Organic Contaminant Analytical Methods of the National Status and Trends Program: 2000-2006

This document describes the analytical methods used to quantify core organic chemicals in tissue and sediment collected as part of NOAA’s National Status and Trends Program (NS&T) for the years 2000-2006. Organic contaminat analytical methods used during the early years of the program are described in NOAA Technical Memoranda NOS ORCA 71 and 130 (Lauenstein and Cantillo, 1993; Lauenstein and Cantillo, 1998) for the years 1984-1992 and 1993-1996, respectively. These reports are available from our website (http://www.ccma.nos.gov) The methods detailed in this document were utilized by the Mussel Watch Project and Bioeffects Project, which are both part of the NS&T program. The Mussel Watch Project has been monitoring contaminants in bivalves and sediments since 1986 and is the longest active national contaminant monitoring program operating in U.S. costal waters. Approximately 280 Mussel Watch sites are sampled on a biennial and decadal timescale for bivalve tissue and sediment respectively. Similarly, the Bioeffects Assessment Project began in 1986 to characterize estuaries and near coastal environs. Using the sediment quality triad approach that measures; (1) levels of contaminants in sediments, (2) incidence and severity of toxicity, and (3) benthic macrofaunal conmmunities, the Bioeffects Project describes the spatial extent of sediment toxicity. Contaminant assessment is a core function of both projects. These methods, while discussed here in the context of sediment and bivalve tissue, were also used with other matricies including: fish fillet, fish liver, nepheloid layer, and suspended particulate matter. The methods described herein are for the core organic contaminants monitored in the NS&T Program and include polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyls (PCBs), butyltins, and organochlorines that have been analyzed consistently over the past 15-20 years. Organic contaminants such as dioxins, perfluoro compounds and polybrominated biphenyl ethers (PBDEs) were analyzed periodically in special studies of the NS&T Program and will be described in another document. All of the analytical techniques described in this document were used by B&B Laboratories, Inc, an affiliate of TDI-Brook International, Inc. in College Station, Texas under contract to NOAA. The NS&T Program uses a performance-based system approach to obtain the best possible data quality and comparability, and requires laboratories to demonstrate precision, accuracy, and sensitivity to ensure results-based performance goals and measures. (PDF contains 75 pages)

Catch trends from Lake Victoria - Tanzanian waters

Catch trends from Fisheries Department reports from the last eleven years (1985-1995) were analyzed. These showed a shift in the fishery from a cichlid-based system to one dominated by Nile perch and tilapias. In recent years, catches have declined from a peak in the early 1990s. Catch per unit effort appears to have remained stable except for a drop in 1995, however, this is considered dubious because the effort showed a doubling in that year. Limitations of the fisheries data collection system for the Tanzanian sector of Lake Victoria are highlighted and discussed.

Gunnislake Fish Counter. Annual Report 1999

This is the Gunnislake Fish Counter, Annual Report 1999 produced by the Environment Agency South West Region on March 2000. The report presents the daily upstream counts of migratory salmonids recorded at Gunnislake Weir fish counting station (SX 435 713) situated on the River Tamar in 1999. The counter data contained within this report covers the period of the commercial migratory salmonid net buy-back scheme and the implementation of the National Spring Salmon Byelaws. The fish counter at Gunnislake is a resistivity based system (Logie 2100A – Aquantic limited) and is installed in the fish pass on the Cornish bank of the River Tamar at the head of the tide. The minimum salmon count for 1999 was 2691. The run pattern observed for salmon and sea trout in 1999 was generally consistent with that of previous years. However, the total combined annual count of salmon and sea trout migrating upstream on the River Tamar in 1999 was 25% higher than the 5 year average (1994 - 1998).

Restormel Fish Counter Annual Report 1999

This is the Restormel Fish Counter, Annual Report 1999 produced by the Environment Agency South West Region on March 2000. The report presents the daily upstream counts of migratory salmonids recorded at Restormel Weir counting station (SX 107 613) River Fowey in 1999. The counter data covers the period of the commercial migratory salmonid net buy-back scheme, which was in operation between March and June 1999. The fish counter is a resistivity based system (Logie 2100 A - Aquantic limited) and operates over all three channels of the weir at Restormel. The minimum salmon count estimate was 497, and the 1999 upstream count for sea trout was 6590. The run pattern observed for salmon and sea trout in 1999 was generally consistent with that of previous years. Flows on average were half those of 1998 during September, October, and November.

