The forced oscillations of submerged bodies

The increasing use of very light structures in aerospace applications are given rise to the need of taking into account the effects of the surrounding media in the motion of a structure (as for instance, in modal testing of solar panels or antennae) as it is usually performed in the motion of bodies submerged in water in marine applications. New methods are in development aiming at to determine rigid-body properties (the center of mass position and inertia properties) from the results of oscillations tests (at low frequencies during modal testing, by exciting the rigid-body modes only) by using the equations of the rigid-body dynamics. As it is shown in this paper, the effect of the surrounding media significantly modifies the oscillation dynamics in the case of light structures and therefore this effect should be taken into account in the development of the above-mentioned methods. The aim of the paper is to show that, if a central point exists for the aerodynamic forces acting on the body, the motion equations for the small amplitude rotational and translational oscillations can be expressed in a form which is a generalization of the motion equations for a body in vacuum, thus allowing to obtain a physical idea of the motion and aerodynamic effects and also significantly simplifying the calculation of the solutions and the interpretation of the results. In the formulation developed here the translational oscillations and the rotational motion around the center of mass are decoupled, as is the case for the rigid-body motion in vacuum, whereas in the classical added mass formulation the six motion equations are coupled. Also in this paper the nonsteady motion of small amplitude of a rigid body submerged in an ideal, incompressible fluid is considered in order to define the conditions for the existence of the central point in the case of a three-dimensional body. The results here presented are also of interest in marine applications.

Induced Damping on Vibrating Circular Plates Submerged in still Fluid

When a structure vibrates immersed in a fluid it is known that the dynamic properties of the system are modified. The surrounding fluid will, in general, contribute to the inertia, the rigidity and the damping coefficient of the coupled fluid-structure system. For light structures, like spacecraft antennas, even when the fluid is air the contribution to the dynamic properties can be important. For not so light structures the ratio of the equivalent fluid/structure mass and rigidity can be very small and the fluid contribution could be neglected. For the ratio of equivalent fluid/structure damping both terms are of the same order and therefore the fluid contribution must be studied. The working life of the spacecraft structure would be on space and so without any surrounding fluid. The response of a spacecraft structure on its operational life would be attenuated by the structural damping alone but when the structure is dynamically tested on the earth the dynamic modal test is performed with the fluid surrounding it. The results thus are contaminated by the effects of the fluid. If the damping added by the fluid is of the same order as the structural damping the response of the structure in space can be quite different to the response predicted on earth. It is therefore desirable to have a method able to determine the amount of damping induced by the fluid and that should be subtracted of the total damping measured on the modal vibration test. In this work, a method for the determination of the effect of the surrounding fluid on the dynamic characteristics of a circular plate has been developed. The plate is assumed to vibrate harmonically with the vacuum modes and the generalized forces matrix due to the fluid is thus computed. For a compressible fluid this matrix is formed by complex numbers including terms of inertia, rigidity and damping. The matrix due to the fluid loading is determined by a boundary element method (BEM). The BEM used is of circular rings on the plate surface so the number of elements to obtain an accurate result is very low. The natural frequencies of the system are computed by an iteration procedure one by one and also the damping fluid contribution. Comparisons of the present method with various experimental data and other theories show the efficiency and accuracy of the method for any support condition of the plate.

Coastal shapes. Geentic clasification 1973 - 2010

An analysis of a stretch of coastline shows multiple alterations through environmental climate actions. The narrow, fragile line displays singularities due to three basic causes. The first is the discontinuity in feed or localised loss of solid coastal material. Called massics, their simplest examples are deltas and undersea canyons. The second is due to a brusque change in the alignment of the shoreline’s edge, headlands, groins, harbour and defence works. Given the name of geometric singularities, their simplest uses are artificial beaches in the shelter of a straight groin or spits. The third is due to littoral dynamics, emerged or submerged obstacles which diffract and refract wave action, causing a change in the sea level’s super-elevation in breaker areas. Called dynamics, the simplest examples are salients, tombolos and shells. Discussion of the causes giving rise to variations in the coastline and formation of singularities is the raison d’être of investigation, using actual cases to check the suitability of the classification proposed, the tangential or differential action of waves on the coastal landscape in addition to possible simple, compound and complex shapes detected in nature, both in erosion and deposit processes

Ground maritime structure interaction. Recent failures in inner gravity constructions on the Spanish Coastline

A maritime construction is usually a slender line in the ocean.It is usual to see just its narrow surface strip and not analyse the large amount of submerged material the latter is supporting.Without doubt,it is the ground to which a notable load is transmitted in an environment subjected to periodic,alternating stresses,dynamic forces which the sea's media constitute. Both an outer and inner maritime construction works in a complex fashion.A granular solid(breakwater)breathes with the incident wave flow,dissipating part of the wave energy between its gaps.The backflow tries to extract the different items from the solid block,setting a balance between effective and neutral tensions that follow Terzaghui's principle. On some occasions,fluidification of the armour layer has caused the breakwater to collapse(Sines,Portugal,February 1978).On others,siphoning or liquefaction of sand supporting monoliths(vertical breakwaters)lead them to destruction or collapse(New Barcelona Harbour Mouth,Spain,November 2001). This is why the ground-force-structure interaction is a complicated analysis with joint design tools still in an incipient state. The purpose of this article is to describe two singular failures in inner maritime constructions in Spain deriving from ground problems(Malaga,July 2004and Barcelona,January 2007).They occurred recently and the causes are the subject of reflection and analysis.

