found that a cemented zone through the full depth of a liquefiable layer results in considerable reduction of structural settlements. Increased magnitude and higher frequency accelerations are transmitted to the structure but, depending on the building characteristics, it is likely that improved overall seismic performance can be achieved. Improvements in structural settlements can also be obtained with partialdepth remediation, if the depth of the cemented zone is greater than the depth of liquefaction. This type of remediation seems to have little effect on the accelerations transmitted to the structure.

Sustainable binders for soil stabilisation

Portland cement is the most commonly and widely used binder in ground improvement soil stabilisation applications. However, many changes are now affecting the selection and application of stabilisation additives. These include the significant environmental impacts of Portland cement, increased use of industrial by-products and their variability, increased range of application of binders and the development of alternative cements and novel additives with enhanced environmental and technical performance. This paper presents results from a number of research projects on the application of a number of Portland cement-blended binders, which offer sustainability advantages over Portland cement alone, in soil stabilisation. The blend materials included ground granulated blastfurnace slag, pulverised fuel ash, cement kiln dust, zeolite and reactive magnesia and stabilised soils, ranging from sand and gravel to clay, and were assessed based on their mechanical performance and durability. The results are presented in terms of strength and durability enhancements offered by those blended binders.

Dynamics of in-plane arch rocking: An energy approach

This study employs an analytical model to describe the rocking response of a masonry arch to in-plane seismic loading. Through evaluation of the rate of energy input to the system, the model reveals the ground motions that cause maximum rocking amplification. An experimental investigation of small-scale masonry arches subjected to past earthquake time histories is used to evaluate the analytical model and to explore arch rocking behaviour. The results demonstrate that rocking amplification can occur, but is highly sensitive to slight variations in the ground motion. Thus, the accuracy to which the arch response can be predicted is brought into perspective. The concept that the primary impulse of an expected ground motion is fundamentally important in predicting arch collapse is evaluated in light of the developed energy approach. Finally, a statistical method is proposed for predicting the probability of arch collapse during seismic loading.

Applying quality control in building energy modelling: Comparative simulation of a high performance building

Quality control is considered from the simulator's perspective through comparative simulation of an ultra energy-efficient building with EE4-DOE2.1E and EnergyPlus. The University of Calgary's Leadership in Energy and Environmental Design Platinum Child Development Centre, with a 66% certified energy cost reduction rating, was the case study building. A Natural Resources Canada incentive program required use of EE4 interface with DOE2.1E simulation engine for energy modelling. As DOE2.1E lacks specific features to simulate advanced systems such as radiant cooling in the CDC, an EnergyPlus model was developed to further evaluate these features. The EE4-DOE2.1E model was used for quality control during development of the base EnergyPlus model and simulation results were compared. Advanced energy systems then added to the EnergyPlus model generated small difference in estimated total annual energy use. The comparative simulation process helped identify the main input errors in the draft EnergyPlus model. The comparative use of less complex simulation programs is recommended for quality control when producing more complex models. © 2009 International Building Performance Simulation Association (IBPSA).