The structure of lean hydrogen-air flame balls

An analysis of the structure of flame balls encountered under microgravity conditions, which are stable due to radiant energy losses from H₂O, is carried out for fuel-lean hydrogen-air mixtures. It is seen that, because of radiation losses, in stable flame balls the maximum flame temperature remains close to the crossover temperature, at which the rate of the branching step H + O₂ -> OH + O equals that of the recombination step H + O₂ + M -> HO₂ + M. Under those conditions, all chemical intermediates have very small concentrations and follow the steady-state approximation, while the main species react according to the overall step 2H₂ + O₂-> 2H₂O; so that a one-step chemical-kinetic description, recently derived by asymptotic analysis for near-limit fuel-lean deflagrations, can be used with excellent accuracy to describe the whole branch of stable flame balls. Besides molecular diffusion in a binary-diffusion approximation, Soret diffusion is included, since this exerts a nonnegligible effect to extend the flammability range. When the large value of the activation energy of the overall reaction is taken into account, the leading-order analysis in the reaction-sheet approximation is seen to determine the flame ball radius as that required for radiant heat losses to remove enough of the heat released by chemical reaction at the flame to keep the flame temperature at a value close to crossover. The results are relevant to burning velocities at lean equivalent ratios and may influence fire-safety issues associated with hydrogen utilization.

Diseño de una vivienda unifamiliar con instalación geotérmica de muy baja entalpía

El objetivo del presente proyecto es el diseño de una vivienda unifamiliar de manera que el aporte de energía no renovable sea el mínimo para conseguir las condiciones de confort óptimas para los ocupantes durante todo el año. Para su diseño se tendrá en cuenta el aporte de energía solar pasiva y el uso de aislantes térmicos a lo largo de la envolvente para la reducción de las necesidades de energía. Se dimensiona una instalación geotérmica para el abastecimiento de calefacción, refrigeración y agua caliente sanitaria (ACS). En este dimensionamiento se incluyen los sondeos geotérmicos, el equipo de bomba de calor y la instalación de suelo radiante. En el estudio de iluminación se analizan las necesidades de alumbrado de la vivienda utilizando luminarias led. Por último se evalúa la viabilidad económica que supone sustituir una instalación de caldera de gasoil por la instalación geotérmica dimensionada y la viabilidad de sustituir luminarias incandescentes por luminarias led. ABSTRACT The purpose of this paper is the design of a single family home with the lowest nonrenewable energy input, so optimum comfort living conditions for the occupants during the whole year can be reached. In order to design the house, both passive solar energy input and the use of thermal insulators will be taken into account. A geothermal installation for the heating, cooling and Domestic Hot Water (DHC) supply will be measured. In this measuring, the boreholls, the heat pump equipment and the radiant floor heating installation are included. In the study of illumination of the house, the lighting needs using LED luminaires are analised. Finally, the economic viability when replacing the installation of a diesel boiler for the measured geothermal installation is assessed, as well as the viability when replacing incandescent luminaires for LED luminaires

La implementación arquitectónica de los acristalamientos activos con agua circulante, y su contribución en edificios de consumo de energía casi nulo

