Coupled Ge/Si and Ge isotope ratios as geochemical tracers of seafloor hydrothermal systems: Case studies at Loihi Seamount and East Pacific Rise 9°50’N

Germanium (Ge) and Silicon (Si) exhibit similar geochemical behaviour in marine environments but are variably enriched in seafloor hydrothermal fluids relative to seawater. In this study, Ge isotope and Ge/Si ratio systematics were investigated in low temperature hydrothermal vents from Loihi Seamount (Pacific Ocean, 18°54’N, 155°15’W) and results were compared to high-temperature vents from the East Pacific Rise (EPR) at 9°50’N. Loihi offers the opportunity to understand contrasting Ge and Si behaviour in low temperature seafloor hydrothermal systems characterized by abundant Fe oxyhydroxide deposition at the seafloor. The results show that both Ge/Si and δ74/70Ge in hydrothermal fluids are fractionated relative to the basaltic host rocks. The enrichment in Ge vs. Si relative to fresh basalts, together with Ge isotope fractionation (Δ74/70Ge fluid-basalt up to 1.15 ‰ at EPR 9°50’N and 1.64 ‰ at Loihi) are best explained by the precipitation of minerals (e.g. quartz and Fe-sulfides) during higher temperature seawater-rock reactions in the subsurface. The study of Fe-rich hydrothermal deposits at Loihi, largely composed of Fe-oxyhydroxides, shows that Ge isotopes are also fractionated upon mineral precipitation at the seafloor. We obtained an average Ge isotope fractionation factor between Fe-oxyhydroxide (ferrihydrite) and dissolved Ge in the fluid of -2.0 ± 0.6 ‰ (2sd), and a maximum value of -3.6 ± 0.6 ‰ (2sd), which is consistent with recent theoretical and experimental studies. The study of a hydrothermal chimney at Bio 9 vent at EPR 9°50’N also demonstrates that Ge isotopes are fractionated by approximately -5.6 ± 0.6 ‰ (2sd) during precipitation of metal sulfides under hydrothermal conditions. Using combined Ge/Si and estimated Ge isotope signatures of Ge sinks and sources in seawater, we propose a preliminary oceanic budget of Ge which reveals that an important sink, referred as the “missing Ge sink”, may correspond to Ge sequestration into authigenic Fe-oxyhydroxides in marine sediments. This study shows that combining Ge/Si and δ74/70Ge systematics provides a useful tool to trace hydrothermal Ge and Si sources in marine environments and to understand formation processes of seafloor hydrothermal deposits.

Intraplate versus ridge volcanism on the Pacific-Antarctic Ridge near 37°S -111°W

Exploration of the Foundation Volcanic Chain (33 degrees S-131 degrees W; 37 degrees S-111 degrees W) revealed the existence of different magmatic provinces with relation to their geological settings. (1) The Pacific-Antarctic Ridge (PAR) is made up of several en echelon segments where both glassy midocean ridge basalts (MORBs) with low incompatible elements (K2O<200 ppm, Zr<120 ppm and Ce <20 ppm) as well as andesites and dacites have erupted, (2) Oblique Ridges located up to 300 lan from the PAR axis are topped with seamounts made up essentially of transitional (T) and enriched (E) MORBs with intermediate incompatible elements (K2O=0.11-0.40 %, Zr=70-140 ppm and Ce=15-30 ppm), (3) the Foundation Seamounts (FS) consisting essentially of isolated volcanoes which have erupted alkalic lavas (alkali basalt, trachybasalt and trachyandesite) with high incompatible elements (K2O (0.50-1.1 %, Zr (>150 ppm) and Ce (>48 ppm)) at about 306-1300 km from the PAR axis, (4) The Old Pacific Seamounts built on a crust older than 23 m. y. located west of longitude 124 degrees W (> 1300 km from the PAR axis) consist of T and EMORB. On the PAR axis, extensive crystal fractionation (>65%) produced the silicic lavas. On the basis of Pacific plate reconstruction using a half spreading rate of about 50 mm/yr and integrating the observed compositional changes with respect to the structural settings, it is inferred that the last volcanic events giving rise to the FS took place at about 110 km from the PAR axis about 5 m. y. ago. The Oblique Ridges built between 5 m. y. and <1 m. y. are believed to represent ancient leaky transforms and/or large discontinuities between accreting ridge segments filled by volcanic cones during the interaction (mixing) of the enriched plume components of the FS with PAR depleted (MORB type) magmatism. The Old Pacific Seamounts built on ancient crust (>23 m. y.) with MORB volcanics comparable to those of the the Oblique Ridge-PAR provinces, could also have been formed by an interaction between the Foundation Seamount (dredge site 28) hotspot magmatism and that of an ancient accreting ridge magmatism precursor of the PAR.