Chemical recycling of municipal packaging waste by pyrolysis

[EN]The present doctoral thesis centers on studying pyrolysis as a chemical recycling technique for rejected packaging waste fractions coming from separation and sorting plants. The pyrolysis experiments have been carried out in a lab-scale installation equipped with a 3.5 L semi-batch reactor and a condensation and collection system for the liquids and gases generated. In the present thesis, an experimental study on the conventional pyrolysis process applied to the aforementioned waste fractions has been conducted, as well as the study of non-conventional or advanced pyrolysis processes such as catalytic and stepwise pyrolysis. The study of the operating parameters has been carried out using a mixed plastics simulated sample, the composition of which is similar to that found in real fractions, and subsequently the optimized process has been applied to real packaging waste. An exhaustive characterization of the solids, liquids and gases obtained in the process has been made after each experiment and their potential uses have been established. Finally, an empirical model that will predict the pyrolysis yields (% organic liquid, % aqueous liquid, % gases, % char, % inorganic solid) as a function of the composition of the initial sample has been developed. As a result of the experimental work done, the requirements have been established for an industrial packaging waste pyrolysis plant that aims to be sufficiently versatile as to generate useful products regardless of the nature of the raw material.

“Steer-by-wire” software garapena

[EU]Proiektu honek automobilen antzinako direkzio sistemak ordezkatuko dituen steer-by-wire-ren inplementazioa deskribatuko du, software-aren garapena, hain zuzen. Lan hau garatzeko, ezinbestekoa izango da orain arte egindako lanen bilketa eta azterketa egitea, baita nolako zailtasunak, arriskuak egongo diren eta posiblea izango litzatekeen etorkizun batean teknologia hau instalatzea. Programazio, mekanika eta automatika ezagutzaren bidez teknologia berri hau ordenagailu batean simulatuko da eta orain arte erabili izan diren teknologiekin alderatuko dira, ateratako emaitzekin ondorio nabarmenak ezarriz. Programazio eta simulaziorako “Labview” eta “Matlab-Simulink” software-ak erabiliko dira, beharrezkoak diren tresnen ezagutzak aurretik lortuz.

Bideratze arazoen ebazpenerako aplikatutako algoritmo metaheuristikoen diseinu, inplementazio eta konparaketa.

[EU]Proiektu honen helburua sare ezberdinetan algoritmo metaheuristikoen erabileraren bitartez bideratze arazoak ebaztea eta aztertzea da. Helburu honetarako erabiliko diren algoritmoak Coral Reefs Optimization eta Firefly Algorithm dira. Bi algoritmoak Python erabiliz inplementatuko dira, baita sareak simulatzen dituen programa ere. Modu honetan, algoritmo bakoitzaren gaitasuna aztertuko da sareko bi punturen arteko bide bideragarri bat, zeinek ezarritako murrizketak betetzen dituen, aurkitzeko; prozesu hau ausaz sortutako simulatutako sare batean oinarrituz garatuko da. Honen bitartez, arazo honen ebazpenerako algoritmo bakoitza egokia den eta bietariko zein den egokiena ondorioztatu ahalko da.