La presente Tesis Doctoral evalúa la contribución de una fachada activa, constituida por acristalamientos con circulación de agua, en el rendimiento energético del edificio. Con especial énfasis en la baja afección sobre su imagen, su integración ha de favorecer la calificación del edificio con el futuro estándar de Edificio de consumo de Energía Casi Nulo (EECN). El propósito consiste en cuantificar su aportación a limitar la demanda de climatización, como solución de fachada transparente acorde a las normas de la energía del 2020. En el primer capítulo se introduce el planteamiento del problema. En el segundo capítulo se desarrollan la hipótesis y el objetivo fundamental de la investigación. Para tal fin, en el tercer capítulo, se revisa el estado del arte de la tecnología y de la investigación científica, mediante el análisis de la literatura de referencia. Se comparan patentes, prototipos, sistemas comerciales asimilables, investigaciones en curso en Universidades, y proyectos de investigación y desarrollo, sobre envolventes que incorporan acristalamientos con circulación de agua. El método experimental, expuesto en el cuarto capítulo, acomete el diseño, la fabricación y la monitorización de un prototipo expuesto, durante ciclos de ensayos, a las condiciones climáticas de Madrid. Esta fase ha permitido adquirir información precisa sobre el rendimiento del acristalamiento en cada orientación de incidencia solar, en las distintas estaciones del año. En paralelo, se aborda el desarrollo de modelos teóricos que, mediante su asimilación a soluciones multicapa caracterizadas en las herramientas de simulación EnergyPlus y IDA-ICE (IDA Indoor Climate and Energy), reproducen el efecto experimental. En el quinto capítulo se discuten los resultados experimentales y teóricos, y se analiza la respuesta del acristalamiento asociado a un determinado volumen y temperatura del agua. Se calcula la eficiencia en la captación de la radiación y, mediante la comparativa con un acristalamiento convencional, se determina la reducción de las ganancias solares y las pérdidas de energía. Se comparan el rendimiento del acristalamiento, obtenido experimentalmente, con el ofrecido por paneles solares fototérmicos disponibles en el mercado. Mediante la traslación de los resultados experimentales a casos de células de tamaño habitable, se cuantifica la afección del acristalamiento sobre el consumo en refrigeración y calefacción. Diferenciando cada caso por su composición constructiva y orientación, se extraen conclusiones sobre la reducción del gasto en climatización, en condiciones de bienestar. Posteriormente, se evalúa el ahorro de su incorporación en un recinto existente, de construcción ligera, localizado en la Escuela de Arquitectura de la Universidad Politécnica de Madrid (UPM). Mediante el planteamiento de escenarios de rehabilitación energética, se estima su compatibilidad con un sistema de climatización mediante bomba de calor y extracción geotérmica. Se describe el funcionamiento del sistema, desde la perspectiva de la operación conjunta de los acristalamientos activos e intercambio geotérmico, en nuestro clima. Mediante la parametrización de sus funciones, se estima el beneficio adicional de su integración, a partir de la mejora del rendimiento de la bomba de calor COP (Coefficient of Performance) en calefacción, y de la eficiencia EER (Energy Efficiency Ratio) en refrigeración. En el recinto de la ETSAM, se ha analizado la contribución de la fachada activa en su calificación como Edificio de Energía Casi Nula, y estudiado la rentabilidad económica del sistema. En el sexto capítulo se exponen las conclusiones de la investigación. A la fecha, el sistema supone alta inversión inicial, no obstante, genera elevada eficiencia con bajo impacto arquitectónico, reduciéndose los costes operativos, y el dimensionado de los sistemas de producción, de mayor afección sobre el edificio. Mediante la envolvente activa con suministro geotérmico no se condena la superficie de cubierta, no se ocupa volumen útil por la presencia de equipos emisores, y no se reduce la superficie o altura útil a base de reforzar los aislamientos. Tras su discusión, se considera una alternativa de valor en procesos de diseño y construcción de Edificios de Energía Casi Nulo. Se proponen líneas de futuras investigación cuyo propósito sea el conocimiento de la tecnología de los acristalamientos activos. En el último capítulo se presentan las actividades de difusión de la investigación. Adicionalmente se ha proporcionado una mejora tecnológica a las fachadas activas existentes, que ha derivado en la