Selección de métodos estadísticos para la interpretación de intercomparaciones en ensayos de áridos finos

El objeto de este proyecto es seleccionar los métodos estadísticos adecuados para el tratamiento de los resultados obtenidos en un ejercicio de intercomparación para ensayos de áridos para construcción con el fin de cumplir la normativa para dicho ejercicio. Los ensayos estudiados son: - Ensayo Azul de Metileno - Equivalente de arena - Contenido total en azufre - Contenido en humus - Reactividad álcali-carbonato Los criterios aplicables para el desarrollo de los trabajos son los exigidos por la Entidad Nacional de Acreditación (ENAC) para laboratorios acreditados conforme a la Norma UNE-EN ISO/IEC 17025 y para proveedores acreditados conforme a la Norma UNE-EN ISO/IEC 17043. ABSTRACT: The purpose of this Project is to select appropriate statistical methods for the treatment of the results obtained from an intercomparison exercise for testing of aggregates for construction with the target of comply the rules for this exercise. The studied assays are: - Methylene Blue Assay - Sand equivalent - Total Sulfur Content - Humus content - Alkali-carbonate reactivity The criteria for the development of the work are those required by the National Accreditation Body (ENAC) for laboratories accredited in accordance with the UNE-EN ISO / IEC 17025 and for suppliers in accordance with the UNE-EN ISO / IEC 17043.

Sol-gel TiO2 nanoparticles prompt photocatalytic cement for pollution degradation

TiO2 nanoparticles (TiO2NPs) prepared by the sol–gel method have been incorporated to cement paste with the aim of creating a photocatalytic system capable of compensating, through degradation of hazardous molecules, the envi- ronmental impact associated to the production of the clinker. Doping was carried out at different mass ratios with TiO2NPs precursor solutions within a fresh ce- ment paste, which was then characterized using scanning electron microscopy (SEM). The photocatalytic performance was evaluated by the degradation of Methylene Blue (MB) using a 125W UV lamp as irradiating source. Main cement properties such as hydration degree and C-S-H content are affected by TiO2NPs doping level. Cement containing TiO2NPs exhibited an increasing photocatalytic activity for increasing doping, while the pure cement paste control could hardly degrade MB. The kinetics of the system where also studied and their second order behavior related to microstructural aspects of the system.