4 resultados para polymers in dispersed form

em Universidad Politécnica de Madrid


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Derive coordinate-free expressions for geometric characteristics of conics written in Bézier form in terms of their control points and weights.

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Synthetic derivation of closed formulae of the geometric characteristic of a conic given in Bézier form in terms of its control polygon, (P; Q; R) and weights, (1; w; 1g)

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Polymers constitute a distinct class of anisotropic particles with unique dynamical, rheological and mechanical properties.

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We review the main results from extensive Monte Carlo (MC) simulations on athermal polymer packings in the bulk and under confinement. By employing the simplest possible model of excluded volume, macromolecules are represented as freely-jointed chains of hard spheres of uniform size. Simulations are carried out in a wide concentration range: from very dilute up to very high volume fractions, reaching the maximally random jammed (MRJ) state. We study how factors like chain length, volume fraction and flexibility of bond lengths affect the structure, shape and size of polymers, their packing efficiency and their phase behaviour (disorder–order transition). In addition, we observe how these properties are affected by confinement realized by flat, impenetrable walls in one dimension. Finally, by mapping the parent polymer chains to primitive paths through direct geometrical algorithms, we analyse the characteristics of the entanglement network as a function of packing density.