solicitud de una patente, actualmente en tramitación. ABSTRACT This Thesis evaluates the contribution of an active water flow glazing façade on the energy performance of buildings. Special emphasis is made on the low visual impact on its image, and the active glazing implementation has to encourage the qualification of the building with the future standard of Nearly Zero Energy Building (nZEB). The purpose is to quantify the façade system contribution to limit air conditioning demand, resulting in a transparent façade solution according to the 2020 energy legislation. An initial approach to the problem is presented in first chapter. The second chapter develops the hypothesis and the main objective of the research. To achieve this purpose, the third chapter reviews the state of the art of the technology and scientific research, through the analysis of reference literature. Patents, prototypes, assimilable commercial systems, ongoing research in other universities, and finally research and development projects incorporating active fluid flow glazing are compared. The experimental method, presented in fourth chapter, undertakes the design, manufacture and monitoring of a water flow glazing prototype exposed during test cycles to weather conditions in Madrid. This phase allowed the acquisition of accurate information on the performance of water flow glazing on each orientation of solar incidence, during different seasons. In parallel, the development of theoretical models is addressed which, through the assimilation to multilayer solutions characterized in the simulation tools EnergyPlus and IDA-Indoor Climate and Energy, reproduce the experimental effect. Fifth chapter discusses experimental and theoretical results focused to the analysis of the active glazing behavior, associated with a specific volume and water flow temperature. The efficiency on harvesting incident solar radiation is calculated, and, by comparison with a conventional glazing, the reduction of solar gains and energy losses are determined. The experimental performance of fluid flow glazing against the one offered by photothermal solar panels available on the market are compared. By translating the experimental and theoretical results to cases of full-size cells, the reduction in cooling and heating consumption achieved by active fluid glazing is quantified. The reduction of energy costs to achieve comfort conditions is calculated, differentiating each case by its whole construction composition and orientation. Subsequently, the saving of the implementation of the system on an existing lightweight construction enclosure, located in the School of Architecture at the Polytechnic University of Madrid (UPM), is then calculated. The compatibility between the active fluid flow glazing and a heat pump with geothermal heat supply system is estimated through the approach of different energy renovation scenarios. The overall system operation is described, from the perspective of active glazing and geothermal heat exchange combined operation, in our climate. By parameterization of its functions, the added benefit of its integration it is discussed, particularly from the improvement of the heat pump performance COP (Coefficient of Performance) in heating and efficiency EER (Energy Efficiency Ratio) in cooling. In the case study of the enclosure in the School of Architecture, the contribution of the active glazing façade in qualifying the enclosure as nearly Zero Energy Building has been analyzed, and the feasibility and profitability of the system are studied. The sixth chapter sets the conclusions of the investigation. To date, the system may require high initial investment; however, high efficiency with low architectural impact is generated. Operational costs are highly reduced as well as the size and complexity of the energy production systems, which normally have huge visual impact on buildings. By the active façade with geothermal supply, the deck area it is not condemned. Useful volume is not consumed by the presence of air-conditioning equipment. Useful surface and room height are not reduced by insulation reinforcement. After discussion, water flow glazing is considered a potential value alternative in nZEB design and construction processes. Finally, this chapter proposes future research lines aiming to increase the knowledge of active water flow glazing technology. The last chapter presents research dissemination activities. Additionally, a technological improvement to existing active facades has been developed, which has resulted in a patent application, currently in handling process.