Modelling and Simulation of Moored Devices for Ocean Currents Energy Harnessing

The main objective of this paper is the presentation of modelling solutions off loating devices that can be used for harnessing energy from ocean currents. It has been structured into three main parts. First, the growing current interest in marine renewable energy in general, and in extracting energy from currents in particular, is presented, showing the large number of solutions that are emerging and some of the most significant types. GESMEY generator is presented in second section. It is based on a new concept that has been patented by the Universidad Politécnica de Madrid and which is currently being developed through a collaborative agreement with the SOERMAR Foundation. The main feature of this generator is that on operation is fully submerged, and no other facilities are required to move to floating state for maintenance, which greatly increases its performance. Third part of the article is devoted to present the modelling and simulation challenges that arise in the development of devices for harnessing the energy of marine currents, along with some solutions which have been adopted within the frame of the GESMEY Project, making particular emphasis on the dynamics of the generator and its control

Optimización de la succión de sólidos sumergidos utilizando bombas centrífugas con velocidad variable

La acumulación de material sólido en embalses, cauces fluviales y en zonas marítimas hace que la extracción mecánica de estos materiales por medio de succión sea cada vez mas frecuente, por ello resulta importante estudiar el rendimiento de la succión de estos materiales analizando la forma de las boquillas y los parámetros del flujo incluyendo la bomba. Esta tesis estudia, mediante equipos experimentales, la eficacia de distintos dispositivos de extracción de sólidos (utilizando boquillas de diversas formas y bombas de velocidad variable). El dispositivo experimental ha sido desarrollado en el Laboratorio de Hidráulica de la E.T.S.I. de Caminos, C. y P. de la Universidad Politécnica de Madrid. Dicho dispositivo experimental incluye un lecho sumergido de distintos tipos de sedimentos, boquillas de extracción de sólidos y bomba de velocidad variable, así como un elemento de separación del agua y los sólidos extraídos. Los parámetros básicos analizados son el caudal líquido total bombeado, el caudal sólido extraído, diámetro de la tubería de succión, forma y sección de la boquilla extractora, así como los parámetros de velocidad y rendimiento en la bomba de velocidad variable. Los resultados de las medidas obtenidas en el dispositivo experimental han sido estudiados por medio del análisis dimensional y con métodos estadísticos. A partir de este estudio se ha desarrollado una nueva formulación, que relaciona el caudal sólido extraído con los diámetros de tubería y boquilla, caudal líquido bombeado y velocidad de giro de la bomba. Así mismo, desde el punto de vista práctico, se han analizado la influencia de la forma de la boquilla con la capacidad de extracción de sólidos a igualdad del resto de los parámetros, de forma que se puedan recomendar que forma de la boquilla es la más apropiada. The accumulation of solid material in reservoirs, river channels and sea areas causes the mechanical extraction of these materials by suction is becoming much more common, so it is important to study the performance of the suction of these materials analyzing the shape of the nozzles and flow parameters, including the pump. This thesis studies, using experimental equipment, the effectiveness of different solids removal devices (using nozzles of different shapes and variable speed pumps). The experimental device was developed at the Hydraulics Laboratory of the Civil University of the Polytechnic University of Madrid. The device included a submerged bed with different types of sediment solids, different removal nozzles and variable speed pump. It also includes a water separation element and the solids extracted. The key parameters analyzed are the total liquid volume pumped, the solid volume extracted, diameter of the suction pipe, a section of the nozzle and hood, and the parameters of speed and efficiency of the variable speed pump. The basic parameters analyzed are the total liquid volume pumped, the removed solid volume, the diameter of the suction pipe, the shape and cross-section of the nozzle, and the parameters of speed, efficiency and energy consumed by the variable speed pump. The measurements obtained on the experimental device have been studied with dimensional analysis and statistical methods. The outcome of this study is a new formulation, which relates the solid volume extracted with the pipe and nozzle diameters, the pumped liquid flow and the speed of the pump. Also, from a practical point of view, the influence of the shape of the nozzle was compared with the solid extraction capacity, keeping equal the rest of the parameters. So, a recommendation of the best shape of the nozzle can be given.

Desarrollo y caracterización de un material celular de alta porosidad con base cementicia activada mediante agentes inorgánicos