Gunnislake Fish Counter Annual Report 2000

This is the Gunnislake Fish Counter, Annual Report 2000 produced by the Environment Agency South West Region on March 2001. The report presents the daily upstream counts of migratory salmonids recorded on the River Tamar at Gunnislake Weir fish counting station (SX 435 713) situated in 2000. Data contained within this report covers the period of the commercial migratory salmonid net buy-back scheme and the National Spring Salmon Byelaws. The fish counter at Gunnislake is a resistivity based system (Logie 2100A – Aquantic limited) and is installed in the fish pass on the Cornish bank of the River Tamar at the head of the tide. The minimum salmon count for 2000 was 2654. The 2000 upstream count for sea trout was 6417. The run pattern observed for salmon and sea trout in 2000 was generally consistent with that of previous years.

Gunnislake Annual Report 2001

This is the Gunnislake Fish Counter, Annual Report 2001 produced by the Environment Agency South West Region on March 2002. The report presents the daily upstream counts of migratory salmonids recorded on the River Tamar at Gunnislake Weir fish counting station (SX 435 713) situated in 2001. Data contained within this report covers the period of the commercial migratory salmonid net buy-back scheme and the National Spring Salmon Byelaws. The fish counter at Gunnislake is a resistivity based system (Logie 2100A – Aquantic limited) and is installed in the fish pass on the Cornish bank of the River Tamar at the head of the tide. The minimum salmon count for 2001 was 3138. The 2001 upstream count for sea trout was 7503. The run pattern observed for salmon and sea trout in 2001 was generally consistent with that of previous years.

Restormel Annual Report 2001

This is the Restormel Fish Counter, Annual Report 2001 produced by the Environment Agency South West Region on March 2002. The report presents the daily upstream counts of migratory salmonids on the River Fowey at Restormel Weir fish counting station (SX 107 613) in 2001. The counter data covers the period of the commercial salmonid net buy back scheme and the national spring salmon byelaws. These reduce the commercial netting season for salmon and sea trout to between 16 June and 31 August. The fish counter at Restormel is installed on a crump sectioned weir on the River Fowey. The fish counter is a resistivity based system and operates over all three channels of the weir. 2001 was a good year for large sea trout. The number of returning large sea trout was above average in April, May, June and July and equal to or higher than the previous recorded maximum in those months. The main run of small sea trout occurred at a similar time to previous years with the highest numbers of fish entering the Fowey during June and July.

Restormel Fish Counter Annual Report 2002

This is the Restormel Fish Counter, Annual Report 2002 produced by the Environment Agency South West Region on March 2003. The report presents the daily upstream counts of migratory salmonids recorded on the River Fowey at Restormel Weir fish counting station (SX 107 613) in 2002. Data contained within this report covers the period of the commercial migratory salmonid net buy-back scheme and the National Spring Salmon Bylaws. The fish counter at Restormel is a resistivity based system (Logie 2100A - Aquantic limited) and is installed on the weir at Restormel approximately 2 km upstream of the tidal limit. The run pattern observed for salmon and sea trout in 2002 was generally consistent with that of previous years. The upstream salmon / large sea trout count for 2002 was 1804.

Fabrication and optimizing of metal nano silicate as toxic metal absorbent from sea water