Ultra high temperature latent heat energy storage and thermophotovoltaic energy conversion

A conceptual energy storage system design that utilizes ultra high temperature phase change materials is presented. In this system, the energy is stored in the form of latent heat and converted to electricity upon demand by TPV (thermophotovoltaic) cells. Silicon is considered in this study as PCM (phase change material) due to its extremely high latent heat (1800 J/g or 500 Wh/kg), melting point (1410 C), thermal conductivity (~25 W/mK), low cost (less than $2/kg or $4/kWh) and abundance on earth. The proposed system enables an enormous thermal energy storage density of ~1 MWh/m3, which is 10e20 times higher than that of lead-acid batteries, 2e6 times than that of Li-ion batteries and 5e10 times than that of the current state of the art LHTES systems utilized in CSP (concentrated solar power) applications. The discharge efficiency of the system is ultimately determined by the TPV converter, which theoretically can exceed 50%. However, realistic discharge efficiencies utilizing single junction TPV cells are in the range of 20e45%, depending on the semiconductor bandgap and quality, and the photon recycling efficiency. This concept has the potential to achieve output electric energy densities in the range of 200-450 kWhe/m3, which is comparable to the best performing state of the art Lithium-ion batteries.

Reduced order models for industrial thermo-fluid problems

A new method is presented to generate reduced order models (ROMs) in Fluid Dynamics problems of industrial interest. The method is based on the expansion of the flow variables in a Proper Orthogonal Decomposition (POD) basis, calculated from a limited number of snapshots, which are obtained via Computational Fluid Dynamics (CFD). Then, the POD-mode amplitudes are calculated as minimizers of a properly defined overall residual of the equations and boundary conditions. The method includes various ingredients that are new in this field. The residual can be calculated using only a limited number of points in the flow field, which can be scattered either all over the whole computational domain or over a smaller projection window. The resulting ROM is both computationally efficient(reconstructed flow fields require, in cases that do not present shock waves, less than 1 % of the time needed to compute a full CFD solution) and flexible(the projection window can avoid regions of large localized CFD errors).Also, for problems related with aerodynamics, POD modes are obtained from a set of snapshots calculated by a CFD method based on the compressible Navier Stokes equations and a turbulence model (which further more includes some unphysical stabilizing terms that are included for purely numerical reasons), but projection onto the POD manifold is made using the inviscid Euler equations, which makes the method independent of the CFD scheme. In addition, shock waves are treated specifically in the POD description, to avoid the need of using a too large number of snapshots. Various definitions of the residual are also discussed, along with the number and distribution of snapshots, the number of retained modes, and the effect of CFD errors. The method is checked and discussed on several test problems that describe (i) heat transfer in the recirculation region downstream of a backwards facing step, (ii) the flow past a two-dimensional airfoil in both the subsonic and transonic regimes, and (iii) the flow past a three-dimensional horizontal tail plane. The method is both efficient and numerically robust in the sense that the computational effort is quite small compared to CFD and results are both reasonably accurate and largely insensitive to the definition of the residual, to CFD errors, and to the CFD method itself, which may contain artificial stabilizing terms. Thus, the method is amenable for practical engineering applications. Resumen Se presenta un nuevo método para generar modelos de orden reducido (ROMs) aplicado a problemas fluidodinámicos de interés industrial. El nuevo método se basa en la expansión de las variables fluidas en una base POD, calculada a partir de un cierto número de snapshots, los cuales se han obtenido gracias a simulaciones numéricas (CFD). A continuación, las amplitudes de los modos POD se calculan minimizando un residual global adecuadamente definido que combina las ecuaciones y las condiciones de contorno. El método incluye varios ingredientes que son nuevos en este campo de estudio. El residual puede calcularse utilizando únicamente un número limitado de puntos del campo fluido. Estos puntos puede encontrarse dispersos a lo largo del dominio computacional completo o sobre una ventana de proyección. El modelo ROM obtenido es tanto computacionalmente eficiente (en aquellos casos que no presentan ondas de choque reconstruir los campos fluidos requiere menos del 1% del tiempo necesario para calcular una solución CFD) como flexible (la ventana de proyección puede escogerse de forma que evite contener regiones con errores en la solución CFD localizados y grandes). Además, en problemas aerodinámicos, los modos POD se obtienen de un conjunto de snapshots calculados utilizando un código CFD basado en la versión compresible de las ecuaciones de Navier Stokes y un modelo de turbulencia (el cual puede incluir algunos términos estabilizadores sin sentido físico que se añaden por razones puramente numéricas), aunque la proyección en la variedad POD se hace utilizando las ecuaciones de Euler, lo que hace al método independiente del esquema utilizado en el código CFD. Además, las ondas de choque se tratan específicamente en la descripción POD para evitar la necesidad de utilizar un número demasiado grande de snapshots. Varias definiciones del residual se discuten, así como el número y distribución de los snapshots,el número de modos retenidos y el efecto de los errores debidos al CFD. El método se comprueba y discute para varios problemas de evaluación que describen (i) la transferencia de calor en la región de recirculación aguas abajo de un escalón, (ii) el flujo alrededor de un perfil bidimensional en regímenes subsónico y transónico y (iii) el flujo alrededor de un estabilizador horizontal tridimensional. El método es tanto eficiente como numéricamente robusto en el sentido de que el esfuerzo computacional es muy pequeño comparado con el requerido por el CFD y los resultados son razonablemente precisos y muy insensibles a la definición del residual, los errores debidos al CFD y al método CFD en sí mismo, el cual puede contener términos estabilizadores artificiales. Por lo tanto, el método puede utilizarse en aplicaciones prácticas de ingeniería.