Esta tesis ha estudiado los morteros celulares, centrándose en la experimentación con pastas de cemento aireadas (PCA) con polvo de aluminio como agente expansor. El objetivo es el desarrollo de un material cementicio con una baja conductividad térmica que sirva como aislamiento térmico. La naturaleza inorgánica del material lo hace incombustible, en contraste con las espumas poliméricas existentes en el mercado, cuya aplicación en cámaras ventiladas ha sido prohibida por normativas de construcción tanto a nivel nacional como internacional. Las posibles aplicaciones son con proyección neumática o en paneles prefabricados. Se han ensayado dos series de pastas de cemento con polvo de aluminio: - Serie WPC/CAC/CH. Mezcla de referencia con cemento blanco (WPC), cemento de aluminato cálcico (CAC) y cal aérea (CH) en proporción 5:1:4. - Serie OPC/CH. Mezcla de referencia con cemento portland con cenizas volantes (OPC) y cal aérea (CH) en proporción OPC/CH de 4:1 A las mezclas de referencia se le han añadido adiciones de metacaolín (MK) (10 y 20%) o sepiolita (SP) (1 y 2%) para observar el efecto que producen tanto en el mortero fresco como en el mortero endurecido. Se ha estudiado la reología de las pastas en estado fresco, analizando el proceso de expansión de las pastas, registrando los valores de tensión de fluencia, aire ocluido y temperatura durante la expansión. Con los valores obtenidos se ha discutido la influencia de las adiciones utilizadas en la cinética de corrosión del polvo de aluminio que genera la expansión, concluyendo que las adiciones puzolánicas (CV y MK) y la SP reducen mucho el periodo de inducción, lo que provoca poros más grandes y mayor cantidad de aire ocluido. Asimismo se ha analizado la relación entre la tensión de fluencia y el contenido de aire ocluido, deduciendo que a mayor tensión de fluencia en el momento de iniciarse la expansión, menor tamaño de poros y contenido de aire ocluido. Finalmente, se han obtenido las densidades y capacidades de retención de agua de los morteros frescos. Para caracterizar la red porosa de las pastas aireadas endurecidas, se obtuvieron tanto las densidades reales, netas, aparentes y relativas como las porosidades abiertas, cerradas y totales con ensayos hídricos. Finalmente se obtuvieron imágenes de los poros con tomografía axial computerizada para obtener las porosimetrías de las muestras. La caracterización de la red porosa ha servido para terminar de analizar lo observado en la evolución de la expansión del mortero fresco. Se ha analizado la influencia de la red porosa en la conductividad térmica, obtenida con caja caliente, comparándola con la existente en la literatura existente tanto de morteros celulares como de espumas poliméricas. Se concluye que los valores de conductividad térmica conseguida están en el mínimo posible para un material celular de base cementicia. La microestructura se ha estudiado con microscopía electrónica de barrido, difracción de rayos X y ensayos térmicos TG/ATD, observando que los productos de hidratación encontrados coinciden con los que se producen en morteros sin airear. Las imágenes SEM y los resultados de ultrasonidos han servido para analizar la presencia de microfisuras de retracción en las pastas aireadas, observando que en las muestras con adiciones de MK y SP, se reduce la presencia de microfisuras. ABSTRACT This thesis has studied cellular mortars, focusing in testing aerated cement pastes with aluminum powder as expansive agent. The purpose is the development of a cementitious material with low thermal conductivity that can be used as thermal isolation. Inorganic nature of this material makes it non-combustible, in contrast with polymeric foams in market, whose application in ventilated double skin façade systems has been banned by building standards, both domestically and internationally. Possible uses for this material are pneumatically sprayed applications and precast panels. Two series of batches with aluminum powder have been tested: - WPC/CAC/CH series. Reference paste with white portland cement (WPC), calcium aluminate cement (CAC) and lime (CH) with 5:1:4 ratio. - OPC/CH series. Reference paste with portland cement with fly ash (OPC) and lime (CH) with 4:1 ratio. Metakaolin (MK) (10 and 20%) or sepiolite (SP) (1 and 2%) additions were used in reference pastes to characterize the effect in fresh and hardened mortar. Rheology in fresh pastes was studied, expansion process of pastes was analyzed, recording yield stress, entrained air and temperature values during expansion. Recorded values were used to discuss influence of additions on reaction kinetics of aluminum powder corrosion, that produces expansion.. Conclusion is that pozzolanic additions (FA and MK) and SP greatly reduce induction period, producing bigger pores and more entrained air. Relation between yield stress and entrained air has been also analyzed, observing that the bigger yield stress at beginning of expansion, the smaller pores size and the lower entrained air values. Finally density and water retention of fresh mortars were obtained. Pore network in hardened aerated cement pastes was characterized by imbibition methods providing true, bulk and relative density, and providing also open, closed and total porosity. Finally, pore system imaging were obtained with computerized axial tomography to study porosimetry of specimens. Pore network characterization was useful to complete facts analysis observed in expansion of fresh mortars. Influence of pore network in thermal conductivity, checked in hot box, was analyzed comparing with those existing values in cellular mortar and polymeric foams researches. It was concluded that thermal conductivity values achieved are close to minimum possible in a cementitious cellular material. Microstructure was studied with Scanning Electron Microscopy, X-Ray Diffractometry and TG-DTA analysis, observing that hydration phases found, are those produced in non aerated mortar. SEM imaging and ultrasound results were useful to analyze shrinkage microcracks in aerated cement pastes, concluding that microcrack presence in specimens with MK and SP additions were reduced.

The influence of sulfuric environments on concretes elaborated with sulfate resistant cements and mineral admixtures. Part 1: Concrete exposed to Sodium Sulfate (Na2SO4) = Estudio de la influencia de los medios con presencia de sulfatos en hormigones con cementos sulforresistentes y adiciones minerales. Parte 1: Hormigones expuestos a sulfato sódico (Na2SO4)

The study of sulfate attack in concrete is considered vital for the preservation of the structural integrity of constructions. Its aggressive behaviour causes degradation of the cement matrix which changes the initial properties of the material. In this article, the sulfate resistance of concrete is studied. To that goal, four different concrete mixes were made with sulphur resistant cement. The concretes were tested for compressive strength, transport capacity of sulfates and microstructural properties. An experimental program was proposed in which the concrete samples were submerged in sodium sulphate (Na2SO4) solution. The obtained results were compared with reference values of concretes cured in calcium hydroxide [Ca(OH)2]. According to the results the concrete with ground granulated blast-furnace slag presented the best behavior when exposed to sodium sulphate (Na2SO4) solution. El estudio del ataque de sulfatos en el hormigón se considera de gran importancia para la conservación de la integridad estructural de las construcciones. Su agresividad se basa en la degradación de la matriz cementicia modificando las características iniciales de diseño. En el presente trabajo se estudia la resistencia del hormigón al ataque de sulfatos provenientes de sulfato sódico (Na2SO4). Para llevar a cabo la investigación se diseñaron cuatro dosificaciones de hormigón empleando cementos sulforresistentes y adiciones minerales. Se llevó a cabo una propuesta experimental donde las muestras de hormigón se sumergieron en disolución de sulfato sódico (Na2SO4) de concentración 1M. Posteriormente se realizaron ensayos de resistencia mecánica, capacidad de transporte de sulfatos y propiedades microestructurales, a distintas edades. Los resultados obtenidos se compararon con valores de referencia de mezclas de hormigón curadas expuestas a hi-dróxido cálcico [Ca(OH)2]. De acuerdo a los resultados obtenidos, el hormigón con escoria de alto horno presentó las mejores características de durabilidad frente a sulfatos provenientes de sulfato sódico

