Si(100) versus Ge(100): Watching the interface formation for the growth of III-V-based solar cells on abundant substrates

We investigated the atomic surface properties of differently prepared silicon and germanium (100) surfaces during metal-organic vapour phase epitaxy/chemical vapour deposition (MOVPE/MOCVD), in particular the impact of the MOVPE ambient, and applied reflectance anisotropy/difference spectroscopy (RAS/RDS) in our MOVPE reactor to in-situ watch and control the preparation on the atomic length scale for subsequent III-V-nucleation. The technological interest in the predominant opto-electronic properties of III-V-compounds drives the research for their heteroepitaxial integration on more abundant and cheaper standard substrates such as Si(100) or Ge(100). In these cases, a general task must be accomplished successfully, i.e. the growth of polar materials on non-polar substrates and, beyond that, very specific variations such as the individual interface formation and the atomic step structure, have to be controlled. Above all, the method of choice to grow industrial relevant high-performance device structures is MOVPE, not normally compatible with surface and interface sensitive characterization tools, which are commonly based on ultrahigh vacuum (UHV) ambients. A dedicated sample transfer system from MOVPE environment to UHV enabled us to benchmark the optical in-situ spectra with results from various surfaces science instruments without considering disruptive contaminants. X-ray photoelectron spectroscopy (XPS) provided direct observation of different terminations such as arsenic and phosphorous and verified oxide removal under various specific process parameters. Absorption lines in Fourier-transform infrared (FTIR) spectra were used to identify specific stretch modes of coupled hydrides and the polarization dependence of the anti-symmetric stretch modes distinguished different dimer orientations. Scanning tunnelling microscopy (STM) studied the atomic arrangement of dimers and steps and tip-induced H-desorption proved the saturation of dangling bonds after preparati- n. In-situ RAS was employed to display details transiently such as the presence of H on the surface at lower temperatures (T <; 800°C) and the absence of Si-H bonds at elevated annealing temperature and also surface terminations. Ge buffer growth by the use of GeH4 enables the preparation of smooth surfaces and leads to a more pronounced amplitude of the features in the spectra which indicates improvements of the surface quality.

Free-Form, High Energy Performance, Transparent Vacuum Envelope

El artículo examina un nuevo sistema envolvente ligero, delgado, con ahorro energético, libre de formas diseñado para su uso en proyectos de arquitectura.

Experimental measurements of the scattered-light polarization from different liquid flows

An experimental system designed to measure very low optical powers, of the order of a few picowatts, is presented. Its main aid is to detect the polarisation state of scattered light from a fluid flow, in different angular directions with respect to the longitudinal axis of the flow. A laser beam incident linearly polarized crosses the fluid flow orthogonally. The scattered light is detected by means of a photodetector situated behind a lineal polarizer whose orientation can be rotated. The outgoing electrical signal is amplified by means of a Mode-lockin amplifier and is digitally processed.

Mechanical Degradation of Tungsten Alloys at Extreme Temperatures in Vacuum and Oxidation Atmospheres

Mechanical degradation of tungsten alloys at extreme temperatures in vacuum and oxidation atmospheres.

Drifting plasma collection by a positive biased tether wire in LEO-like plasma conditions: current measurement and plasma diagnostic

BETs is a three-year project financed by the Space Program of the European Commission, aimed at developing an efficient deorbit system that could be carried on board any future satellite launched into Low Earth Orbit (LEO). The operational system involves a conductive tape-tether left bare to establish anodic contact with the ambient plasma as a giant Langmuir probe. As a part of this project, we are carrying out both numerical and experimental approaches to estimate the collected current by the positive part of the tether. This paper deals with experimental measurements performed in the IONospheric Atmosphere Simulator (JONAS) plasma chamber of the Onera-Space Environment Department. The JONAS facility is a 9- m3 vacuum chamber equipped with a plasma source providing drifting plasma simulating LEO conditions in terms of density and temperature. A thin metallic cylinder, simulating the tether, is set inside the chamber and polarized up to 1000 V. The Earth's magnetic field is neutralized inside the chamber. In a first time, tether collected current versus tether polarization is measured for different plasma source energies and densities. In complement, several types of Langmuir probes are used at the same location to allow the extraction of both ion densities and electron parameters by computer modeling (classical Langmuir probe characteristics are not accurate enough in the present situation). These two measurements permit estimation of the discrepancies between the theoretical collection laws, orbital motion limited law in particular, and the experimental data in LEO-like conditions without magnetic fields. In a second time, the spatial variations and the time evolutions of the plasma properties around the tether are investigated. Spherical and emissive Langmuir probes are also used for a more extensive characterization of the plasma in space and time dependent analysis. Results show the ion depletion because of the wake effect and the accumulation of- ions upstream of the tether. In some regimes (at large positive potential), oscillations are observed on the tether collected current and on Langmuir probe collected current in specific sites.