Pure Water, is a crucial demand of creature life. Following industrial development, extra amount of toxic metals such as chromium enters the environmental cycle through the sewage, which is considered as a serious threat for organisms. One of the modern methods of filtration and removal of contaminants in water, is applying Nano-technology. According to specific property of silicate materials, in this article we try to survey increased power in composites and various absorption in several morphologies and also synthesis of Nano-metal silicates with different morphologies as absorbent of metal toxic ions. At first, we synthesize nano zink silicate with three morphologies considering context and the purpose of this survey. 1) Nano synthesis of zink silicate hollow cavity by hydrothermal method in mixed solvent system of ethanol/glycol polyethylene. 2) Zink nano wires silicate in a water-based system by controlling the amount of sodium silicate. 3) Synthesis of nano zink silicate membrane. After synthesizing, we measured the cadmium ion absorbance by synthesized nano zink silicates. Controlling PH, is the applied absorption method. Next step, we synthesized nano zink-magnesium silicate composite in two various morphologies of nanowires and membrane by different precent of zink and magnesium, in order to optimize synthesized nano metal silicate. We used zink nitrate and magnesium nitrate and also measured cadmium absorption by synthesized nano metal silicates in the same way of PH control absorption. In the 3rd step, in order to determine the impact of the type of metal in nano metal silicate, we synthesized nano magnesium silicate and compared its absorption with nano zink silicate. Furthermore, we calculated the optimal concentration in one of synthesizes. Optimal concentration is the process which has the maximum absorption. While applying two methods of absorption in the test, finally we compared the effect of absorption method on the absorption level. Below you find further steps of synthesis: 1) Using IR, RAMAN, XRD spectroscopy to check the accuracy of synthesis. 2) Checking the dispersion of nano particles in ethanol solution by light microscope. 3) Measuring and observing particles with scanning electron microscope (SEM). 4) Using atomic absorption device for measuring the cadmium concentration in water-based solutions. The nano metal silicates were synthesized successfully. All of synthesized nano absorbents have the cadmium ion absorbency. The cadmium absorption via nano absorbents depend on various factors such as kind of metal in nano silicate and percent of metal in nano metal silicate composite. Meanwhile the absorption and PH control of medium containing the absorbent and solution would affect the cadmium absorption.

Management of waterlogged areas, island and coastal saline soils using fish based mixed farming system

Problems in India regarding the management of various coastal saline soil and waterlogged environments are discussed in detail, considering in particular the potential application of mixed fish farming systems. Various operational and cost requirements of such systems are examined.

HACCP based management system for improving quality of freshwater giant prawn, Macrobrachium rosenbergii

The study was conducted on the present status of HACCP based quality management system of golda, Macrobrachium rosenbergii farms in Fulpur region of Mymensingh. Information was collected on general condition of farms, culture systems and post-harvest quality management. In almost all farms, there is no or inadequate infrastructure facilities such as, road access, electric supply, telecommunications, ice, feed storage facility, vehicle for golda transportation, washing and toilet facilities. The problems associated with sanitation and hygiene was: widespread use of cow dung, poultry manure and construction of open toilet within the vicinity of prawn culture pond. Different grades of commercially available and locally prepared feeds were used for golda culture in the pond. Golda post-larvae (PL) of 40-50 days old were stocked with carp species. The price of golda PL ranged from Tk. 1.00 to Tk. 1.25/piece. The pond size varied from 50 decimal (0.2 ha) to 2.5 acre (1.0 ha) with an average depth of 2-2.5 m. The culture period of golda varied from April-May to November-December and survival rate ranged between 75 and 80%. Production of golda varied from 250-500 kg/acre (625-1,250 kg/ha). Harvested golda were transported to city market within 4 h. Two size grading were generally followed during pricing, e.g. Tk. 500 to 550/kg for >100 g size and Tk. 300/kg for <100 g size. The cost-benefit ratio was found to remain around 1:1.25 depending on availability of PL. Water quality parameters such as, water temperature, pH, dissolved oxygen, total alkalinity and chlorophyll a in five golda farms in Fulpur region were monitored. Water temperature ranged from 29°C to 33°C, dissolved oxygen from 2.28 to 4.13 mg/l, pH between 6.65 and 7.94, alkalinity from 44 to 70 mg/l and chlorophyll a concentration from 61.88 to 102.34 µg/l in the five investigated ponds. The Aerobic Plate Count (APC) of the water sample was within the range of 2.0x10^6 - 2.96x10^7 CFU/ml and of soil samples within the range of 6.9x10^6 - 7.73x10^6 CFU/g. Streptococcus sp., Bacillus sp., Escherichia coli, Staphylococcus sp., Pseudomonas sp. and Salmonella sp. were isolated from pond water and sediment. Different feed samples used for golda was analyzed for proximate composition. Moisture content ranged around 14.14-21.22%, crude protein 20.55-44.1%, lipid 4.67-12.54% and ash 9.7-27.69%. The TVB-N values and peroxide values of feeds used as starter, grower and fish meal were found within the acceptable ranges and samples were free from pathogenic organisms. A training was organized for the golda farmers on HACCP, water quality and post-harvest quality management of prawn.