Rotation-Induced Breakdown of Torsional Quantum Control

Control of the torsional angles of nonrigid molecules is key for the development of emerging areas like molecular electronics and nanotechnology. Based on a rigorous calculation of the rotation-torsion-Stark energy levels of nonrigid biphenyl-like molecules, we show that, unlike previously believed, instantaneous rotation-torsion-Stark eigenstates of such molecules, interacting with a strong laser field, present a large degree of delocalization in the torsional coordinate even for the lowest energy states. This is due to a strong coupling between overall rotation and torsion leading to a breakdown of the torsional alignment. Thus, adiabatic control of changes on the planarity of this kind of molecule is essentially impossible unless the temperature is on the order of a few Kelvin.

Inelastic torsional seismic response of nominally symmetric reinforced concrete frame structures: shaking table tests

This paper discusses the torsional response of a scaled reinforced concrete frame structure subjected to several uniaxial shaking table tests. The tested structure is nominally symmetric in the direction of shaking and exhibits torsion attributable to non-uniform yielding of structural components and uncertainties in the building process. Asymmetric behavior is analyzed in terms of displacement, strain in reinforcing bars, energy dissipated at plastic hinges, and damage at section and frame levels. The results show that for low levels of seismic hazard, for which the structure is expected to perform basically within the elastic range, the accidental eccentricity is not a concern for the health of the structure, but it significantly increases the lateral displacement demand in the frames (about 30%) and this might cause significant damage to non-structural components. For high levels of seismic hazard the effects of accidental torsion become less important. These results underline the need to consider accidental eccentricity in evaluating the performance of a structure for very frequent or frequent earthquakes, and suggest that consideration of torsion may be neglected for performance levels associated with rare or very rare earthquakes.