40ar/39ar Dating of alunite from the Pueblo Viejo Gold-Silver District, Dominican Republic

New 40Ar/39Ar ages for alunite from the Moore and Monte Negro deposits in the Pueblo Viejo district, as well as from a newly discovered alunite-bearing zone on Loma la Cuaba west of the known deposits, are reported here. The ages range from about 80 to 40 Ma, with closely adjacent samples exhibiting very different ages. Interpretation of these results in the context of estimated closure temperatures for alunite and the geologic and tectonic evolution of Hispaniola does not lead to a simple conclusion about the age of mineralization. The simplest interpretation, that mineralization was caused by a buried Late Cretaceous (~80 Ma) intrusion, is complicated by lack of intrusions of this age in the area and absence of alteration in overlying limestone. The alternative interpretation, that mineralization was formed during Early Cretaceous (~110 Ma) magmatism and that the 40Ar/39Ar ages were completely reset by Late Cretaceous thrusting, is complicated by a lack of information on the timing and thermal effects of thrusting in central Hispaniola. Alunite studies have yielded similar unclear results in other pre-Cenozoic ore systems, notably those of the Lachlan fold belt in Australia

Guidelines of natural zeolites characterization for acid mine drainage treatment. Case study Guayaquil, Ecuador

Zeolites constitute one of the less common groups of tectosilicates. Zeoli1es with pores between -2 to 10 A in their structures have strong sorption capacity and are widely used in industrial and municipal operations to eliminate toxic substances. One of the major environmental problems in the mining activity is the treating of acid mine drainage. In this context, it is very important to search alternatives to manage this challenge. One feasible alternative is using zeolitic tuffs. The results of the physical-chemical characterization of zeolitic tuffs are the c1ue lo continue or not with deeper analysis and tests 01 acid mine drainage treatments. The guidelines to reach this purpose are the main goal of this work. Zeolite 1uff samples (named as XB_01 and XB_02) studied in this work were laken rn the Late Cretaceous Coastal Cayo Arch Ecuador, specifically in the Guaraguao River, showing the most important characteristics of heulandite zeolitic tuffs. X-ray powder diffraction (XRD) tests were developed in order to confirm that the samples belong to the heulandite-type zeoli1ic tuffs. Additionally, Thermogravimetric analysis (TG), Inductively coupled plasma-atomic emission spectroscopy (ICP-AES) and X-ray fluorescence (XRF) of the samples was necessary in order to define the Si/Al ratio and the main mineralogical phases. The XB_01 sample shows a higher ratio Si/Al than XB_02 sample. The cation exchange capacity est was the fundamental step to define the potentiality of the zeolite to use in acid mine drainage treatment Three methodologies were employed to determine the cation exchange capacity. The Cuban standard 626 and the ammonium exchange methodologies reflect results more consistent with each other. This is the starting point to continue with deeper studies such as breakthrough curves for heavy metal ions found in acid mine waters.