Aplicación de la teoría de redes complejas a procesos dinámicos en la sociedad

Podemos definir la sociedad como un sistema complejo que emerge de la cooperación y coordinación de billones de individuos y centenares de países. En este sentido no vivimos en una isla sino que estamos integrados en redes sociales que influyen en nuestro comportamiento. En esta tesis doctoral, presentamos un modelo analítico y una serie de estudios empíricos en los que analizamos distintos procesos sociales dinámicos desde una perspectiva de la teoría de redes complejas. En primer lugar, introducimos un modelo para explorar el impacto que las redes sociales en las que vivimos inmersos tienen en la actividad económica que transcurre sobre ellas, y mas concretamente en hasta qué punto la estructura de estas redes puede limitar la meritocracia de una sociedad. Como concepto contrario a meritocracia, en esta tesis, introducimos el término topocracia. Definimos un sistema como topocrático cuando la influencia o el poder y los ingresos de los individuos vienen principalmente determinados por la posición que ocupan en la red. Nuestro modelo es perfectamente meritocrático para redes completamente conectadas (todos los nodos están enlazados con el resto de nodos). Sin embargo nuestro modelo predice una transición hacia la topocracia a medida que disminuye la densidad de la red, siendo las redes poco densascomo las de la sociedad- topocráticas. En este modelo, los individuos por un lado producen y venden contenidos, pero por otro lado también distribuyen los contenidos producidos por otros individuos mediando entre comprador y vendedor. La producción y distribución de contenidos definen dos medios por los que los individuos reciben ingresos. El primero de ellos es meritocrático, ya que los individuos ingresan de acuerdo a lo que producen. Por el contrario el segundo es topocrático, ya que los individuos son compensados de acuerdo al número de cadenas mas cortas de la red que pasan a través de ellos. En esta tesis resolvemos el modelo computacional y analíticamente. Los resultados indican que un sistema es meritocrático solamente si la conectividad media de los individuos es mayor que una raíz del número de individuos que hay en el sistema. Por tanto, a la luz de nuestros resultados la estructura de la red social puede representar una limitación para la meritocracia de una sociedad. En la segunda parte de esta tesis se presentan una serie de estudios empíricos en los que se analizan datos extraídos de la red social Twitter para caracterizar y modelar el comportamiento humano. En particular, nos centramos en analizar conversaciones políticas, como las que tienen lugar durante campañas electorales. Nuestros resultados indican que la atención colectiva está distribuida de una forma muy heterogénea, con una minoría de cuentas extremadamente influyente. Además, la capacidad de los individuos para diseminar información en Twitter está limitada por la estructura y la posición que ocupan en la red de seguidores. Por tanto, de acuerdo a nuestras observaciones las redes sociales de Internet no posibilitan que la mayoría sea escuchada por la mayoría. De hecho, nuestros resultados implican que Twitter es topocrático, ya que únicamente una minoría de cuentas ubicadas en posiciones privilegiadas en la red de seguidores consiguen que sus mensajes se expandan por toda la red social. En conversaciones políticas, esta minoría de cuentas influyentes se compone principalmente de políticos y medios de comunicación. Los políticos son los mas mencionados ya que la gente les dirige y se refiere a ellos en sus tweets. Mientras que los medios de comunicación son las fuentes desde las que la gente propaga información. En un mundo en el que los datos personales quedan registrados y son cada día mas abundantes y precisos, los resultados del modelo presentado en esta tesis pueden ser usados para fomentar medidas que promuevan la meritocracia. Además, los resultados de los estudios empíricos sobre Twitter que se presentan en la