Assessment of Hydrogen as suistinable clean energy

The progressive depletion of fossil fuels and their high contribution to the energy supply in this modern society forces that will be soon replaced by renewable fuels. But the dispersion and alternation of renewable energy production also undertake to reduce their costs to use as energy storage and hydrogen carrier. It is necessary to develop technologies for hydrogen production from all renewable energy storage technologies and the development of energy production from hydrogen fuel cells and cogeneration and tri generation systems. In order to propel this technological development discussed where the hydrogen plays a key role as energy storage and renewable energy, the National Centre of Hydrogen and Fuel Cell Technology Experimentation in Spain equipped with installations that enable scientific and technological design, develop, verify, certify, approve, test, measure and, more importantly, the facility ensures continuous operation for 24 hours a day, 365 days year. At the same time, the system is scalable so as to allow continuous adaptation of new technologies are developed and incorporated into the assembly to verify integration at the same time it checks the validity of their development. The transformation sector can be said to be the heart of the system, because without neglecting the other sectors, this should prove the validity of hydrogen as a carrier - energy storage are important efforts that have to do to demonstrate the suitability of fuel cells or internal combustion systems to realize the energy stored in hydrogen at prices competitive with conventional systems. The multiple roles to meet the fuel cells under different conditions of operation require to cover their operating conditions, many different sizes and applications. The fourth area focuses on integration is an essential complement within the installation. We must integrate not only the electricity produced, but also hydrogen is used and the heat generated in the process of using hydrogen energy. The energy management in its three forms: hydrogen chemical, electrical and thermal integration requires complicated and require a logic and artificial intelligence extremes to ensure maximum energy efficiency at the same time optimum utilization is achieved. Verification of the development and approval in the entire production system and, ultimately, as a demonstrator set to facilitate the simultaneous evolution of production technology, storage and distribution of hydrogen fuel cells has been assessed.

Some physical and chemical proceddes in fluids

The ability to reproduce reduced gravity conditions for long periods is one of the reasons why the orbiting laboratory is so attractive. In this paper several fluid dynamics problem areas are reviewed in which zero-gravity conditions are of great importance. Although emphasis is placed on space processing, there are some older problems also in which gravity masks the phenomcna, impeding a reasonably simple approach to the solution. Three problems are considered: Thermal convection under reduced gravity. The dumping effect ofsurface gravity waves at the outset of convection induced by surface tractions is discussed in particular. The existence of convection is of concern for some satellite thermal control techniques presently used, and for most of the proposed manufacturing processes. Whereas convection should be normally avoided, problems related to the containerless stirring ofa melt constitute an exception. Secondly, gravity and chemical reactions. Although chemical reactions are independent of gravity because of the small mass of the molecules and atoms involved, in many cases the reaction rate dcpends on the arrival of the species to the reaction zone. When the arrival process is buoyancy-controlled, the net specd of the reaction will be affected by the gravity. Thirdly, two-phase flows under reduced gravity provkle interesting problems from boiling heat transfer to degasslng of melts. This part of the paper deals only with the measurement of sound veiocity in a liquid containing bubbles. It is suggested that such measurements should be mude under reduced gravity to provide reliable residís.