The influence of sulfuric environments on concretes elaborated with sulfate resistant cements and mineral admixtures. Part 2: Concrete exposed to Magnesium Sulfate (MgSO4) = Estudio de la influencia de los medios con presencia de sulfatos en hormigones con cementos sulforresistentes y adiciones minerales. Parte 2.Hormigones expuestos a sulfato magnésico (MgSO4)

The present work studies the resistant of the concrete against magnesium sulfate (MgSO4) and compare the results with values obtained previously of the same concretes exposed to sodium sulfate (Na2SO4). Thus, it is possible analyze the influence of the cation type. To that end, four different concrete mixes were made with sulfur resistant cement and mineral admixtures (silica fume, fly ash and blast furnace slag). The concretes were submerged for different period in magnesium sulfate (MgSO4). After that, different tests were carried out to define mechanical and microstructural properties. The results obtained were compared with reference values of concretes cured in calcium hydroxide [Ca(OH)2]. According to the results, the concrete with blast furnace slag presented the best behavior front MgSO4, meanwhile the concretes with silica fume and fly ash were the most susceptible. The resistance of the concrete with blast furnace slag could be attributed to the characteristics of the hydrated silicates formed during the hydration time, which include aluminum in the chemical chain that hinder its chemical decomposition during the attack of magnesium. The magnesium sulfate solution was most aggressive than sodium sulfate solution. El presente trabajo estudia la resistencia de hormigones al ataque de sulfatos provenientes de sulfato magnésico (MgSO4) y compara estos valores con resultados previos de los mismos hormigones atacados con sulfato sódico (Na2SO4). De esta manera se estudia la interacción del catión que acompaña al ion sulfato durante su afectación a la matriz cementicia. Para lo anterior, se diseñaron cuatro dosificaciones empleando cementos sulforresistentes y adiciones minerales (humo de sílice, ceniza volante y escoria de alto horno). Los hormigones se sumergieron, por distintos periodos de tiempo, en disolución de sulfato magnésico (MgSO4) de concentración 1M, para después realizarles ensayos mecánicos y a nivel microestructural. Los valores obtenidos se compararon con los obtenidos en el hormigón de referencia curado en hidróxido cálcico. El hormigón con escoria de alto horno presentó el mejor comportamiento frente a MgSO4, siendo las mezclas de humo de sílice y ceniza volante las más susceptibles. La resistencia del hormigón con escoria se atribuye a las características de los silicatos hidratados formados durante la hidratación, los cuales incorporan aluminio en las cadenas impidiendo su descomposición ante un ataque por magnesio. El medio con sulfato magnésico mostro una mayor agresividad que el medio con sulfato sódico.

Advanced characterization of a coffee fermenting tank by multi-distributed wireless sensors: spatial interpolation and phase diagrams.

In coffee processing the fermentation stage is considered one of the critical operations by its impact on the final quality of the product. However, the level of control of the fermentation process on each farm is often not adequate; the use of sensorics for controlling coffee fermentation is not common. The objective of this work is to characterize the fermentation temperature in a fermentation tank by applying spatial interpolation and a new methodology of data analysis based on phase space diagrams of temperature data, collected by means of multi-distributed, low cost and autonomous wireless sensors. A real coffee fermentation was supervised in the Cauca region (Colombia) with a network of 24 semi-passive TurboTag RFID temperature loggers with vacuum plastic cover, submerged directly in the fermenting mass. Temporal evolution and spatial distribution of temperature is described in terms of the phase diagram areas which characterizes the cyclic behaviour of temperature and highlights the significant heterogeneity of thermal conditions at different locations in the tank where the average temperature of the fermentation was 21.2 °C, although there were temperature ranges of 4.6°C, and average spatial standard deviation of ±1.21ºC. In the upper part of the tank we found high heterogeneity of temperatures, the higher temperatures and therefore the higher fermentation rates. While at the bottom, it has been computed an area in the phase diagram practically half of the area occupied by the sensors of the upper tank, therefore this location showed higher temperature homogeneity

Advanced Characterisation of a Coffee Fermenting Tank by Multi-distributed Wireless Sensors: Spatial Interpolation and Phase Space Graphs

The fermentation stage is considered to be one of the critical steps in coffee processing due to its impact on the final quality of the product. The objective of this work is to characterise the temperature gradients in a fermentation tank by multi-distributed, low-cost and autonomous wireless sensors (23 semi-passive TurboTag® radio-frequency identifier (RFID) temperature loggers). Spatial interpolation in polar coordinates and an innovative methodology based on phase space diagrams are used. A real coffee fermentation process was supervised in the Cauca region (Colombia) with sensors submerged directly in the fermenting mass, leading to a 4.6 °C temperature range within the fermentation process. Spatial interpolation shows a maximum instant radial temperature gradient of 0.1 °C/cm from the centre to the perimeter of the tank and a vertical temperature gradient of 0.25 °C/cm for sensors with equal polar coordinates. The combination of spatial interpolation and phase space graphs consistently enables the identification of five local behaviours during fermentation (hot and cold spots).