segunda parte de esta tesis son de vital importancia para entender la nueva "sociedad digital" que emerge. En concreto hemos presentado resultados relevantes que caracterizan el comportamiento humano en Internet y que pueden ser usados para crear futuros modelos. Abstract Society can be defined as a complex system that emerges from the cooperation and coordination of billions of individuals and hundreds of countries. Thus, we do not live in social vacuum and the social networks in which we are embedded inevitably shapes our behavior. Here, we present an analytical model and several empirical studies in which we analyze dynamical social systems through a network science perspective. First, we introduce a model to explore how the structure of the social networks underlying society can limit the meritocracy of the economies. Conversely to meritocracy, in this work we introduce the term topocracy. We say that a system is topocratic if the compensation and power available to an individual is determined primarily by her position in a network. Our model is perfectly meritocratic for fully connected networks but becomes topocratic for sparse networks-like the ones in society. In the model, individuals produce and sell content, but also distribute the content produced by others when they belong to the shortest path connecting a buyer and a seller. The production and distribution of content defines two channels of compensation: a meritocratic channel, where individuals are compensated for the content they produce, and a topocratic channel, where individual compensation is based on the number of shortest paths that go through them in the network. We solve the model analytically and show that the distribution of payoffs is meritocratic only if the average degree of the nodes is larger than a root of the total number of nodes. Hence, in the light of our model, the sparsity and structure of networks represents a fundamental constraint to the meritocracy of societies. Next, we present several empirical studies that use data gathered from Twitter to analyze online human behavioral patterns. In particular, we focus on political conversations such as electoral campaigns. We found that the collective attention is highly heterogeneously distributed, as there is a minority of extremely influential accounts. In fact, the ability of individuals to propagate messages or ideas through the platform is constrained by the structure of the follower network underlying the social media and the position they occupy on it. Hence, although people have argued that social media can allow more voices to be heard, our results suggest that Twitter is highly topocratic, as only the minority of well positioned users are widely heard. This minority of influential accounts belong mostly to politicians and traditional media. Politicians tend to be the most mentioned, while media are the sources of information from which people propagate messages. We also propose a methodology to study and measure the emergence of political polarization from social interactions. To this end, we first propose a model to estimate opinions in which a minority of influential individuals propagate their opinions through a social network. The result of the model is an opinion probability density function. Next, we propose an index to quantify the extent to which the resulting distribution is polarized. Finally, we illustrate our methodology by applying it to Twitter data. In a world where personal data is increasingly available, the results of the analytical model introduced in this work can be used to enhance meritocracy and promote policies that help to build more meritocratic societies. Moreover, the results obtained in the latter part, where we have analyzed Twitter, are key to understand the new data-driven society that is emerging. In particular, we have presented relevant information that can be used to benchmark future models for online communication systems or can be used as empirical rules characterizing our online behavior.