Systematic Approach for the selection of monitoring technologies in CO2 geological storage projects. Application of multicriteria decision making

Geologic storage of carbon dioxide (CO2) has been proposed as a viable means for reducing anthropogenic CO2 emissions. Once injection begins, a program for measurement, monitoring, and verification (MMV) of CO2 distribution is required in order to: a) research key features, effects and processes needed for risk assessment; b) manage the injection process; c) delineate and identify leakage risk and surface escape; d) provide early warnings of failure near the reservoir; and f) verify storage for accounting and crediting. The selection of the methodology of monitoring (characterization of site and control and verification in the post-injection phase) is influenced by economic and technological variables. Multiple Criteria Decision Making (MCDM) refers to a methodology developed for making decisions in the presence of multiple criteria. MCDM as a discipline has only a relatively short history of 40 years, and it has been closely related to advancements on computer technology. Evaluation methods and multicriteria decisions include the selection of a set of feasible alternatives, the simultaneous optimization of several objective functions, and a decision-making process and evaluation procedures that must be rational and consistent. The application of a mathematical model of decision-making will help to find the best solution, establishing the mechanisms to facilitate the management of information generated by number of disciplines of knowledge. Those problems in which decision alternatives are finite are called Discrete Multicriteria Decision problems. Such problems are most common in reality and this case scenario will be applied in solving the problem of site selection for storing CO2. Discrete MCDM is used to assess and decide on issues that by nature or design support a finite number of alternative solutions. Recently, Multicriteria Decision Analysis has been applied to hierarchy policy incentives for CCS, to assess the role of CCS, and to select potential areas which could be suitable to store. For those reasons, MCDM have been considered in the monitoring phase of CO2 storage, in order to select suitable technologies which could be techno-economical viable. In this paper, we identify techniques of gas measurements in subsurface which are currently applying in the phase of characterization (pre-injection); MCDM will help decision-makers to hierarchy the most suitable technique which fit the purpose to monitor the specific physic-chemical parameter.

Testing a GIS-based methodology for optimal location of Pumped Storage power plants in Norway

Europe needs to restructure its energy system. The aim to decrease the reliance on fossil fuels to a higher dependence on renewable energy has now been imposed by The European Commission. In order to achieve this goal there is a great interest in Norway to become "The Green Battery of Europe". In the pursuit of this goal a GIS-tool was created to investigate the pump storage potential in Norway. The tool searches for possible connections between existing reservoirs and dams with the criteria selected by the user. The aim of this thesis was to test the tool and see if the results suggested were plausible, develop a cost calculation method for the PSH lines, and make suggestions for further development of the tool. During the process the tool presented many non-feasible pumped storage hydropower (PSH) connections. The area of Telemark was chosen for the more detailed study. The results were discussed and some improvements were suggested for further development of the tool. Also a sensitivity test was done to see which of the parameters set by the user are the most relevant for the PSH connection suggestion. From a range of the most promising PSH plants suggested by the tool, the one between Songavatn and Totak was chosen for a case study, where there already exists a power plant between both reservoirs. A new Pumped Storage Plant was designed with a power production of 1200 MW. There are still many topics open to discussion, such as how to deal with environmental restrictions, or how to deal with inflows and outflows of the reservoirs from the existing power plants. Consequently the GIS-tool can be a very useful tool to establish the best possible connections between existing reservoirs and dams, but it still needs a deep study and the creation of new parameters for the user.

Effects of high hydrostatic pressure on rheological and termal properties of chickpea Cicer arietinum L. flour slurry and heat-induced paste.

Thermorheological changes in high hydrostatic pressure (HHP)-treated chickpea flour (CF) slurries were studied as a function of pressure level (0.1, 150, 300, 400, and 600 MPa) and slurry concentration (1:5, 1:4, 1:3, and 1:2 flour-to-water ratios). HHP-treated slurries were subsequently analyzed for changes in properties produced by heating, under both isothermal and non-isothermal processes. Elasticity (G′) of pressurized slurry increased with pressure applied and concentration. Conversely, heat-induced CF paste gradually transformed from solid-like behavior to liquid-like behavior as a function of moisture content and pressure level. The G′ and enthalpy of the CF paste decreased with increasing pressure level in proportion with the extent of HHP-induced starch gelatinization. At 25 °C and 15 min, HHP treatment at 450 and 600 MPa was sufficient to complete gelatinization of CF slurry at the lowest concentration (1:5), while more concentrated slurries would require higher pressures and temperature during treatment or longer holding times. Industrial relevance Demand for chickpea gel has increased considerably in the health and food industries because of its many beneficial effects. However, its use is affected by its very difficult handling. Judicious application of high hydrostatic pressure (HHP) at appropriate levels, adopted as a pre-processing instrument in combination with heating processes, is presented as an innovative technology to produce a remarkable decrease in thermo-hardening of heat-induced chickpea flour paste, permitting the development of new chickpea-based products with desirable handling properties and sensory attributes.

