New chiral mesogens 3(R)-methylcyclohexanone derivatives

New chiral compounds 3R-methylcyclohexanone derivatives were synthesized. These compounds were revealed to exhibit the mesomorphic behavior within rather wide temperature ranges. Types of formed mesophases and phase transition temperatures were determined by polarizing microscopy, differential scanning calorimetry and small angle scattering of X-ray. Mesomorphic properties of the new chiral compounds were compared with those for the chiral 2-arylidene derivatives of 3R,6R-3-methyl-6-isopropylcyclohexanone (d-isomenthone) studied earlier. Distinctions between these two types of compounds in an ability to form mesophases and also in twisting properties as chiral dopants in induced cholesteric mesophases are considered.

Zonal RANS-LES modeling for turbines in aeroengines

The cost of large-eddy simulation (LES) modeling in various zones of gas turbine aeroengines is outlined. This high cost clearly demonstrates the need to perform hybrid Reynolds-averaged Navier-Stokes-LES (RANS-LES) over the majority of engine zones because the Reynolds number is too high for pure LES. The RANS layer is used to cover over the fine streaks found in the inner part of the boundary layer. The hybrid strategy is applied to various engine zones, which is shown to typically give much greater predictive accuracy than pure RANS simulations. However, the cost estimates show that the RANS layer should be disposed within the low-pressure turbine zone. Also, the nature of the flow physics in this zone makes LES most sensible. © 2012 by Begell House, Inc.