Effects of sheep and horse manure and pine bark amendments on metal distribution and chemical properties of contaminated mine soils.

Mine soils usually contain large levels of heavy metals and poor fertility conditions which limit their reclamation and the application of phyto-remediation technologies. Two organic waste materials (pine bark compost and sheep and horse manure compost), with different pHs and varying degrees of humification and nutrient contents, were applied as amendments to assess their effects on copper (Cu) and zinc (Zn) bioavailability and on fertility conditions of mine soils. Soil samples collected from two abandoned mining areas near Madrid (Spain) were mixed with 0, 30 and 60 t ha?1 of the organic amendments. The concentrations of metals among the different mineral and organic fractions of soil were determined by several extraction procedures to study the metal distribution in the solid phase of the soil affected by the organic amendments. The results showed that the manure amendment increased the soil pH and the cation exchange capacity and enhanced the nutrient levels of these soils. The pine bark amendment decreased the soil pH and did not significantly change the nutrient status of soil. Soil pH, organic matter content and its degree of humification, which were altered by the amendments, were the main factors affecting Cu fractionation. Zn fractionation was mainly affected by soil pH. The addition of manure not only improved soil fertility, but also decreased metal bioavailability resulting in a reduction of metal toxicity. Conversely, pine bark amendment increased metal ioavailability. The use of sheep and horse manure could be a cost-effective practice for the restoration of contaminated mine soils.

Physical characterization of growing media using standard methods (CEN)- Limitations of Applicability for pine bark and vermiculite

CEN standards have helped to harmonize analytical methods for substrate analysis.Though, for special substrates or constituents the applicability might be Iimited. In this paper a comparative study of implementation of CEN standards to samples of pine bark and vermiculite has been carried out. For composted pine bark, an elongation of the equilibrium period up to 72 instead of 48 hours might increase the accuracy of determinations physical parameters according to EN 13041. For vermiculite, we suggest pycnometry as a feasible technique for the determination of particle density (PD), as the determination of organic matter (OM) as requested by EN 13041 for the calculation of the PD seems not to be applicable for this kind of material.

El templo parroquial de San Antonio de la Florida

El templo parroquial de San Antonio de la Florida

Dentro de sus casas. Casa Fisac en Cerro del Aire. Casa Cano Lasso en la Florida. Casa Asís Cabrero en Puerta de Hierro. Casa Carvajal en Somosaguas. Casa Corrales en Aravaca

Esta tesis doctoral se especializa en el estudio desde el interior de casas de maestros españoles proyectadas y construidas para ellos y sus familias. Casas proyectadas y construidas para ellos mismos por arquitectos “maestros” de la arquitectura española del siglo XX, que acabaron sus estudios de arquitectura después de la guerra civil y que se habían formado en la Escuela de Madrid. Las cinco casas escogidas están situadas en la provincia de Madrid, en la hoy definida como Comunidad de Madrid. Las cinco casas son para el arquitecto y su familia. También las cinco casas son de tipología unifamiliar aislada. Todas ellas tuvieron el carácter de vivienda estable, no de fin de semana, no de refugios experimentales. El método de análisis se estructura en dos grandes bloques, lo que hemos denominado “Enfocando” y “Desde dentro”. Enfocando: Se analizan las obras precedentes de similares características y se realiza un estudio de aproximación al lugar cuyo punto final es la entrada de la casa Desde dentro: Se Inicia el estudio de la vivienda en un recorrido que atiende a los parámetros de relaciones con el exterior, materiales de acabado, mobiliario, condiciones de flexibilidad y crecimiento y relaciones vivienda-estudio. Siempre con el espacio interior como protagonista del estudio Abstract The dissertation focuses on the interior space of "master`s houses" which were conceived and built for the architect and his family. The five houses selected were built in the XX Century .The five houses are located in Madrid. The five houses are detached houses, the five houses are "residences", not experimental houses, or weekend houses. The method has two parts. Focusing and Inside Focusing: This part studies previous works, with similar characteristics. Moreover this part looks at the path from the street to the main door, through the private exterior. Inside: This part studies the relationship between interior and exterior, finishing materials, furniture, flexibility and relation with the professional spaces. All these elements are studied, always with the interior space as the main character.