Storage stability of SBS/sulfur modified bitumens at high temperature: influence of bitumen composition and structure

Polymer modified bitumens, PMBs, are usually prepared at high temperature and subsequently stored for a period of time, also at high temperature. The stability of PMBs, in these conditions, has a decisive influence in order to obtain the adequate performances for practical applications. In this article the attention is focused in the analysis of the factors that determine the stability of styrene–butadiene–styrene copolymer (SBS)/sulfur modified bitumens when the mixtures are maintained at high temperature. Bitumens from different crude oil sources were used to prepare SBS/sulfur modified bitumens. Changes in the values of viscosity, softening point, as well as in the morphology of PMB samples, stored at 160 °C, were related to the bitumen chemical composition and to the amount of asphaltene micelles present in the neat bitumen used in their preparation El trabajo se centra en el estudio de la influencia de la estructura /composición del betún sobre la compatibilidad del sistema betún/SBS. Cuatro betunes provenientes de dos crudos distintos se seleccionaron y sus mezclas se utilizaron para preparar betunes modificados con contenidos de SBS del 3% en peso

Steady state analysis of a storage integrated solar thermophotovoltaic (SISTPV) system

This paper presents the theoretical analysis of a storage integrated solar thermophotovoltaic (SISTPV) system operating in steady state. These systems combine thermophotovoltaic (TPV) technology and high temperature thermal storage phase-change materials (PCM) in the same unit, providing a great potential in terms of efficiency, cost reduction and storage energy density. The main attraction in the proposed system is its simplicity and modularity compared to conventional Concentrated Solar Power (CSP) technologies. This is mainly due to the absence of moving parts. In this paper we analyze the use of Silicon as the phase change material (PCM). Silicon is an excellent candidate because of its high melting point (1680 K) and its very high latent heat of fusion of 1800 kJ/kg, which is about ten times greater than the conventional PCMs like molten salts. For a simple system configuration, we have demonstrated that overall conversion efficiencies up to ?35% are approachable. Although higher efficiencies are expected by incorporating more advanced devices like multijunction TPV cells, narrow band selective emitters or adopting near-field TPV configurations as well as by enhancing the convective/conductive heat transfer within the PCM. In this paper, we also discuss about the optimum system configurations and provide the general guidelines for designing these systems. Preliminary estimates of night time operations indicate it is possible to achieve over 10 h of operation with a relatively small quantity of Silicon.

Evaluación del comportamiento mecánico de estructuras de hormigón armado utilizadas como elementos termoactivos