Pattern formation of parametrically driven surface waves induced by vibration

Esta tesis se centra en la generación de ondas superficiales subarmónicas en fluidos sometidos a vibración forzada en el régimen gravitatorio capilar con líquidos de baja viscosidad. Tres problemas diferentes han sido estudiados: un contenedor rectangular con vibración horizontal, la misma geometría pero con una combinación de vibración vertical y horizontal y un obstáculo completamente sumergido vibrado verticalmente en un contenedor grande. Se deriva una ecuación de amplitud desde primeros principios para describir las ondas subarmónicas con forzamiento parámetrico inducido por la vibración. La ecuación es bidimensional mientras que el problema original es tridimensional y admite un forzamiento espacial no uniforme. Usando esta ecuación los tres sistemas han sido analizados, centrándose en calcular la amplitud crítica, la orientación de los patrones y el carácter temporal de los patrones espaciotemporales, que pueden ser estrictamente subarmónicos o cuasiperiodicos con una frecuencia de modulación temporal. La dependencia con los parámetros adimensionales también se considera. La teoría será comparada con los experimentos disponibles en la literatura. Abstract This thesis focus on the generation of subharmonic surface waves on fluids subject to forced vibration in the gravity-capillary regime with liquids of small viscosity. Three different problems have been considered: a rectangular container under horizontal vibration; the same geometry but under a combination of horizontal and vertical vibration; and a fully submerged vertically vibrated obstacle in a large container. An amplitude equation is derived from first principles that fairly precisely describes the subharmonic surfaces waves parametrically driven by vibration. That equation is two dimensional while the underlying problem is three-dimensional and permits spatially nonuniform forcing. Using this equation, the three systems have been analyzed, focusing on the calculation of the threshold amplitude, the pattern orientation, and the temporal character of the spatio-temporal patterns, which can be either strictly subharmonic or quasi-periodic, showing an additional modulation frequency. Dependence on the non-dimensional parameters is also considered. The theory is compared with the experiments available in the literature.

Selectively filled photonic liquid crystal fibers = Fibras de cristal fotónico selectivamente llenas con cristal líquido

