Treading in Mortimer's footsteps: the geochemical cycling of iron and manganese in Esthwaite water

A study of the geochemical cycling of iron and manganese in a seasonally stratified lake, Esthwaite water is described. This work is based on speculative ideas on environmental redox chemistry of iron which were proposed by C.H. Mortimer in the 1940's. These observations have been verified and some speculations confirmed, along with a new understanding of the manganese cycle, and detailed information on the particulate forms of both iron and manganese. Details on the mechanisms and transformations of iron have also emerged.

Copper, zinc, iron and manganese in sediments and in the rock oyster Saccostrea cucullata in Mumbai coast

Sediment and oyster (Saccostrea cucullata) samples were collected at Dhanda, a fishing village in Mumbai, Maharashtra. The samples were analysed for copper, zinc, iron and manganese contents. Metal concentrations in the sediments and bioaccumulated levels in oysters were correlated. There is no positive correlation between the total sedimentary levels of metals analysed and the bioaccumulated levels of respective metals in oyster. A positive correlation between the bioavailable fractions of zinc, iron and manganese, and the bioaccumulated levels exists. Copper, however, shows a negative correlation with respect to the bioaccumulated levels.

Effect of zinc and manganese supplementation to tricalcium phosphate rich diet for tiger puffer (Takifugu rubripes)

Effects of zinc (Zn) and manganese (Mn) supplementation to a tricalcium phosphate (TCP) rich diet for tiger puffer have been investigated. A TCP supplement to the diet decreased the growth of fish compared to the control diet with a Ca supplementation from Ca-lactate. However, addition of either Zn or Mn to the TCP supplemented diet could not improve the growth of tiger puffer. Addition of both zinc and manganese to the TCP supplemented diet improved the growth of tiger puffer.

Copper and manganese forms in Lake Edku sediments, Alexandria, Egypt

Lake Edku is one of the Nile Delta lakes. It is subjected to contaminations by several anthropogenic materials such as trace elements and other wastes. The distribution of the different chemical forms of copper and manganese has been studied using sequential extraction techniques. Chemical analysis of the sediments shows that CaCO sub(3) ranged from 3.7% to 9.6% and organic matter from 3.06% to 8.11%. The results indicate that the distribution of manganese among the six chemical forms in the sediments of the lake obeys the following order: Mn-residual>Mn-carbonate>Mn-moderately reducible>Mn-organic form>Mn-exchangeable > Mn-easily reducible fraction. Also, the data revealed that more than 50% of the total manganese was found in the residual form, while the remainder was distributed among the other forms. In contrast, more than 70% of the total copper content was associated with the five chemical forms (exchangeable, carbonate, easily and moderately reducible and organic forms). Generally, the enrichment of manganese in the residual form revealed the important role in building up of clay minerals, while the distribution of copper among the different forms reflects an important role in biological and biochemical processes.