El objetivo de este trabajo es conocer las posibles modificaciones que puede producir en el comportamiento de las estructuras de hormigón armado (EHA) el hecho de que sean utilizadas como estructuras termoactivas, ya sea como intercambiadores en contacto con el terreno, o como sistema de distribución de calor utilizando la inercia térmica de los elementos de hormigón del edificio, basándose en el uso de energías renovables. Las EHA termoactivas se caracterizan por la incorporación en su interior de tubos de polietileno por los que circulan fluidos a temperaturas medias, que pueden incidir en el comportamiento mecánico de los elementos estructurales debido a dos efectos fundamentales: el incremento de temperatura que se produce en el interior de la EHA y la perturbación provocada por la incorporación de los tubos de polietileno. Con este fin, se ha realizado una campaña experimental de probetas de hormigón, estudiando los dos efectos por separado, por un lado se ha evaluado el comportamiento de probetas de hormigón tipo H-25 y tipo H-30 sometidas a cuatro temperaturas diferentes: 20ºC, 40ºC, 70ºC y 100ºC, ensayando la resistencia a compresión y la resistencia a anclaje/adherencia mediante ensayo “pull-out”; y, por otro lado, se ha evaluado el comportamiento de probetas de hormigón tipo H-25 y tipo H-30, elaboradas con dos tipos de molde (cilíndrico y cúbico), en las que se ha colocado tubos de polietileno en su interior en distintas posiciones, ensayando su resistencia a compresión. Los resultados de los ensayos han puesto de manifiesto que aunque se produce una disminución en la resistencia a compresión, y a arrancamiento, del hormigón, al ser sometido a aumentos de temperatura, esta disminución de la propiedades mecánicas es inferior al 20% al no superar esta tecnología los 70ºC; y respecto a la variación de la resistencia a compresión de probetas cilíndricas y cúbicas, debidas a la incorporación de los tubos de polietileno, se observa que si la posición de los mismos es paralela a la dirección de la carga tampoco se ven comprometidas las propiedad mecánicas del hormigón en valores superiores al 20%. ABSTRACT The aim of this project is to study the effects of using concrete structures as thermo-active constructions, either as energy foundations or other kind of thermo-active ground structures, or as a thermally activated building structure utilizing its own thermal mass conductivity and storage capacity to heat and cool buildings, based on renewable or “free” energy sources. The pipes, filled with a heat carrier fluid, that are embedded into the building´s concrete elements may bring on two different adverse effects on concrete structures. In one hand, the consequence of thermal variations and, on the other hand, because of the fact that the pipes are inside of the concrete mortar and in direct contact with the reinforcing steel bars. For this reason, different types of specimens and testing procedures have been proposed to discuss the effects of temperature (20º, 40ºC, 70ºC y 100ºC) on the performance of two different hardened concrete: H-25 and H-30, and the effects of having the pipes embedded in different positions inside of specimens made of two types of concrete, H-25 and H-30, and with two kind of cast, cylindrical and cubical. The experimental program includes the use of compressive strength test and also pull-out test, in order to investigate the interfacial adhesion quality and interfacial properties between steel bar and concrete. The results of the mechanical test showed that the increase of temperature in hardened concrete specimens lower than 70ºC, and the introduction of embedded pipes placed in parallel to the load, in cylindrical or cubic specimens, does not jeopardize the mechanical properties of concrete with strength decreases higher than 20%.

Simulation of an Integrated Gasification Combined Cycle with Chemical-Looping Combustion and CO2 sequestration

Chemical-looping combustion allows an integration of CO2 capture in a thermal power plant without energy penalty; secondly, a less exergy destruction in the combustion chemical transformation is achieved, leading to a greater overall thermal efficiency. This paper focus on the study of the energetic performance of this concept of combustion in an integrated gasification combined cycle power plant when synthesis gas is used as fuel for the gas turbines. After thermodynamic modelling and optimization of some cycle parameters, the power plant performance is evaluated under diverse working conditions and compared to a conventional integrated gasification combined cycle with precombustion capture. Energy savings in CO2 capture and storage has been quantified. The overall efficiency increase is found to be significant and even notable, reaching values of around 7%. In order to analyze the influence of syngas composition on the results, different H2-content fuels are considered.

Analysis of thermo-mechanical stress effects on CPV receiver under high intensity light cycles

After construction of the LYSS (Light cYcling Stressing Source) in early 2014, several CPV receivers, with and without secondary optical element (SOE) have been aged under fast transient illumination cycling,. The test plan for Madrid consisted of 50000 cycles. Receivers with poor heat spreaders showed low reliability but those with thicker metal layers passed the test well. The operation of LYSS along 8 months, after more than 250000 cycles, did not show any significant failure, except lamp reposition every 120 hours, in average. The equipment seems valid for unveiling weak receiver designs with respect to intensive illumination, in steady and transient modes.