El presente trabajo de Tesis se ha centrado en el diseño, fabricación y caracterización de dispositivos basados en fibras de cristal fotónico infiltrado selectivamente con cristales líquidos, polímeros y una mezcla de ambos. Todos los dispositivos son sintonizables, y su área de aplicación se centra en comunicaciones ópticas y sensores. La manipulación y fusionado de fibras fotónicas, el llenado selectivo de determinadas cavidades y la alineación recíproca de fibras mantenedoras de polarización son tareas muy específicas y delicadas para las que se requieren protocolos muy estrictos. Previo a la fabricación de dispositivos ha sido necesaria por tanto una tarea de sistematización y creación de protocolos de fabricación. Una vez establecidos se ha procedido a la fabricación y caracterización de dispositivos. Los dispositivos fabricados se enumeran a continuación para posteriormente detallar una a una las singularidades de cada uno. • Interferómetros intermodales hechos a partir de una porción de fibra fotónica soldada entre dos fibras estándar, bien monomodo o PANDA (mantenedora de polarización). Estos interferómetros han sido sumergidos o bien llenados selectivamente con cristales líquidos para así sintonizar la señal interferométrica guiada a través de la fibra. • Infiltración de fibras fotónicas con cristales líquidos colestéricos con especial énfasis en la fase azul (blue phase) de estos materiales. Las moléculas de cristal líquido se autoalinean en volumen por lo que la infiltración de fibras fotónicas con estos cristales líquidos es muy interesante, pues es conocida la dificultad de alinear apropiadamente cristales líquidos dentro de cavidades micrométricas de las fibras fotónicas. • Grabación de redes holográficas de forma selectiva en las cavidades de una fibra fotónica. Estas redes holográficas, llamadas POLICRYPS (POlymer-LIquid CRYstal-Polymer Slices), son redes fabricadas a base de franjas de polímero y cristal líquido alineado perpendicularmente a dichas franjas. Las franjas son a su vez perpendiculares al eje de la fibra como lo puede ser una red de Bragg convencional. El cristal líquido, al estar alineado perpendicularmente a dichos franjas y paralelo al eje de la fibra, se puede conmutar aplicando un campo eléctrico externo, modificando así el índice efectivo de la red. Se puede fabricar por lo tanto una red de Bragg sintonizable en fibra, muy útil en comunicaciones ópticas. • Llenado selectivo de fibras fotónicas con polidimetilsiloxano (PDMS), un polímero de tipo silicona. Si se realiza un llenado selectivo asimétrico se puede inducir birrefringencia en la fibra. El índice de refracción del PDMS tiene una fuerte dependencia térmica, por lo que se puede sintonizar la birrefringencia de la fibra. • Estudio teórico de llenado selectivo de fibras fotónicas con PDMS dopado con nanopartículas de plata de 5, 40 y 80 nm. Estas nanopartículas poseen un pico de absorción en torno a los 450 nm debido a resonancias superficiales localizadas de plasmones (LSPR). La resonancia del plasmon tiene una fuerte dependencia con el índice de refracción del material colindante, y al ser éste PDMS, la variación de índice de refracción se ve amplificada, obteniendo una absorción sintonizable. Se ha propuesto la fabricación de polarizadores sintonizables usando esta técnica. Como ya se ha dicho, previamente a la fabricación ha sido necesaria la protocolización de diversos procedimientos de fabricación de alta complejidad, así como protocolizar el proceso de toma de medidas para optimizar los resultados. Los procedimientos que han requerido la formulación de protocolos específicos han sido los siguientes: • Llenado selectivo de cavidades en una fibra fotónica. Dichas fibras tienen generalmente un diámetro externo de 125 μm, y sus cavidades son de entre 5 y 10 μm de diámetro. Se han desarrollado tres técnicas diferentes para el llenado/bloqueado selectivo, pudiéndose combinar varios protocolos para la optimización del proceso. Las técnicas son las siguientes: o Llenado y bloqueado con un prepolímero. Dicho prepolímero, también llamado adhesivo óptico, está inicialmente en estado líquido y posee una cierta viscosidad. Las cavidades de la fibra fotónica que se desea llenar o bloquear poseen un diámetro diferente al resto, por lo que en el proceso de llenado aparecen dos frentes de llenado dependientes de su diámetro. A mayor diámetro, mayor velocidad de llenado. Polimerizando cuando existe dicha diferencia en los frentes se puede cortar por medio, obteniendo así una fibra parcialmente bloqueada. o Colapsamiento de las cavidades de menor diámetro mediante aplicación de calor. El calor producido por un arco voltaico de una soldadora de fibra estándar fusiona el material exterior de la fibra produciendo el colapsamiento de las cavidades de menor diámetro. En esta técnica también es necesaria una diferencia de diámetros en las cavidades de la fibra. o Bloqueo una a una de las cavidades de la fibra fotónica con adhesivo óptico. Este procedimiento es muy laborioso y requiere mucha precisión. Con este sistema se pueden bloquear las cavidades deseadas de una fibra sin importar su diámetro. • Alineación de una fuente de luz linealmente polarizada con una fibra mantenedora de polarización ya sea PANDA o fotónica. Así mismo también se han alineado entre sí fibras mantenedoras de polarización, para que sus ejes rápidos se fusionen paralelos y así el estado de polarización de la luz guiada se mantenga. • Sistematización de toma de medidas para caracterizar los interferómetros modales. Éstos son altamente sensibles a diversas variables por lo que el proceso de medida es complejo. Se deben aislar variables de forma estrictamente controlada. Aunque todos los dispositivos tienen en común el llenado selectivo de cavidades en una fibra fotónica cada dispositivo tiene sus peculiaridades, que van a ser explicadas a continuación. ABSTRACT The present Thesis has been centered in the design, fabrication and characterization of devices based on photonic crystal fibers selectively filled with liquid crystals, polymers and a mixture of both. All devices are tunable and their work field is optical communications and sensing The handling and splicing of photonic crystal fibers, the selective filling of their holes and the aligning of polarization maintaining fibers are very specific and delicate tasks for which very strict protocols are required. Before the fabrication of devices has therefore been necessary task systematization and creation of manufacturing protocols. Once established we have proceeded to the fabrication and characterization of devices. The fabricated devices are listed below and their peculiarities are detailed one by one: • Intermodal interferometers made with a portion of photonic crystal fiber spliced between two optical communication fiber pigtails, either single mode or PANDA (polarization-maintaining) fiber. These interferometers have been submerged or selectively filled with liquid crystals to tune the interferometric guided signal. • Infiltration of photonic fibers with cholesteric liquid crystals with special emphasis on their blue phase (blue phase). The liquid crystal molecules are self-aligning in volume so the infiltration of photonic fibers with these liquid crystals is very interesting. It is notoriously difficult to properly align liquid crystals within micron cavities such as photonic fibers. • Selectively recording of holographic gratings in the holes of photonic crystal fibers. These holographic gratings, called POLICRYPS (POlymer-LIquid CRYstal-Polymes Slices), are based on walls made of polymer and liquid crystal aligned perpendicular to them. These walls are perpendicular to the axis of the fiber as it can be a conventional Bragg grating. The liquid crystal is aligned perpendicular to the walls and parallel to the fiber axis, and can be switched by applying an external electric field and thus change the effective index of the grating. It is thus possible to manufacture a tunable Bragg grating fiber, useful in optical communications. •Asymmetrically selective filling of photonic crystal fibers with a silicone polymer like called polydimethylsiloxane (PDMS) to induce birefringence in the fiber. The refractive index of PDMS has temperature dependence, so that the birefringence of the fiber can be tuned. • Theoretical study of photonic crystal fibers selectively filled with PDMS doped with silver nanoparticles of 5, 40 and 80 nm. These nanoparticles have an absorption peak around 450 nm due to localized surface plasmon resonances (LSPR). Plasmon resonance has a strong dependence on the refractive index of the adjacent material, and as this is PDMS, the refractive index variation is amplified, obtaining a tunable absorption. Fabrication of tunable polarizers using this technique has been proposed. Before starting the fabrication, it has been necessary to optimize several very delicate procedures and different protocols have been designed. The most delicate procedures are as follows: • Selective filling of holes in a photonic crystal fiber. These fibers generally have an outer diameter of 125 μm, and their holes have a diameter around between 5 and 10 μm. It has been developed three different techniques for filling / selective blocking, and they can be combined for process optimization. The techniques are: o Filling and blocked with a prepolymer. This prepolymer also called optical adhesive is initially in liquid state and has a certain viscosity. The holes of the photonic crystal fiber that are desired to be filled or blocked should have a different diameter, so that in the filling process appear two different fronts depending on the hole diameter. The holes with larger diameter are filled faster. Then the adhesive is polymerized when there is such a difference on the front. A partially blocked fiber is obtained cutting between fronts. o Collapsing of holes of smaller diameter by application of heat. The heat produced by an arc of a standard fusion splicer fuses the outer fiber material producing the collapsing of the cavities of smaller diameter. In this technique also you need a difference of diameters in the fiber holes. o Blocking one by one the holes of photonic crystal fiber with optical adhesive. This procedure is very laborious and requires great precision. This system can block unwanted cavities regardless fiber diameter. • Aligning a linearly polarized light source with a polarization-maintaining fiber (either a PANDA fiber as a photonic crystal fiber). It is needed also an aligning between polarization-maintaining fibers, so that their fast axes parallel merge and that is state of polarization of light guided is maintained. • Systematization of taking measurements to characterize the modal interferometers. These are highly sensitive to several variables so the measurement process is very complicated. Variables must be fixed in a very controlled manner. Although all devices have the common characteristic of being selectively filled PCFs with some kind of material, each one has his own peculiarities, which are explained below.