Polarization properties of polymer-based photonic crystal fibers

Selectively filled photonic crystal fibers with polydimethylsiloxane (PDMS), a silicon-type material, have been studied. Is has been demonstrated that polarization properties of these hybrid devices and the properties of the guided light in relation with the temperature changes, finding that the state of polarization (SOP) change with the increasing temperature but remains constant for a wide spectrum of wavelengths for a determinate temperature.

Polarization analysis in anisotropous nonlinear dielectric media

Análisis de la polarización en medios dieléctricos anisótropos no lineales centrosimétricos y no centrosimétricos.

Novel dual-band single circular polarization antenna feeding network for satellite communications

In this paper a novel dual-band single circular polarization antenna feeding network for satellite communications is presented. The novel antenna feed chain1 is composed of two elements or subsystems, namely a diplexer and a bi-phase polarizer. In comparison with the classic topology based on an orthomode transducer and a dual-band polarizer, the proposed feed chain presents several advantages, such as compactness, modular design of the different components, broadband operation and versatility in the subsystems interconnection. The design procedure of this new antenna feed configuration is explained. Different examples of antenna feeding networks at 20/30 GHz are presented. It is pointed out the excellent results obtained in terms of isolation and axial ratio.

Temporally flat top pulse generation from gain switched semiconductor lasers based on a polarization interferometer with variable transfer function

We propose the use of a polarization based interferometer with variable transfer function for the generation of temporally flat top pulses from gain switched single mode semiconductor lasers. The main advantage of the presented technique is its flexibility in terms of input pulse characteristics, as pulse duration, spectral bandwidth and operating wavelength. Theoretical predictions and experimental demonstrations are presented and the proposed technique is applied to two different semiconductor laser sources emitting in the 1550 nm region. Flat top pulses are successfully obtained with input seed pulses with duration ranging from 40 ps to 100 ps.

Thermally tunable polarization by nanoparticle plasmonic resonance in photonic crystal fibers

A photonic crystal fiber selectively filled with silver nanoparticles dispersed in polydimethylsiloxane has been numerically studied via finite elements analysis. These nanoparticles possess a localized surface plasmon resonance in the visible region which depends on the refractive index of the surrounding medium. The refractive index of polydimethylsiloxane can be thermally tuned leading to the design of polarization tunable filters. Filters found with this setup show anisotropic attenuation of the x-polarization fundamental mode around ?x = 1200dB/cm remarkably higher than the y-polarization mode. Moreover, high fiber birefringence and birefringence reversal is observed in the spectral region of the plasmon.

Reflectarray antennas for dual polarization and broadband telecom satellite applications

A reflectarray antenna with improved performance is proposed to operate in dual-polarization and transmit-receive frequencies in Ku-band for broadcast satellite applications. The reflectarray element contains two orthogonal sets of four coplanar parallel dipoles printed on two surfaces, each set combining lateral and broadside coupling. A 40-cm prototype has been designed, manufactured, and tested. The lengths of the coupled dipoles in the reflectarray cells have been optimized to produce a collimated beam in dual polarization in the transmit and receive bands. The measured radiation patterns confirm the high performance of the antenna in terms of bandwidth (27%), low losses, and low levels of cross polarization. Some preliminary simulations at 11.95 GHz for a 1.2-m antenna with South American coverage are presented to show the potential of the proposed antenna for spaceborne antennas in Ku-band.

Immune Polarization in Allergic Patients: Role of the Innate Immune System

Allergens come into contact with the immune system as components of a very diverse mixture. The most common sources are pollen grains, food, and waste. These sources contain a variety of immunomodulatory components that play a key role in the induction of allergic sensitization. The way allergen molecules bind to the cells of the immune system can determine the immune response. In order to better understand how allergic sensitization is triggered, we review the molecular mechanisms involved in the development of allergy and the role of immunomodulators in allergen recognition by innate cells.

Light polarization sensitive photodetectors with m- and r-plane homoepitaxial ZnO/ZnMgO quantum wells

Homoepitaxial ZnO/(Zn,Mg)O multiple quantum wells (MQWs) grown with m- and r-plane orientations are used to demonstrate Schottky photodiodes sensitive to the polarization state of light. In both orientations, the spectral photoresponse of the MQW photodiodes shows a sharp excitonic absorption edge at 3.48 eV with a very low Urbach tail, allowing the observation of the absorption from the A, B and C excitonic transitions. The absorption edge energy is shifted by ∼30 and ∼15 meV for the m- and r-plane MQW photodiodes, respectively, in full agreement with the calculated polarization of the A, B, and C excitonic transitions. The best figures of merit are obtained for the m-plane photodiodes, which present a quantum efficiency of ∼11%, and a specific detectivity D* of ∼6.4 × 1010 cm Hz1/2/W. In these photodiodes, the absorption polarization sensitivity contrast between the two orthogonal in-plane axes yields a maximum value of (R⊥/R||)max ∼ 9.9 with a narrow bandwidth of ∼33 meV.