Epitaxial self-alignment: A new route to hybrid active plasmonic nanostructures

Concepts of lateral ordering of epitaxial semiconductor quantum dots (QDs) are for the first time transferred to hybrid nanostructures for active plasmonics. We review our recent research on the self-alignment of epitaxial nanocrystals of In and Ag on ordered one-dimensional In(Ga)As QD arrays and isolated QDs by molecular beam epitaxy. By changing the growth conditions the size and density of the metal nanocrystals are easily controlled and the surface plasmon resonance wavelength is tuned over a wide range in order to match the emission wavelength of the QDs. Photoluminescence measurements reveal large enhancement of the emitted light intensity due to plasmon enhanced emission and absorption down to the single QD level.

Enhanced radon emission in natural CO2 flows in Campo de Calatrava region (central Spain)

Activity of radon gas in natural soils is commonly low (in the order of few thousands of Bq·m-3) due to the fast decay (half-life= 3.8 days in the case of 222Rn) that prevents accumulation in soil pores. Exceptionally, high Rn soil activity (up to 430 KBq·m-3) is found around point sources of deep CO2 fluxes. These fluxes allow the transport of trace gases (including Rn) to long distances in the geosphere leading to a potential hazard as Rn accumulation in buildings. CO2 degassing is common in active or ancient volcanic fields and occurs as free gas fluxes or dissolved in groundwater. In this work, the occurrence of Rnbearing, CO2 fluxes from the Campo de Calatrava region in Central Spain has been studied in order to determine their (1) magnitude, (2) migration paths and (3) potential impact on the environment, and (4) methodologies to best detection and measurement.

Enhanced thermionic currents by non equilibrium electron population of metals

An analytical expression is derived for the electron thermionic current from heated metals by using a non equilibrium, modified Kappa energy distribution for electrons. This isotropic distribution characterizes the long high energy tails in the electron energy spectrum for low values of the index ? and also accounts for the Fermi energy for the metal electrons. The limit for large ? recovers the classical equilibrium Fermi-Dirac distribution. The predicted electron thermionic current for low ? increases between four and five orders of magnitude with respect to the predictions of the equilibrium Richardson-Dushmann current. The observed departures from this classical expression, also recovered for large ?, would correspond to moderate values of this index. The strong increments predicted by the thermionic emission currents suggest that, under appropriate conditions, materials with non equilibrium electron populations would become more efficient electron emitters at low temperatures.