Perfil de playas sustentadas : estudio hidrodinámico y experimental : directrices de diseño

Las playas sustentadas por medio de un pie sumergido son una atractiva alternativa de diseño de regeneración de playas especialmente cuando las condiciones física del emplazamiento o las características de la arena nativa y de préstamo producen perfiles de alimentación que no se intersectan. La observación y propuesta de este tipo de solución data de los años 1960’s, así como la experiencia internacional en la construcción de este tipo de playas. Sin embargo, a pesar de su utilización y los estudios en campo y laboratorio, no se dispone de criterios ingenieriles que apoyen el diseño de las mismas. Esta tesis consiste en un análisis experimental del perfil de playas sustentadas en un pie sumergido (o colgadas) que se concreta en una propuesta de directrices de diseño general que permiten estimar la ubicación y características geométricas del pie sumergido frente a un oleaje y material que constituye la playa determinados. En la tesis se describe el experimento bidimensional realizado en el modelo físico de fondo móvil, donde se combinan cinco tipos de oleaje con tres configuraciones del pie sumergido (“Sin estructura”, configuración baja o “Estructura 1” y configuración alta o “Estructura 2”), se presentan los resultados obtenidos y se realiza una discusión detallada de las implicaciones de los resultados desde el punto de vista hidrodinámico utilizando monomios adimensionales. Se ha realizado un análisis detallado del estado del arte sobre playas colgadas, presentando el concepto y las experiencias de realizaciones en distintos países. Se ha realizado una cuidadosa revisión de la literatura publicada sobre estudios experimentales de playas colgadas, modelos teóricos y otras cuestiones auxiliares, necesarias para la formulación de la metodología de la tesis. El estudio realizado se ha estructurado en dos fases. En la primera fase se ha realizado una experimentación en un modelo físico de fondo móvil construido en las instalaciones del Centro de Estudios de Puertos y Costas (CEPYC) del Centro de Estudios y Experimentación de Obras Públicas (CEDEX), consistente en un canal de 36 m de longitud, 3 m de anchura y 1.5 m de altura, provisto de un generador de oleaje de tipo pistón. Se ha diseñado una campaña de 15 ensayos, que se obtienen sometiendo a cinco tipos de oleaje tres configuraciones distintas de playa colgada. En los ensayos se ha medido el perfil de playa en distintos instantes hasta llegar al equilibrio, determinando a partir de esos datos el retroceso de la línea de costa y el volumen de sedimentos perdido. El tiempo total efectivo de ensayo asciende a casi 650 horas, y el número de perfiles de evolución de playa obtenidos totaliza 229. En la segunda fase se ha abordado el análisis de los resultados obtenidos con la finalidad de comprender el fenómeno, identificar las variables de las que depende y proponer unas directrices ingenieriles de diseño. Se ha estudiado el efecto de la altura de ola, del periodo del oleaje, del francobordo adimensional y del parámetro de Dean, constatándose la dificultad de comprensión del funcionamiento de estas obras ya que pueden ser beneficiosas, perjudiciales o inocuas según los casos. También se ha estudiado la respuesta del perfil de playa en función de otros monomios adimensionales, tales como el número de Reynolds o el de Froude. En el análisis se ha elegido el monomio “plunger” como el más significativo, encontrando relaciones de éste con el peralte de oleaje, la anchura de coronación adimensional, la altura del pie de playa adimensional y el parámetro de Dean. Finalmente, se propone un método de diseño de cuatro pasos que permite realizar un primer encaje del diseño funcional de la playa sustentada frente a un oleaje de características determinadas. Las contribuciones más significativas desde el punto de vista científico son: - La obtención del juego de resultados experimentales. - La caracterización del comportamiento de las playas sustentadas. - Las relaciones propuestas entre el monomio plunger y las distintas variables explicativas seleccionadas, que permiten predecir el comportamiento de la obra. - El método de diseño propuesto, en cuatro pasos, para este tipo de esquemas de defensa de costas. Perched beaches are an attractive beach nourishment design alternative especially when either the site conditions or the characteristics of both the native and the borrow sand lead to a non-intersecting profile The observation and suggestion of the use of this type of coastal defence scheme dates back to the 1960’s, as well as the international experience in the construction of this type of beaches. However, in spite of its use and the field and laboratory studies performed to-date, no design engineering guidance is available to support its design. This dissertation is based on the experimental work performed on a movable bed physical model and the use of dimensionless parameters in analyzing the results to provide general functional design guidance that allow the designer, at a particular stretch of coast - to estimate the location and geometric characteristics of the submerged sill as well as to estimate the suitable sand size to be used in the nourishment. This dissertation consists on an experimental analysis of perched beaches by means of a submerged sill, leading to the proposal of general design guidance that allows to estimate the location and geometric characteristics of the submerged sill when facing a wave condition and for a given beach material. The experimental work performed on a bi-dimensional movable bed physical model, where five types of wave conditions are combined with three configurations of the submerged sill (“No structure”, low structure or “Structure 1”, and high structure or “Structure 2”) is described, results are presented, and a detailed discussion of the results - from the hydrodynamic point of view – of the implications of the results by using dimensionless parameters is carried out. A detailed state of the art analysis about perched beaches has been performed, presenting the “perched beach concept” and the case studies of different countries. Besides, a careful revision of the literature about experimental studies on perched beaches, theoretical models, and other topics deemed necessary to formulate the methodology of this work has been completed. The study has been divided into two phases. Within the first phase, experiments on a movable-bed physical model have been developed. The physical model has been built in the Centro de Estudios de Puertos y Costas (CEPYC) facilities, Centro de Estudios y Experimentación de Obras Públicas (CEDEX). The wave flume is 36 m long, 3 m wide and 1.5 m high, and has a piston-type regular wave generator available. The test plan consisted of 15 tests resulting from five wave conditions attacking three different configurations of the perched beach. During the development of the tests, the beach profile has been surveyed at different intervals until equilibrium has been reached according to these measurements. Retreat of the shoreline and relative loss of sediment in volume have been obtained from the measurements. The total effective test time reaches nearly 650 hours, whereas the total number of beach evolution profiles measured amounts to 229. On the second phase, attention is focused on the analysis of results with the aim of understanding the phenomenon, identifying the governing variables and proposing engineering design guidelines. The effect of the wave height, the wave period, the dimensionless freeboard and of the Dean parameter have been analyzed. It has been pointed out the difficulty in understanding the way perched beaches work since they turned out to be beneficial, neutral or harmful according to wave conditions and structure configuration. Besides, the beach profile response as a function of other dimensionless parameters, such as Reynolds number or Froude number, has been studied. In this analysis, the “plunger” parameter has been selected as the most representative, and relationships between the plunger parameter and the wave steepness, the dimensionless crest width, the dimensionless crest height, and the Dean parameter have been identified. Finally, an engineering 4-step design method has been proposed, that allows for the preliminary functional design of the perched beach for a given wave condition. The most relevant contributions from the scientific point of view have been: - The acquisition of a consistent set of experimental results. - The characterization of the behavior of perched beaches. - The proposed relationships between the plunger parameter and the different explanatory variables selected, that allow for the prediction of the beach behavior. - The proposed design method, four-step method, for this type of coastal defense schemes.

Corrosión de armaduras en el hormigón armado en ambiente marino aéreo

La presente tesis doctoral surge ante la necesidad de completar el estudio sobre la corrosión en el hormigón armado expuesto al ambiente marino iniciado por D. Miguel Ángel Bermúdez Odriozola en 2007 con la tesis doctoral con título “Corrosión de las armaduras del hormigón armado en ambiente marino: zona de carrera de mareas y zona sumergida”. Una vez realizado el estudio bibliográfico, se ha planteado un estudio experimental en el que se analizan cuatro muelles de distintas edades y localizados en distintos lugares de la geografía española. Uno de ellos contiene adiciones en el hormigón. Una vez inspeccionados, se extraen testigos de cada uno de ellos con el fin de realizar ensayos de caracterización y se analizan sus resultados en paralelo con los coeficientes de difusión. Uno se los objetivos ha sido comprobar el mejor método de ensayo que permita controlar la durabilidad del hormigón en ambiente IIIa. La tesis que se presenta ha demostrado la efectividad del ensayo de penetración de agua para discriminar los hormigones que presentarán un buen comportamiento frente a la difusión de cloruros y por tanto para predecir la vida útil de la estructura. Asimismo, otro objetivo ha sido valorar el uso de adiciones en el hormigón y cómo afectan a la mejora del comportamiento del hormigón expuesto al ambiente marino. Se han obtenido valores del coeficiente de eficacia de cenizas volantes y humo de sílice frente a la difusión de cloruros, muy superiores a los actualmente considerados en términos de resistencia. El ambiente marino aéreo engloba estructuras situadas en primera línea de costa así como aquellas que se sitúan hasta 5km de distancia de la línea del mar. La investigación realizada ha demostrado la necesidad de establecer una nueva subdivisión en este ambiente introduciendo la zona Spray, siguiendo criterios internacionales, que permita diferenciar la zona más desfavorable del mismo que comprende las estructuras ubicadas sobre el nivel del mar tal como los tableros de pantalanes portuarios estudiados. Se han analizado en profundidad los valores del contenido de cloruros en superficie de hormigón en los diferentes tipos de ambiente marino recogidos por la Instrucción EHE- 08 contrastando los requisitos normativos. Como conclusión se han hecho nuevas propuestas normativas que afectan al ambiente sumergido y al ambiente marino aéreo (zona spray). Asimismo se ha realizado un análisis en profundidad de la concentración crítica de cloruros recogida por la Instrucción EHE-08, a partir de los datos obtenidos en estructuras reales. Se ha evaluado el ensayo de resistividad para estimar el valor del coeficiente de difusión de cloruros. Este ensayo ha demostrado su efectividad para discriminar hormigones con adiciones y con muy baja penetración de agua, si bien no resulta sensible para detectar hormigones con elevada permeabilidad. Finalmente en la tesis se ha obtenido un modelo de difusión de cloruros (a/c-D) en ambiente marino aéreo a fin de poder estimar la difusión de cloruros en el hormigón a partir de un requisito normativo como es la relación a/c. This Thesis is focussed to complete the previous study on the corrosion of reinforced concrete exposed to marine environment, carried out by Dr. Miguel Ángel Bermúdez Odrizola in 2007. That Thesis title was “Corrosion of concrete reinforcement located in marine environment: tidal zone and submerged zone”. After the literature review presented in the State of the Art, an experimental programme was carried out. Four docks of different ages and locations have been studied, one of them was a fly ash concrete. The structures were inspected on site and several cores extracted in order to develop characterization tests and obtain diffusion profiles at the laboratory. One of the objectives has been to check the best laboratory test method to control concrete durability when exposed to atmospheric marine environment. This Thesis has proven the effectiveness of the water penetration test to differentiate concretes well behaved against chloride diffusion and also to predict the structure service life. Another objective has been to study the effect of mineral additions in concrete and how they improve the durability of concrete in this environment. Efficiency factors have been obtained for fly ashes and silica fume, much higher than those consider for strength. According to the Spanish Concrete Code EHE 08, the atmospheric marine environment includes structures located at the cost, from the sea line up to 5km inland. The research conducted has shown the need to consider a spray zone which is the most unfavourable area of the atmospheric environment, affecting structures over the sea level as the decks of the wharves here studied. Surface chloride contents of structures in the different marine environments have been deeply analysed, checking the actual standard limits. As a conclusion, new normative values have been proposed for submerged and atmospheric zone (spray zone). A complete analysis of the chloride threshold concentration from the data obtained in real structures has also been performed. It has been evaluated the resistivity test as a tool to estimate the chloride diffusion coefficient. This test has proven effectiveness to discriminate concrete with mineral additions and low water penetration values, while it is not sensitive to detect concretes with high permeability. Finally, a chloride diffusion model (w/c) has been obtained in atmospheric marine environment in order to estimate the chloride diffusion of the concrete knowing a normative requirement as w/c.